2.天津工业大学,省部共建分离膜与膜过程国家重点实验室,天津 300387
1.School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, China
2.State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
的去除效率;通过三维荧光光谱、亲疏水性和凝胶色谱分析,考察了两种技术对不同种类、不同亲疏水性以及不同分子质量有机物的去除规律。结果表明,MIEX在净水性能上整体都明显优于K
预氧化能够促进疏水组分向亲水组分、大分子向小分子转化,致使二者在去除亲水性和弱疏水性有机物,腐殖质类和类络氨酸类蛋白质,以及分子质量为0.2~1 kDa有机物几方面都表现出明显的协同效应。联合处理工艺对总有机物和芳香族类有机物的协同去除效应系数分别达到2.08和1.22。以上实验结果表明,K
预氧化和MIEX吸附两种技术耦合在净水方面确实存在很好的协同效应。
pre-oxidation and MIEX adsorption, their difference and possible synergistic effects of water purification were systematically explored. The removal efficiencies of DOC and UV
-MIEX were investigated, respectively. Through three-dimensional fluorescence spectrum, hydrophilicity and hydrophobicity, and gel chromatography analysis, the removal of organics with different species, hydrophilic and hydrophobic properties and molecular scales were studied. The results showed that on the whole, the water purification performance of MIEX adsorption was significantly better than K
pre-oxidation. During the combined treatment of K
pre-oxidation could promote the conversion of hydrophobic components to hydrophilic ones, macro-molecules to micro-molecules. As a result, K
and MIEX showed significant synergistic effects on removing hydrophilic and weakly hydrophobic components, humic-like substances and tyrosine-like proteins, and organic matters with a molecular weight range of 0.2 to 1 kDa. The synergistic coefficients of the combined process on removing total organic matters and aromatic organic matters were 2.08 and 1.22, respectively. These experimental results showed that the coupling of K
pre-oxidation and MIEX adsorption does have a good synergistic effect on water purification.
.
oxidation at different dosages
Three-dimensional fluorescence spectra and FRI analysis
Molecular weight distribution of organic matters in water
Corresponding relationship between the matrix partition of excitation-emission fluorescence spectra response values and the types of organic matters
[1] | YU W, YANG Y, GRAHAM N. Evaluation of ferrate as a coagulant aid/oxidant pretreatment for mitigating submerged ultrafiltration membrane fouling in drinking water treatment[J]. Chemical Engineering Journal, 2016, 298: 234-242. doi: 10.1016/j.cej.2016.03.080 |
[2] | WANG W Q, WA Y C, ZHANG X F, et al. Whey protein membrane processing methods and membrane fouling mechanism analysis[J]. Food Chemistry, 2019, 289: 468-481. doi: 10.1016/j.foodchem.2019.03.086 |
[3] | DHARUPANEEDI S P, NATARAJ S K, NADAGOUDA M, et al. Membrane-based separation of potential emerging pollutants[J]. Separation and Purification Technology, 2019, 210: 850-866. |
[4] | ARHIN S G, BANADDA N, KOMAKECH A J, et al. Application of hybrid coagulation-ultrafiltration for decentralized drinking water treatment: Impact on flux water quality and costs[J]. Water Science and Technology Water Supply, 2019, 19(7): 2163-2171. doi: 10.2166/ws.2019.097 |
[5] | TABATABAI S, SCHIPPERS J C, KENNEDY M D. Effect of coagulation on fouling potential and removal of algal organic matter in ultrafiltration pretreatment to seawater reverse osmosis[J]. Water Research, 2014, 59: 283-294. |
[6] | BODZEK M. Membrane separation techniques removal of inorganic and organic admixtures and impurities from water environment: Review[J]. Archives of Environmental Protection, 2019, 45(4): 4-19. |
