摘要/Abstract

过渡金属催化C—H活化反应中，配体能够对催化中心的空间及电子效应进行调控，从而实现芳烃C—H键的选择性官能化.近年来，配体促进芳烃远程C—H键官能化反应研究有了新的进展.对近几年来配体促进的过渡金属催化芳烃远程meta-C—H键选择性官能化反应进行了系统总结，并对该研究领域的局限性和未来的发展前景进行总结和展望.
关键词: 过渡金属催化, 远程meta-C—H键, 官能化反应, 配体促进
Ligands can regulate both the steric and electronic effects of the catalytic center in transition-metal-catalyzed C-H activation reactions, leading to the site-selective C-H functionalization of arenes. In recent years, ligand-promoted remote C-H functionalization of arenes has developed rapidly. The recent progress on ligand-promoted transition-metal-catalyzed remote meta-selective C-H bond functionalization of arenes is summarized, and the limitations of the research field and prospects for future development are presented.
Key words: transition metal catalysis, remote meta-C—H bond, functionalization, ligand promotion


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