张艺蕾1,
李科1,
吴颖虹2,
汪磊1
1. 南开大学环境科学与工程学院, 环境污染过程与基准教育部重点实验室/天津市城市生态环境修复与污染防治重点实验室, 天津 300071;
2. 天津市疾病预防控制中心理化室, 天津 300011
作者简介: 刘玉斌(1994-),男,硕士研究生,研究方向为环境化学,E-mail:15900366759@163.com.
基金项目: 国家自然科学基金资助项目(41722304，21777075)；教育部“111”引智基地项目(T2017002)；中央高校基本科研专项中图分类号: X171.5
Phthalates in Daily Clothes: Occurrence and Human Exposure
Liu Yubin1,Zhang Yilei1,
Li Ke1,
Wu Yinghong2,
Wang Lei1
1. Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria/Tianjin Key Laboratory of Environmental Remediation and Pollution Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China;
2. Department of Physical and Chemical Test, Tianjin Centers for Disease Control and Prevention, Tianjin 300011, China
CLC number: X171.5
-->
摘要
HTML全文
图
参考文献
相关文章
施引文献
资源附件
访问统计
摘要:邻苯二甲酸酯(PAEs)作为一类内分泌干扰物，被广泛应用于工业生产。为了查明日常衣物中PAEs的污染状况，并评估其通过衣物的皮肤接触可能造成的人体暴露风险，本研究检测了日常生活中的新、旧衣服中7种典型PAEs的浓度，并通过实验模拟研究了衣料中PAEs向汗液的析出行为。结果表明，邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二异辛酯(DEHP)分别是旧衣服和新衣服中的代表性PAE。旧衣服中DEHP的浓度显著高于新衣服；婴儿衣服中DEHP的浓度高于成人衣服。穿着和清洗过程中的二次污染可能对衣服中的PAEs有显著影响，衣服材质可能是影响旧衣服中PAEs浓度的重要因素。汗液会导致衣物中的PAEs析出，从而明显增加PAEs的人体暴露风险。
关键词: 邻苯二甲酸酯/
日常衣物/
皮肤暴露/
模拟汗液
Abstract:Phthalate esters (PAEs), a class of endocrine disrupting chemicals, are widely used in industry. To evaluate the occurrence of PAEs in daily clothes and the risk of exposure via skin contact, the concentrations of seven typical PAEs in daily clothes were detected. The role of sweat on PAEs release from clothes was evaluated in simulated experiments. The results show that di-n-butyl phthalate (DBP) and di (2-ethylhexyl) phthalate (DEHP) were the dominant PAEs in the used clothes and new clothes, respectively. Higher levels of DEHP was detected in the used clothes and the infant clothes, compared with those in the new clothes and the adult clothes, respectively. These results suggest that further PAEs contamination in clothes may occur during wearing or laundering, and the clothing material may be an important factor influencing PAEs contamination in the used clothes. Sweat can increase the release of PAEs from clothes, inducing a higher risk of human exposure to PAEs.
Key words:phthalates/
daily clothes/
dermal exposure/
artificial sweat.
| 朱敏,张弛,康嘉玲,等.邻苯二甲酸酯的毒性及其降解研究[J].环境科学与技术, 2013, 36(12M):433-447Zhu M, Zhang C, Kang J L, et al. Toxicity of phthalic acid esters and research of degradation[J]. Environmental Science & Technology, 2013, 36(12M):433-447(in Chinese) |
| Meeker J D, Calafat A M, Hauser R. Di (2-ethylhexyl) phthalate metabolites may alter thyroid hormone levels in men[J]. Environmental Health Perspectives, 2007, 115(7):1029-1034 |
| Huang P C, Kuo P L, Guo Y L, et al. Associations between urinary phthalate monoesters and thyroid hormones in pregnant women[J]. Human Reproduction, 2007, 22(10):2715-2722 |
| Qu R J, Feng M B, Sun P, et al. A comparative study on antioxidant status combined with integrated biomarker response in Carassius auratus fish exposed to nine phthalates[J]. Environmental Toxicology, 2015, 30(10):1125-1134 |
| 黄培东,于芳芳.环境激素及其污染防治研究进展[J].广东化工, 2007, 34(12):86-89Huang P D, Yu F F. Research development on the environmental hormone and its pollution control[J]. Guangdong Chemical Industry, 2007, 34(12):86-89(in Chinese) |
| Braun J M, Sathyanarayana S, Hauser R. Phthalate exposure and children's health[J]. Current Opinion in Pediatrics, 2013, 25(2):247-254 |
| Valvi D, Casas M, Romaguera D, et al. Prenatal phthalate exposure and childhood growth and blood pressure:Evidence from the Spanish INMA-Sabadell birth cohort study[J]. Environmental Health Perspectives, 2015, 123(10):1022-1029 |
| Zhang B, Zhang T, Duan Y S, et al. Human exposure to phthalate esters associated with e-waste dismantling:Exposure levels, sources, and risk assessment[J]. Environment International, 2019, 124:1-9 |
| Güven K C, Coban B. Phthalate pollution in fish Sarda sarda, Engraulis encrasicolus, Mullus surmuletus, Merlan gius merlangus and shrimp Parapenaeus longirostris[J]. Journal of Black Sea/Mediterranean Environment, 2013, 19:185-189 |
| 张驰,徐周,保绮蓓,等.针织服装中邻苯二甲酸酯检出现状及工艺分析[J].针织工业, 2013(8):64-67 Zhang C, Xu Z, Bao Q B, et al. Inspection results of phthalate in knitted garments and its process analysis[J]. Knitting Industries, 2013(8):64-67(in Chinese) |
