火焰法制备碳纳米管研究进展

删除或更新信息，请邮件至freekaoyan#163.com(#换成@)

本站小编 Free考研考试/2022-01-01

韩伟伟¹，汪鹏²，卫言¹，楚化强^1*，孙勇¹，曹文健¹

1. 安徽工业大学能源与环境学院，安徽马鞍山 243002 2. 安徽工业大学材料科学与工程学院，安徽马鞍山 243002

收稿日期:2018-05-07修回日期:2018-06-21出版日期:2019-02-22发布日期:2019-02-12
通讯作者:楚化强

基金资助:汽油替代燃料层流扩散火焰中PAH和碳烟生成特性研究

Progress in flame synthesis of carbon nanotubes

Weiwei HAN¹, Peng WANG², Yan WEI¹, Huaqiang CHU^1*, Yong SUN¹, Wenjian CAO¹

1. School of Energy and Environment, Anhui University of Technology, Ma'anshan, Anhui 243002, China
2. School of Materials Science and Engineering, Anhui University of Technology, Ma'anshan, Anhui 243002, China

Received:2018-05-07Revised:2018-06-21Online:2019-02-22Published:2019-02-12

摘要/Abstract

摘要： 火焰法是近20年来兴起的一种新颖、高能效、低成本的碳纳米管制备方法。火焰法能同时提供制备碳纳米管所需的碳源和热源，具有大规模制备碳纳米管的潜力。由于火焰中环境极其复杂，控制火焰中碳纳米管的合成仍是巨大的挑战。本工作介绍了碳纳米管的结构及其性能，综述了扩散火焰(同轴扩散火焰、反扩散火焰和对冲扩散火焰)和预混火焰(单面滞止火焰和双面滞止火焰)制备碳纳米管的研究进展，并对碳纳米管的vapor–liquid–solid、顶部和底部及空心和实心生长机理作了简要阐述，介绍了本课题组基于甲烷/空气同轴射流火焰制备碳纳米管的研究进展。分析表明，金属镍起催化作用，催化剂颗粒包覆在碳纳米管内部，火焰合成的碳纳米管基于vapor–liquid–solid生长机制，碳纳米管直径为50~90 nm，平均直径为65 nm。对火焰法制备碳纳米管的发展方向进行了展望。

引用本文

韩伟伟汪鹏卫言楚化强孙勇曹文健. 火焰法制备碳纳米管研究进展[J]. 过程工程学报, 2019, 19(1): 3-13.
Weiwei HAN Peng WANG Yan WEI Huaqiang CHU Yong SUN Wenjian CAO. Progress in flame synthesis of carbon nanotubes[J]. Chin. J. Process Eng., 2019, 19(1): 3-13.

使用本文

0
/ / 推荐
导出引用管理器 EndNote|Ris|BibTeX
链接本文:http://www.jproeng.com/CN/10.12034/j.issn.1009-606X.218203
http://www.jproeng.com/CN/Y2019/V19/I1/3

