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Pd(OAc)2/CuI分步催化合成多取代3-烃硫(硒)基吲哚化合物

本站小编 Free考研考试/2022-02-14

摘要/Abstract



Tandem Pd(OAc)2/CuI catalyzed coupling/cyclization/chalcogenylation reaction of gem-dibromovinylanilines with boronic acids and dichalcogenides has been developed, which provides a new synthetic approach to 3-sulfenyl-and 3-selenylindoles. Various functional groups such as methoxyl, halides and trifluoromethyl groups in the substrates are tolerated.
关键词: 吲哚, Pd(OAc)2/CuI, 催化, 合成
Key words: indole, Pd(OAc)2/CuI, catalysis, synthesis


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