摘要/Abstract

烷基硼酸酯类化合物在有机合成、材料化学和医药领域有着广泛的用途，其合成一直是化学工作者的研究热点.其中，过渡金属催化烯烃硼氢化反应是构建烷基硼酸酯类化合物的最有效方法之一.与铑、钌、钯、铱等贵金属催化剂相比，铁、钴、镍催化剂不但价格便宜，而且具有良好的反应活性和区域选择性.主要综述了1994年以来，铁、钴、镍在催化烯烃硼氢化反应方面的研究进展，详细阐述了不同的催化体系在催化活性、反应选择性、底物适用性等方面的特点.
关键词: 铁催化, 钴催化, 镍催化, 硼氢化反应, 区域选择性
The synthesis of alkyl boronic esters has attracted much attention because of their wide applications in organic synthesis, materials and medicines. Transition-metal catalyzed hydroboration of alkenes was one of the most effective methods to construct alkyl boronic esters. Compared with rhodium, ruthenium, palladium, iridium and other precious metal catalysts, iron, cobalt and nickel catalysts were not only low cost, but also they displayed unique reactivity and selectivity. In this paper, the important advances in hydroboration of alkenes catalyzed by iron, cobalt and nickel have been summarized since 1994, including catalytic activity, selectivity and substrate scope of different catalytic systems.
Key words: iron-catalysis, cobalt-catalysis, nickel-catalysis, hydroboration, regio-selectivity


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