摘要/Abstract

氧杂蒽类有机染料作为光氧化还原催化剂，因具有廉价易得、水溶性好、反应活性高等优点被广泛应用于可见光诱导的有机合成中.其催化的有机反应类型不断被拓展，有逐渐取代部分过渡金属催化剂的趋势.根据反应类型进行分类，综述了近些年几种常用氧杂蒽类有机染料在光诱导有机合成中的研究进展，并对其前景进行了展望.
关键词: 有机染料, 光氧化还原, 有机合成, 过渡金属
Oxime organic dyes, acting as photoredox catalysts, are widely used in visible-light-induced organic synthesis due to their advantages of low cost, good water solubility, high reactivity and so on. The type of organic dyes-catalyzed organic reactions is continuously expanding, and there is a tendency that organic dyes are gradually replacing some of transition metal catalysts. Classified by the type of reactions, the research progress of several common organic dyes in visible-light-induced organic synthesis in recent years is reviewed, and their future outlook is also discussed.
Key words: organic dyes, photoredox, organic synthesis, transition metals


PDF全文下载地址:

点我下载PDF