摘要/Abstract

富电子炔烃，顾名思义，就是碳碳叁键与一个富电子原子或基团连接，使得叁键上的电子云分布改变，从而具有活泼的化学反应活性.富电子炔烃在有机合成中扮演了十分重要的角色，可作为合成模块用于各类新型有机反应的开发.其中，富电子炔烃和羧酸的氢-酰氧化加成反应是富电子炔烃化学的重要部分，近年来也有了系统的研究.本综述对富电子炔烃与羧酸的加成反应及其合成应用进行了详细总结，并对该领域进行了展望.
关键词: 富电子炔烃, 羧酸, 加成反应, 氢-酰氧化
Electron-rich alkynes, in which an electron-donating atom or group is attached to the triple bond, have been widely used as versatile building blocks in organic synthesis, due to their unique chemical reactivity. As an important part of electron-rich alkyne chemistry, the addition reaction between electron-rich alkynes and carboxylic acids received considerable attention these years, and various investigations and advances have been reported. The progress of addition reactions between electron-rich alkynes and carboxylic acids is summarized, and the future perspective is prospected.
Key words: electron-rich alkyne, carboxylic acid, addition reaction, hydro-acyloxylation


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