个人简历

要红昌，南京大学理学博士，香港中文大学访问学者。现任郑州大学化学学院教授，博士生/硕士导师。研究方向主要涉及光催化材料(包括二氧化碳还原、光解水制氢、污染物降解)的设计、合成及性能研究，以及气敏材料的制备及其在呼气分析、环境监测等领域的应用研究。主持和参与国家自然科学基金、河南省科技厅基金、河南省教育厅基金和郑州市科技局项目多项。近年来，以通讯作者或第一作者在Appl. Catal.B: Environm., ACS Appl. Mater. Interfaces, J. Power Sources, Sensors andActuators B, J. CO₂Utilization, J. Hazard. Mater., Chem. Commun.等刊物上发表SCI论文40余篇。

联系方式:

邮箱: yaohongchang@zzu.edu.cn; hchyao111@163.com

主要研究方向：

1.光催化材料的制备及性能研究

环境污染和能源危机是当今世界面临的共同问题。利用太阳能矿化有机污染物、利用太阳能分解水制氢以及利用太阳能把二氧化碳还原为有机原料，是解决上述问题的有效途径。而有效利用太阳能实现污染物矿化、分解水制氢以及二氧化碳还原的关键，是可见光催化剂的制备。课题组通过金属离子掺杂、表面敏化、贵金属沉积以及半导体复合等方法，设计合成新型的可见光催化剂；通过催化剂带隙结构的调节，提高可见光催化效率。相关研究成果已发表在ACS Appl. Mater. Interfaces，J. Hazard. Mater.，Catal.Comm.等专业杂志上。

2.半导体气敏材料的制备及其选择性研究

气体传感器在环境监测、污染监控、煤矿安全、食品检测以及呼气分析等领域发挥着日益重要的作用。金属氧化物半导体气体传感器因灵敏度高、稳定性好、结构简单、价格便宜等特点而受到广泛关注。但半导体气敏材料存在着选择性差等缺点,限制了气体传感器在特定领域的发展和应用。课题组针对这些问题，根据半导体材料对不同气体的气敏机理，通过掺杂、纳米组装、功能化等技术的综合运用，从而达到对特定气体的选择性检测。相关研究成果已发表在Sens. Actuator B，IEEE Sensors J. 等相关专业杂志上。

代表性论文：

[46] Rong-Hui Zhou, Zhi-He Wei, Yan-YangLi, Zhong-Jun Li, Hong-Chang Yao*.Construction of visible light–responsive Z-scheme CdS/BiOI photocatalyst withenhanced photocatalytic CO₂ reduction activity. Journal of Materials Research. 2019,

34, 3907-3917.

[45] Yan-Yang Li, Zhi-He Wei, Jin-BinFan, Zhong-Jun Li*, Hong-Chang Yao*.Photocatalytic CO₂ reduction activity of Z-scheme CdS/CdWO₄catalysts constructed by surface charge directed selective deposition of CdS. Applied Surface Science 2019, 483, 442–452.

[44] Liu-Dan Zhao, Qian Zhang, Jin-BinFan, Li-Qiang Yin, Peng-Wei Qi, Hong-Chang Yao*, Zhong-Jun Li*. Improvement ofthe photoelectrochemical performance of vertically aligned WO₃nanosheet array film with a disordered surface layer by electroreduction. Journal of Solid State Electrochemistry 2019, 23, 1621–1630.

[43] Meng-Di Wang, Yan-Yang Li, Bo-HanYao, Kaihua Zhai, Zhong-Jun Li, Hong-ChangYao*. Synthesis of three-dimensionally ordered macro/mesoporous C-doped WO₃materials: Effffect of template sizes on gas sensing properties. Sensors & Actuators: B. Chemical 2019, 288, 656–666.

[42] Ya-Kun Lv, Bo-Han Yao, Zhi-QiangLiu, Shuang Liang, Qing-Chao Liu*, Kaihua Zhai*, Zhong-Jun Li, Hong-Chang Yao*. Hierarchical Au-loadedWO₃ hollow microspheres with high sensitive and selective propertiesto toluene and xylene. IEEE Sensors Journal 2019,19, 5413-5420.

[41] Qun-Zeng Huang, Ze-Juan Tao,Li-Qun Ye, Hong-Chang Yao*, Zhong-Jun Li*. Mn_0.2Cd_0.8Snanowires modified by CoP₃ nanoparticles for highly efficientphotocatalytic H₂ evolution under visible light irradiation. Appl. Catal. B: Environm. 2018,237, 689-698.