| 李颖.童装:邻苯二甲酸酯(增塑剂)质量安全风险分析[J].中国纤检, 2013(10):38-40 Li Y. Quality and safety risk analysis for phthalates (plasticizers) in the Children's wear[J]. China Fiber Inspection, 2013(10):38-40(in Chinese) |
| 曹龙,张朝升,陈秋丽,等.邻苯二甲酸酯的环境污染和生态行为及毒理效应研究进展[J].生态毒理学报, 2018, 13(2):34-46Cao L, Zhang C S, Chen Q L, et al. Progress in the study of environmental pollution and ecological behavior and toxicological effects of phthalate ester[J]. Asian Journal of Ecotoxicology, 2018, 13(2):34-46(in Chinese) |
| Rudel R A, Gray J M, Engel C L, et al. Food packaging and bisphenol A and bis (2-ethyhexyl) phthalate exposure:Findings from a dietary intervention[J]. Environmental Health Perspectives, 2011, 119(7):914-920 |
| Koch H M, Lorber M, Christensen K L Y, et al. Identifying sources of phthalate exposure with human biomonitoring:Results of a 48 h fasting study with urine collection and personal activity patterns[J]. International Journal of Hygiene and Environment, 2013, 216(6):672-681 |
| Fromme H, Gruber L, Schlummer M, et al. Intake of phthalates and di (2-ethylhexyl) adipate:Results of the integrated exposure assessment survey based on duplicate diet samples and biomonitoring data[J]. Environmental International, 2007, 3(8):1012-1020 |
| Bekö G, Weschler C J, Langer S, et al. Children's phthalate intakes and resultant cumulative exposures estimated from urine compared with estimates from dust ingestion, inhalation and dermal absorption in their homes and daycare centers[J]. Plos One, 2013, 8(4):e62442 |
| Gong M Y, Weschler C J, Liu L P, et al. Phthalate metabolites in urine samples from Beijing children and correlations with phthalate levels in their handwipes[J]. Indoor Air, 2015, 25(6):572-581 |
| Weschler C J, Bekö G, Koch H M, et al. Transdermal uptake of diethyl phthalate and di (n-butyl) phthalate directly from air:Experimental verification[J]. Environmental Health Perspectives, 2015, 123(10):928-934 |
| Xue J, Liu W, Kannan K. Bisphenols, benzophenones, and bisphenol A diglycidyl ethers in textiles and infant clothing[J]. Environmental Science & Technology, 2017, 51(9):5279-5286 |
| Wu C C, Wang W J, Bao L J, et al. Impacts of texture properties and airborne particles on accumulation of tobacco-derived chemicals in fabrics[J]. Journal of Hazardous Materials, 2019, 369:108-115 |
| Krais A, Andersen C, Eriksson A, et al. Excretion of urinary metabolites of the phthalate esters DEP and DEHP in 16 volunteers after inhalation and dermal exposure[J]. International Journal of Environmental Research and Public Health, 2018, 15(11):2514 |
| Kulthong K, Srisung S, Boonpavanitchakul K, et al. Determination of silver nanoparticle release from antibacterial fabrics into artificial sweat[J]. Partical and Fibre Toxicology, 2010, 7(1):9 |
| Sawka M N, Cheuvront S N, Carter R. Human water needs[J]. Nutrition Reviews, 2005, 63(6):30-39 |
| Sawka M N, Cheuvront S N, Kenefick R W. Hypohydration and human performance:Impact of environment and physiological mechanisms[J]. Sports Medicine, 2015, 45:51-60 |
| Stevenson P H. Height-weight-surface formula for the estimation of surface area in Chinese subjects[J]. Chinese Journal of Physiology, 1937, 3:327-330 |
| Viñas P, Campillo N, Pastorbelda M, et al. Determination of phthalate esters in cleaning and personal care products by dispersive liquid-liquid microextraction and liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A, 2015, 1376:18-25 |
| 王夫美,陈丽,焦姣,等.冬季天津家庭室内空气颗粒物中邻苯二甲酸酯污染研究[J].环境科学, 2012, 33(5):1446-1451Wang F M, Chen L, Jiao J, et al. Phthalates esters pollution in household indoor air particles of Tianjin in winter[J]. Environmental Science, 2012, 33(5):1446-1451(in Chinese) |
| Piadé J J, D'Andrés S, Sanders E B. Sorption phenomena of nicotine and ethenylpyridine vapors on different materials in a test chamber[J]. Environmental Science & Technology, 1999, 33(12):2046-2052 |
| Guo Y, Wang L, Kannan K. Phthalates and parabens in personal care products from China:Concentrations and human exposure[J]. Archives of Environmental Contamination and Toxicology, 2010, 66(1):113-119 |
| Guo Y, Kannan K. Comparative assessment of human exposure to phthalate esters from house dust in China and the United States[J]. Environmental Science & Technology, 2011, 45(8):3788-3794 |
