摘要/Abstract

发展了一类β，γ-不饱和腙与二硫/硒化物在铜催化下进行的自由基历程的硫/硒胺基化反应，合成了一系列的硫/硒化吡唑啉类化合物.该反应操作简便且反应条件温和.
关键词: 铜催化, β,γ-不饱和腙, 硫/硒胺基化, 吡唑啉
A convenient copper-catalyzed sulfeno-/seleno-amination of β,γ-unsaturated hydrazones with disulfides/diselenides via radical pathway has been developed. The protocol enables efficient access to various sulfenylated/selenylated pyrazolines under mild reaction conditions.
Key words: copper-catalyzed, β,γ-unsaturated hydrazones, sulfeno-/selenoamination, pyrazoline


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