[40] Zhi-He Wei, Yan-Fang Wang,Yan-Yang Li, Lin Zhang, Hong-Chang Yao*, Zhong-Jun Li*. Enhancedphotocatalytic CO₂ reduction activity of Z-scheme CdS/BiVO₄nanocomposite with thinner BiVO₄ nanosheets. J. CO₂ Utilization 2018, 28, 15-25.

[39] Shiyu Ma, Hongchang Yao,Dongling Lei, Xiaoqing Guo, Youcai Lu, Qingchao Liu* and Zhongjun Li*.Tailoring the components and morphology of discharge products towards highlyrechargeable Li-CO/CO₂ batteries. Chem. Commun. 2018, 54, 8072-8075.

[38] Jun-Yue Shen, Meng-Di Wang,Yan-Fang Wang, Jing-Ya Hu, Yanyan Zhu*, Yu Xin Zhang*, Zhong-JunLi, Hong-Chang Yao*. Iron and carbon codoped WO₃with hierarchical walnut-like microstructure for highly sensitive and selectiveacetone sensor. Sensors and Actuators B2018, 256, 27-37.

[37] Qun-Zeng Huang, Ji-Chao Wang,Li-Qun Ye, Qian Zhang, Hong-Chang Yao*, Zhong-Jun Li*. A novelp–n heterojunction Mn_0.25Cd_0.75S/Co₃O₄for highly efficient photocatalytic H₂ evolution under visible lightirradiation. J. Taiwan Inst. Chem. E. 2017,80, 570–577.

[36] Qun-Zeng Huang, Yan Xiong,Qian Zhang, Hong-Chang Yao*, Zhong-Jun Li*. Noblemetal-free MoS₂modified Mn_0.25Cd_0.75S forhighly efficient visible-light driven photocatalytic H₂. Appl. Catal. B: Environ. 2017,209, 514–522.

[35] Qun-Zeng Huang, Ji-Chao Wang,Pan-Pan Wang, Hong-Chang Yao*, Zhong-Jun Li*. In-situgrowth of mesoporous Nb₂O₅ microspheres on g-C₃N₄nanosheets for enhanced photocatalytic H₂ evolution under visiblelight irradiation. Int. J. HydrogenEnergy 2017, 42, 6683-6694.

[34] Jun-Yue Shen, Lin Zhang, Juan Ren, Ji-Chao Wang, Hong-Chang Yao*, Zhong-Jun Li*. Highlyenhanced acetone sensing performance of porous C-doped WO₃ hollowspheres by carbon spheres as templates. Sensorsand Actuators B 2017, 239,597–607.

[33] Lin Zhang*, Hongchang Yao,Zhaohui Li, Piaopiao Sun, Fei Liu, Cui Dong, Jianshe Wang, Zhongjun Li, MingweiWu, Chang Zhang, Bo Zhao. Synthesis of delaminated layered double hydroxidesand their assembly with graphene oxide for supercapacitor application. J. Alloy. Compd. 2017, 711,31-41.

[32] Ji-Chao Wang, Hong-ChangYao*, Ze-YuFan, Lin Zhang, Jian-She Wang, Shuang-Quan Zang and Zhong-Jun Li*. Indirect Z-Scheme BiOI/g-C₃N₄ Photocatalystswith Enhanced Photoreduction CO₂ Activity under Visible LightIrradiation. ACS Appl. Mater. Interfaces, 2016, 8, 3765-3775.

[31] Ji-Chao Wang,Juan Ren, Hong-Chang Yao*, Lin Zhang, Jian-She Wang, Shuang-QuanZang, Li-Feng Han, Zhong-Jun Li*. SynergisticPhotocatalysis of Cr(VI) Reduction and 4-Chlorophenol Degradation overHydroxylated rmalpha-Fe₂O₃ under Visible LightIrradiation. J. Hazard. Mater.2016, 311,11-19.

[30] Xiao-Bo Wang, Hui-Qin Zheng, HengRao, Hong-Chang Yao*, Yao-Ting Fan*and Hong-Wei Hou. Synthesis of a new iron–sulfur cluster compound and itsphotocatalytic H₂ evolution activity through visible light irradiation.Appl. Organomet.Chem. 2016, 30, 638-644.

[29] Ji-Chao Wang, Lin Zhang, Wen-Xue Fang,Juan Ren, Yong-Yu Li, Hong-Chang Yao*,Jian-She Wang, and Zhong-Jun Li*. Enhanced Photoreduction CO₂Activity over Direct Z‑Scheme α‑Fe₂O₃/Cu₂OHeterostructures under Visible Light Irradiation. ACS Appl. Mater. Interfaces 2015,7, 8631−8639.

