摘要/Abstract

手性甲基脂肪烃类昆虫信息素包括单手性甲基、双手性甲基和多手性甲基脂肪烃类昆虫信息素, 在棘翅夜蛾、南部云杉天牛、桃潜叶蛾等多种农林害虫的绿色防控领域具有极具发展的前景. 按手性甲基的构建方法, 分类阐述了单手性甲基昆虫信息素的合成方法; 根据手性甲基片段的连接策略对双手性甲基与多手性甲基脂肪烃类昆虫信息素的合成方法进行了详细介绍; 并对各种合成方法的优势与不足进行简单讨论, 以及对手性甲基脂肪烃类昆虫信息素的合成研究进行了展望.
关键词: 手性甲基, 昆虫信息素, 不对称合成, 连接策略, 进展
The chiral methyl-branched aliphatic hydrocarbon insect pheromones including single, double and multichiral methyl-branched insect pheromones are the most promising green control ofScoliopteryx libatrix,Monochamus titillator,Lyonetia clerkellaand other many pests. The syntheses of single chiral methyl-branched pheromones are reviewed according to the methods of constructing chiral methyl, whereas the preparation of double chiral methyl-branched and multichiral methyl-branched ones are illustrated on the basis of the linking strategies of the key fragments. Moreover, the advantages and disadvantages of the synthetic approaches are discussed, as well as the prospects for the synthesis of chiral methyl-branched aliphatic hydrocarbon insect pheromones.
Key words: chiral methyl, insect pheromone, asymmetric synthesis, linking strategies, progress


PDF全文下载地址:

点我下载PDF