摘要/Abstract
报道了以三氯异氰尿酸作为氯源,在室温条件下高效实现了α-氰基酮类化合物和1,3-二羰基类化合物氯化反应的研究.该反应过程条件温和,无需额外添加氧化剂或碱.
关键词: 三氯异氰尿酸, 氯化反应, α-氰基酮
The α-chlorination of α-substituted-α-cyano ketone compounds and 1,3-dicabonyl compounds is described. Using 0.34 equiv. trichloroisocyanuric acid as chlorine source, the chlorination can efficiently access at room temperature in a mild condition without additional oxidant or base. The chloride products can be obtained in a higher yield.
Key words: trichloroisocyanuric acid, chlorination reaction, α-cyanoketone
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