阴离子交换膜改性及抗污染性能研究进展

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曹仁强^1,3，冯占立²，李玉娇^1,3，赵志娟^1,3，石绍渊^1,4*

1. 过程工程研究所
2. 鞍钢集团工程技术有限公司
3. 中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室

收稿日期:2018-09-17修回日期:2018-11-30出版日期:2019-06-22发布日期:2019-06-20
通讯作者:石绍渊

基金资助:河南省科技开放合作课题;国家自然科学基金;“十二五”水体污染控制与治理科技重大专项

Research progress on modification and antifouling properties of anion exchange membrane

Renqiang CAO^1,3, Zhanli FENG², Yujiao LI^1,3, Zhijuan ZHAO^1,3, Shaoyuan SHI^1,4*

1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 2. Engineering Technology Co., Ltd., Ansteel Group Corporation, Anshan, Liaoning 114021, China3. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China4. Zhengzhou Institute of Emerging Industrial Technology, Zhengzhou, Henan 450000, China

Received:2018-09-17Revised:2018-11-30Online:2019-06-22Published:2019-06-20

摘要/Abstract

摘要： 电渗析技术应用于工业废水脱盐时，废水中有机物及其它杂质组分等会造成膜污染，进而影响脱盐性能。电渗析膜污染防治对促进电渗析在工业废水处理中的应用有重要意义。相比于阳离子交换膜，阴离子交换膜更易形成有机污染，且更严重。阴离子交换膜污染主要由腐殖酸、牛血清蛋白、阴离子表面活性剂等有机物造成，污染过程主要受静电作用、亲和作用和几何因素的影响。膜改性提高阴离子交换膜的抗污染性能是电渗析膜污染防治的有效方法，目前已有许多有关膜改性提高阴离子交换膜抗污染性能的报道。膜改性方法主要有化学改性法、等离子体改性法、表面涂覆改性法、电沉积改性法、自聚合改性法及改进基膜结构法等。本工作对阴离子交换膜改性及抗污染性能的研究进展进行了综述，对不同改性方法的优缺点进行了分析和评价。这些改性方法能提高阴膜表面的负电荷密度和亲水性、降低膜表面粗糙度和基膜含水率等，因此可以改善阴离子交换膜的抗污染性能。然而，目前研究获得的改性阴离子交换膜仍存在修饰层不稳定、抗污染性能不理想和性能测试不系统等缺点，需进一步优化改性方法、改性工艺、组分修饰及性能测试等，以获得抗污染性能稳定且效果良好的改性阴离子交换膜。

引用本文

曹仁强冯占立李玉娇赵志娟石绍渊. 阴离子交换膜改性及抗污染性能研究进展[J]. 过程工程学报, 2019, 19(3): 473-482.
Renqiang CAO Zhanli FENG Yujiao LI Zhijuan ZHAO Shaoyuan SHI. Research progress on modification and antifouling properties of anion exchange membrane[J]. Chin. J. Process Eng., 2019, 19(3): 473-482.

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