摘要/Abstract

发展了一类自由基引发不饱和酰胺与多氯甲烷的串联合环反应, 该体系提供了一种可选择性地生成多氯甲基取代的异喹啉酮或二氢异喹啉酮的方法. 同时, 在该工作中开展了机理研究和光学实验.
关键词: 不饱和酰胺, 多氯甲烷, 自由基反应, 异喹啉酮, 二氢异喹啉酮
Free radical initiated cascade cyclization of unsaturated amides with polychloromethanes provides a protocol for the selective synthesis of polychlorinated isoquinolinones, or dihydroisoquinolinones. A series of mechanistic studies and optical experiments were operated in this system.
Key words: unsaturated amide, polychloromethane, radical reaction, isoquinolinone, dihydroisoquinolinone


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