[7] | YU W Z, LIU M J, GRAHAM N J D. Combining magnetic ion exchange media and microsand before coagulation as pretreatment for submerged ultrafiltration: Biopolymers and small molecular weight organic matter[J]. American Chemical Society Sustainable Chemistry & Engineering, 2019, 7(22): 18566-18573. |
[8] | XING J, WANG H, CHENG X, et al. Application of low-dosage UV/chlorine pre-oxidation for mitigating ultrafiltration (UF) membrane fouling in natural surface water treatment[J]. Chemical Engineering Journal, 2018, 344: 62-70. doi: 10.1016/j.cej.2018.03.052 |
[9] | GUO J, SHI J, WANG K L. The effect of pre-ozonation on UF membrane fouling by the size fractioned sewage effluent[J]. Desalination and Water Treatment, 2017, 87: 91-100. doi: 10.5004/dwt.2017.21071 |
[10] | GIBRRT O, PANGES N, BERNAT X, et al. Removal of dissolved organic carbon and bromide by a hybrid MIEX-ultrafiltration system: Insight into the behaviour of organic fractions[J]. Chemical Engineering Journal, 2017, 312: 59-67. doi: 10.1016/j.cej.2016.11.120 |
[11] | LEVCHUK I, RUEDA MARQUEZ J J, SILLANPAA M. Removal of natural organic matter (NOM) from water by ion exchange: A review[J]. Chemosphere, 2018, 192: 90-104. doi: 10.1016/j.chemosphere.2017.10.101 |
[12] | 杨晓明, 张朝晖, 王亮, 等. MIEX和PAC对微污染水源水的水质净化效果比较[J]. 化工学报, 2016, 67(4): 1505-1511. |
[13] | RITSON J P, GRAHAM N J D, TEMPLETON M R, et al. The impact of climate change on the treatability of dissolved organic matter (DOM) in upland water supplies: A UK perspective[J]. Science of the Total Environment, 2014, 473: 714-730. |
[14] | YANG Y, DING Q, YANG M, et al. Magnetic ion exchange resin for effective removal of perfluorooctanoate from water: Study of a response surface methodology and adsorption performances[J]. Environment Science Pollution Research Internation, 2018, 25(29): 29267-29278. |
[15] | AFTAB B, HUR J. Unraveling complex removal behavior of landfill leachate upon the treatments of Fenton oxidation and MIEX((R)) via two-dimensional correlation size exclusion chromatography (2D-CoSEC)[J]. Journal Hazardous Materials, 2019, 362: 36-44. doi: 10.1016/j.jhazmat.2018.09.017 |
[16] | CHEN Y Y, XU W Y, ZHU H J, et al. Effect of turbidity on micropollutant removal and membrane fouling by MIEX/ultrafiltration hybrid process[J]. Chemosphere, 2019, 216: 488-498. doi: 10.1016/j.chemosphere.2018.10.148 |
[17] | IMBROGNO A, BISCARRAT J, SCHAFER A I. Estradiol uptake in a combined magnetic ion exchange-ultrafiltration (MIEX-UF) process during water treatment[J]. Current Pharmaceutical Design, 2017, 23(2): 328-337. |
[18] | GOODWILL J E, JIANG Y, RECKHOW D A, et al. Characterization of particles from ferrate preoxidation[J]. Environment Science Technology, 2015, 49(8): 4955-4962. doi: 10.1021/acs.est.5b00225 |
[19] | CHEN G, LAM W W Y, LO P K, et al. Mechanism of water oxidation by Ferrate(VI) at pH 7-9[J]. Chemistry- A European Journal, 2018, 24(70): 18735-18742. doi: 10.1002/chem.201803757 |
[20] | ZHENG L, DENG Y. Settleability and characteristics of ferrate(VI)-induced particles in advanced wastewater treatment[J]. Water Research, 2016, 93: 172-178. doi: 10.1016/j.watres.2016.02.015 |
[21] | VIRENDER K. SHARMA S K M, NASRI N. Oxidation of sulfonamide antimicrobials by ferrate(VI)[Fe(VI) $ {\rm{O}}_4^{2 - } $ ][J]. Environment Science & Technology, 2006, 40(23): 6. |
[22] | KOZIK V, BARBUSINSKI K, THOMAS M, et al. Taguchi method and response surface methodology in the treatment of highly contaminated tannery wastewater using commercial potassium ferrate[J]. Materials, 2019, 12(22). |