[28] Yuanyuan Zhou, HongchangYao, Jianshe Wang, Dalu Wang, Qian Liu, Zhongjun Li. Greener synthesis ofelectrospun collagen/hydroxyapatite composite fibers with an excellent microstructurefor bone tissue engineering. Int. J.Nanomed. 2015, 10, 3203–3215.

[27] Teng Xiao, Xiu-Yue Wang, Zhi-Hua Zhao, Liu Li, Jian-She Wang, Hong-ChangYao*, Zhong-Jun Li. Highlysensitive and selective acetone sensor based on C-doped WO₃ forpotential diagnosis of diabetes mellitus. Sensors and Actuator B 2014, 199, 210-219.

[26] Hong-Chang Yao,Ling-Li Zhang, Zhong-Jun Li. Two Coordination Polymers Assembled From2,2’,6,6’-Tetracarboxybiphenyl and Schiff Base: Synthesis, Crystal Structures,and Properties. Synth. React. Inorg. M.2014, 44, 1-8.

[25] Jiyong Hu, HongchangYao, Yun Bai, Dandan Zhao, Shufang Chen, Jin’an Zhao. Multinuclear-basedcopper coordination architectures constructed frompyridyl-1H-benzimidazol-derived flexible tripodal connector and the magneticbehaviors. Polyhedron 2014, 78, 1-9.

[24] Hong-Chang Yao*, Xue-Li Zhao, Xing Chen, Ji-ChaoWang, Qian-Qing Ge, Jian-She Wang, Zhong-Jun Li. Processing andcharacterization of CoO and Sm₂O₃ codoped ceria solidsolution electrolyte. J. Power Sources2012, 205, 180-187.

[23] Rui-Rui Pei, Xing Chen, Yang Suo, Teng Xiao, Qian-QingGe, Hong-Chang Yao*, Jian-She Wang,Zhong-Jun Li*. Synthesis of La_0.85Sr_0.15Ga_0.8Mg_0.2O_3−δ powder by carbonate co-precipitation combining withazeotropic-distillation process. SolidState Ionics 2012, 219, 34–40.

[22] Xue-Li Zhao, Jia-Jia Liu, Teng Xiao, Ji-Chao Wang,Yu-XinZhang, Hong-Chang Yao*, Jian-She Wang, Zhong-Jun Li. Effectof Ca co-dopant on the electrical conductivity of Gd-doped ceria. J. Electroceram. 2012, 28, 149-157.

[21] Linke Li, HongchangYao, Jingjing Zhao, Zhihui Yang, Hongwei Hou. Two Picolinamide-Based Zn(II)Coordination Polymers: Syntheses, Structures, and Catalytic Activities. Synth. React. Inorg. M. 2012, 42, 46-52.

[20] Hong-Chang Yao*, Yu-Xin Zhang, Jia-Jia Liu, Yue-LiLi, Jian-She Wang, Zhong-Jun Li. Synthesis and characterization of Gd³⁺and Nd³⁺ co-doped ceria by using citric acid–nitrate combustionmethod. Mater. Res. Bull. 2011,46, 75–80.

[19] Wen-Juan Chu, Hong-Chang Yao, Yao-Ting Fan*, Hong-Wei Hou. Anion exchange induced tunablecatalysis properties of an uncommon butterfly-like tetranuclear copper(II)cluster and magnetic characterization.Dalton Trans. 2011, 40, 2555–2561.

[18] Huijun Li, HongchangYao, Erpeng Zhang, Yanyuan Jia, Hongwei Hou*, Yaoting Fan. Crystalstructures and magnetism of infinite alternating chains arranged bypaddle-wheel dinuclear copper and mononuclear copper units. Dalton Trans. 2011,40, 9388–9393.

[17] Hong-Chang Yao,Xian-Wei Wang, Hao Dong, Rui-Rui Pei, Jian-She Wang, Zhong-Jun Li*. Synthesisand characteristics of nanocrystalline YSZ powder by polyethylene glycolassisted coprecipitation combined with azeotropic-distillation process and itselectrical conductivity. Ceram. Int. 2011, 37, 3153–3160.

[16] Yongyu Li, HongchangYao, Jianshe Wang, Ning Wang, Zhongjun Li*. Influence of the precipitationpH on the compositions and properties of Bi-based oxyiodide photocatalysts. Mater. Res. Bull. 2011, 46, 292-296.

