摘要/Abstract

采用Lewis酸和水协同作用策略，以1，8-双取代萘化合物为底物，实现了AuI催化的三甲基硅基的1，2-迁移反应.该方法条件相对较为温和，底物普适性较好，且反应具有较高的分离收率.
关键词: 1,8-双取代萘化合物, AuI催化, 三甲基硅基, 1,2-迁移反应
A gold(I)-catalyzed 1,2-silyl migration on 1,8-di-substituted naphthalene rings was realized by synergistic effect of Lewis acid and water. High yields were achieved under relatively mild conditions.
Key words: gold(I)-catalysis, 1,2-silyl migration, 1,8-di-substituted naphthalene ring


PDF全文下载地址:

点我下载PDF