[23] | YUX W, LICHT S. Recent advances in synthesis and analysis of Fe(VI) cathodes: Solution phase and solid-state Fe(VI) syntheses, reversible thin-film Fe(VI) synthesis, coating-stabilized Fe(VI) synthesis, and Fe(VI) analytical methodologies[J]. Journal of Solid State Electrochemistry, 2008, 12(12): 1523-1540. doi: 10.1007/s10008-008-0541-3 |
[24] | RAI P K, LEE J, KAILASA S K, et al. A critical review of ferrate(VI)-based remediation of soil and groundwater[J]. Environment Research, 2018, 160: 420-448. doi: 10.1016/j.envres.2017.10.016 |
[25] | WU J Z, CAI Y M, ZHANG M Q, et al. Enhancing oxidative capability of ferrate(VI) for oxidative destruction of phenol in water through intercalation of ferrate(VI) into layered double hydroxide[J]. Applied Clay Science, 2019, 171: 48-56. doi: 10.1016/j.clay.2019.02.006 |
[26] | DRZEWICZ P, DROBNIEWSKA A, SIKORSKA K, et al. Analytical and ecotoxicological studies on degradation of fluoxetine and fluvoxamine by potassium ferrate[J]. Environment Technology, 2019, 40(25): 3265-3275. doi: 10.1080/09593330.2018.1468488 |
[27] | WANG X S, LIU Y L, HUANG Z S, et al. Rapid oxidation of iodide and hypoiodous acid with ferrate and no formation of iodoform and monoiodoacetic acid in the ferrate/I-/HA system[J]. Water Research, 2018, 144: 592-602. doi: 10.1016/j.watres.2018.07.061 |
[28] | JUTAPORN P, LAOLERTWORAKUL W, ARMSTRONG M D, et al. Fluorescence spectroscopy for assessing trihalomethane precursors removal by MIEX resin[J]. Water Science and Technology, 2019, 79(5): 820-832. doi: 10.2166/wst.2019.036 |
[29] | 沈兆欢. 磁性离子交换树脂与混凝沉淀组合对有机物去除特性研究[D]. 北京: 清华大学, 2014. |
[30] | CHEN W, WESTERHOFF P, LEENHEER J A, et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter[J]. Environmental Science & Technology, 2003, 37: 10. |
[31] | HE X S, XI B D, WEI Z M, et al. Fluorescence excitation-emission matrix spectroscopy with regional integration analysis for characterizing composition and transformation of dissolved organic matter in landfill leachates[J]. Journal Hazardous Materials, 2011, 190(1/2/3): 293-299. |
[32] | HOSSEINI M, MERTENS S F L, ARSHADI M R. Synergism and antagonism in mild steel corrosion inhibition by sodium dodecylbenzenesulphonate and hexamethylenetetramine[J]. Corrosion Science, 2003, 45(7): 1473-1489. doi: 10.1016/S0010-938X(02)00246-9 |
[33] | ZHANG H, QU J H, LIU H J. Effect of chlorination and ozone pre-oxidation on the photobacteria acute toxicity for dissolved organic matter from sewage treatment plants[J]. Science China-Chemistry, 2010, 53(11): 2394-2398. doi: 10.1007/s11426-010-4040-x |
[34] | LIN P F, ZHANG X J, WANG J, et al. Comparison of different combined treatment processes to address the source water with high concentration of natural organic matter during snowmelt period[J]. Journal of Environmental Sciences, 2015, 27: 51-58. doi: 10.1016/j.jes.2014.04.013 |
[35] | SONG Y, DENG Y, JUNG C. Mitigation and degradation of natural organic matters (NOMs) during ferrate(VI) application for drinking water treatment[J]. Chemosphere, 2016, 146: 145-153. doi: 10.1016/j.chemosphere.2015.12.001 |
[36] | TIRAFERRI A, KANG Y, GIANNELIS E P, et al. Superhydrophilicthin-film composite forward osmosis membranes for organic fouling control: Fouling behavior and antifouling mechanisms[J]. Environmental Science & Technology, 2012, 46(20): 11135-11144. |