[15] Wenjuan Chu, HongchangYao, Hongcui Ma, Yong He, Yaoting Fan*, Hongwei Hou. Syntheses, structures,and characterizations of two coordination polymers assembled from zinc(II)salts with 1,2-bis[3-(1,2,4-triazolyl)-4-amino-5-carboxyl methylthio]ethane. J. Coord. Chem. 2010, 63, 3734-3742.

[14] Hong-Chang Yao,Jian-She Wang, Dong-Ge Hu, Jing-Feng Li, Xiao-Rui Lu, Zhong-Jun Li*. Newapproach to develop dense lanthanum silicate oxyapatite sintered ceramics withhigh conductivity. Solid State Ionics2010, 181, 41–47.

[13] Hong-Chang Yao*, Ning Wang, Su-Lan Xie, Zhong-Jun Li. Magnetic properties of a linear trinuclear manganese compound [Mn₃(PhCO₂)₆(Bipy)₂]·H₂O.Russian J. Coord. Chem. 2009,35(11), 822–826.

[12] Hong-Chang Yao*, Miao-Miao Li, Li-MinZheng, Zhong-Jun Li. Structureand magnetism of a linear trimanganese (III, II, III) complex based on benzoateand Schiff-base ligands. J. Coord. Chem. 2008, 61,2814-2822.

[11] YAO Hong-chang , 　WANG Ning, 　LI Miao-miao, 　LI Zhong-jun. Synthesis, Characterization and Magnetic Property of a Mixed-valence Hexanuclear Manganese Cluster.郑州大学学报(理学版) 2008, 40(4), 88-94.

[10] 要红昌，王宁，李淼淼，李中军. 新颖六核锰(III)簇合物的合成、结构与磁性. 郑州大学学报(理学版), 2008, 40(1), 88-93.

[9] Hong-Chang Yao, Ning Wang, LiZhang and Zhong-Jun Li. Hexa-μ₂-benzoato-bis(2,2’-bipyridyl)-trimanganese(II)monohydrate. Acta Crystallogr. E 2008, E64, m774.

[8] Xiao-Qing Shen, Hong-Chang Yao, Rui Yang, Zhong-Jun Li, Hong-Yun Zhang*,Ben-Lai Wu, Hong-Wei Hou. Synthesis,structure and thermal properties of polynuclear complexes with a newmultidentate ligand, N,N’-bis(5-ethyl-1,3,4-thiadiazol-2-yl)-2,6-pyridinedicarboxamide. Polyhedron 2008, 27, 203–209.

[7] Hong-Chang Yao*, Miao-Miao Li,Gao-Sheng Yang, Zhong-Jun Li, Yu Zhu. Ketonization of methylene ofbis(benzimidazol-2-yl)methane by molecular oxygen under the catalysis ofcobalt(II) ion. Inorg. Chim. Acta 2007, 360,3959-3964.

[6] Yun-Sheng Ma, Hong-Chang Yao, Wei-Jie Hua , Shu-Hua Li Yi-Zhi Li , Li-Min Zheng*. Tetranuclearmanganese(III) clusters containing both carboxylate and phosphonate bridgingligands. Inorg. Chim.Acta 2007, 360,1645–1650.

[5] Hong-Chang Yao, Jun-Jie Wang, Yun-Sheng Ma, OliverWaldmann*, Wen-Xin Du, You Song, Yi-Zhi Li, Li-Min Zheng*, Silvio Decurtins*and Xin-Quan Xin. An iron(III) phosphonate cluster containing a nonanuclearring. Chem. Commun. 2006, 1745–1747.

[4] Hong-Chang Yao, Yi-Zhi Li,You Song, Yun-Sheng Ma, Li-Min Zheng,* and Xin-Quan Xin. DodecanuclearManganese(III) Phosphonates with Cage Structures. Inorg.Chem. 2006, 45, 59-65.

[3] Hong-ChangYao, Yi-Zhi Li, Li-Min Zheng*, Xin-Quan Xin. Syntheses, structures andmagnetic properties of tetra- and heptanuclear iron(III) clusters incorporatingphosphonate ligands. Inorg. Chim. Acta2005, 358, 2523–2529.

[2] Hong-ChangYao, Yi-Zhi Li, Song Gao, You Song, Li-Min Zheng*, Xin-Quan Xin. Copperphosphonates with dinuclear and layer structures: a structural and magneticstudy. J. Solid State Chem. 2004, 177,4557-4563.

[1] 要红昌,郑丽敏*, 忻新泉. 有机膦酸铜化合物的合成、结构及性质.无机化学学报. 2004, 20(6), 625-631.