摘要/Abstract

芳基膦和芳基硫化合物被广泛应用于有机合成、功能材料和药物化学等领域中，发展绿色、温和、高效的磷和硫芳基化方法具有重要意义.近年来，芳炔参与的反应为有机磷和有机硫化合物的芳基化提供了新途径.该方法可避免使用过渡金属催化剂，条件温和且适用范围广.依据反应类型的不同，对近年来芳炔参与的磷和硫芳基化反应的研究进展进行了介绍.
关键词: 芳炔, 有机磷, 有机硫, 芳基化反应
Arylphosphine and aryl sulfur compounds have been widely used in organic synthesis, functional materials and pharmaceutical chemistry. Thus, the development of green, mild and highly efficient methodologies for P- and S-arylation is of great importance. Recently, the reactions involving arynes provided a novel approach to the arylation of organophosphorus and organosulfur compounds. These reactions can be performed in the absence of transition metal catalysts under mild conditions with broad scope. The recent progress in P- and S-arylation reactions with arynes is introduced on the basis of different reaction types.
Key words: aryne, organophosphorus, organosulfur, arylation reaction


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