参考文献

[1]Kroto H W, Heath J R, O' Brien S C, et al.C60: Buckminsterfullerene[J].Nature, 1985, 318(6042):162-163 [2]Iijima S.Helical microtubules of graphitic carbon[J].Nature, 1991, 354(6348):56-58 [3]邹勇, 刘吉平, 尹作栋.碳纳米管载钴氧化物催化剂制备及其分解研究[J].过程工程学报, 2004, 4(s1):333-337 [4]Zhou Y, Liu J P, Yin Z D.Studies on Preparation of Carbon Nanotube Supported Cobalt Oxide and N2O Decomposition Reaction[J].The Chinese Journal of Process Engineering, 2004, 4(s1):333-337 [5]姚运金, 张素平, 颜涌捷.多壁碳纳米管的球磨处理对其吸附储氢性能的影响[J].过程工程学报, 2006, 6(5):837-840 [6]Yao Y J, Zhang S P, Yan Y J.Ball Milling Process and Its Effect on Hydrogen Adsorption Storage of MWNTS[J].The Chinese Journal of Process Engineering, 2006, 6(5):837-840 [7]Hughes M, Chen G Z, Shaffer M S P, et al.Electrochemical Capacitance of a Nanoporous Composite of Carbon Nanotubes and Polypyrrole[J].Chemistry of Materials, 2002, 14(4):1610-1613 [8]Rui X H, Parasuraman A, Liu W, et al.Functionalized Single-walled Carbon Nanotubes with Enhanced Electrocatalytic Activity for Br- Br3- Redox Reactions in Vanadium Bromide Redox Flow Batteries[J].Carbon, 2013, 64(9):464-471 [9] Hamzah N, Yasin M F M, Yusop M Z M, et al.Rapid Production of Carbon Nanotubes: A Review on Advancement in Growth Control and Morphology Manipulations of Flame Synthesis[J]. Journal of Materials Chemistry A, 2017.[J].Journal of Materials Chemistry A, 2017, 5:25144-25170 [10]Hutchison J L, Kiselev N A, Krinichnaya E P, et al.Double-walled Carbon Nanotubes Fabricated by a Hydrogen Arc Discharge Method[J].Carbon, 2001, 39(5):761-770 [11]Shi Z, Lian Y, Zhou X, et al.Mass-production of single-wall carbon nanotubes by arc discharge method 1[J].Carbon, 1999, 37(9):1449-1453 [12]Cassell A M, Raymakers J A, Jing K, et al.Large Scale CVD Synthesis of Single-walled Carbon Nanotubes[J].Journal of Physical Chemistry B, 1999, 103(31):397-403 [13]Yan H, Li Q, Zhang J, et al.Possible Tactics to Improve The Growth of Single-walled Carbon Nanotubes by Chemical Vapor Deposition[J].Carbon, 2002, 40(14):2693-2698 [14]Puretzky A A, Geohegan D B, Fan X, et al.Dynamics of Single-wall Carbon Nanotube Synthesis by Laser Vaporization[J].Applied Physics A, 2000, 70(2):153-160 [15]Height M J, Howard J B, Tester J W, et al.Flame Synthesis of Single-walled Carbon Nanotubes[J].Symposium on Combustion, 2004, 30(2):2537-2543 [16]Wal R L V, Ticich T M, Curtis V E.Diffusion Flame Synthesis of Single-walled Carbon Nanotubes[J].Chemical Physics Letters, 2000, 323(3):217-223 [17]于溯源, 于晓丽, 杨小勇, 等.甲烷受控扩散火焰合成碳纳米管的实验研究[J].热科学与技术, 2007, 6(4):340-345 [18]Yu S Y, Yu X L, Yang X Y, et al.Experimental Research on Synthesis of Multi-walled Carbon Nanotubes by Methane-air Controlled-diffusing Flame[J].Journal of Thermal Science and Technology, 2007, 6(4):340-345 [19]潘剑锋, 杨辉, 张倚, 等.乙炔甲烷预混燃烧合成碳纳米管的试验研究[J].热科学与技术, 2014, 13(4):365-369 [20]Pan J F, Yang H, Zhang Y, et al.Experimental Study of Carbon Nanotubes Synthesized by AcetyleneMethane Premixed Flame[J].Journal of Thermal Science and Technology, 2014, 13(4):365-369 [21]Vander Wal R L, And G M B, Hall L J.Single-Walled Carbon Nanotube Synthesis via a Multi-stage Flame Configuration[J].Journal of Physical Chemistry B, 2002, 106(14):3564-3567 [22]Vander Wal R L, Ticich T M.Curtis V ESubstrate-support interactions in metal- catalyzed carbon nanofiber growth[J].Carbon, 2001, 39(15):2277-2289 [23]Arana C P, Puri I K, Sen S.Catalyst influence on the flame synthesis of aligned carbon nanotubes and nanofibers[J].Proceedings of the Combustion Institute, 2005, 30(2):2553-2560 [24]Hu W, Yuan L, Chen Z, et al.Fabrication and characterization of vertically aligned carbon nanotubes on silicon substrates using porous alumina nanotemplates[J].J Nanosci Nanotechnol, 2002, 2(2):203-207 [25]Lee G W, Jurng J, Hwang J.Formation of Ni-catalyzed multiwalled carbon nanotubes and nanofibers on a substrate using an ethylene inverse diffusion flame[J].Combustion And Flame, 2004, 139(1–2):167-175 [26]Hou S S, Huang W C, Lin T H.Flame synthesis of carbon nanostructures using mixed fuel in oxygen-enriched environment[J].Journal of Nanoparticle Research, 2012, 14(11):1-11 [27]Merchan-Merchan W, Saveliev A V, Kennedy L A.Carbon Nanostructures in Opposed-flow Methane Oxy-flames[J].Combustion Science and Technology, 2003, 175(12):2217-2289 [28]Merchan-Merchan W, Saveliev A V, Kennedy L A.High-rate Flame Synthesis of Vertically Aligned Carbon Nanotubes Using Electric Field Control[J].Carbon, 2004, 42(3):599-608 [29]Height M J, Howard J B, Tester J W, et al.Flame Synthesis of Single-walled Carbon Nanotubes[J].Symposium on Combustion, 2004, 30(2):2537-2543 [30]Memon N K, Xu F, Sun G, et al.Flame Synthesis of Carbon Nanotubes and Few-layer Graphene on Metal-oxide Spinel Powders[J].Carbon, 2013, 63(2):478-486 [31]于晓丽, 杨小勇, 叶萍, 等.乙炔空气预混火焰法合成多壁碳纳米管的实验研究[J].工程热物理学报, 2009, 30(1):165-168 [32]Yu X L, Yang X Y, Ye P, et al.Experimental Study on Multi-walled Carbon Nanotubes Synthesized by Acetylene-air Premixed Flame[J].Journal of Engineering Thermophysics, 2009, 30(1):165-168 [33]Duan H M, Mckinnon J T.Nanoclusters Produced in Flames[J].Journal of Physical Chemistry, 1994, 98(49):12815-12818 [34]Hall B, Zhuo C, Levendis Y A, et al.Influence of The Fuel Structure on the Flame Synthesis of Carbon Nanomaterials[J].Carbon, 2011, 49(11):3412-3423 [35]Nakazawa S, Yokomori T, Mizomoto M.Flame Synthesis of Carbon Nanotubes in a Wall Stagnation Flow[J].Chemical Physics Letters, 2005, 403(1):158-162 [36]Sang K W, Hong Y T, Kwon O C.Flame Synthesis of Carbon Nanotubes Using a Double-faced Wall Stagnation Flow Burner[J].Carbon, 2009, 47(3):912-916 [37]Sang K W, Hong Y T, Kwon O C.Flame-synthesis Limits and Self-catalytic Behavior of Carbon Nanotubes Using a Double-faced Wall Stagnation Flow Burner[J].Combustion and Flame, 2009, 156(10):1983-1992 [38] Chong C T, Tan W H, Lee S L, et al.Morphology and Growth of Carbon Nanotubes Catalytically Synthesized by Premixed Hydrocarbon-rich Flames[J].Materials Chemistry & Physics, 2017, 197:246-255 [39] Hernadi K, Siska A, Thiên-Nga L, et al.Reactivity of Different Kinds of Carbon During Oxidative Purification Of Catalytically Prepared Carbon Nanotubes[J].[J].Solid State Ionics, 2001, 141-142:203-209 [40] Tan W H, Lee S L, Chong C T.TEM and XRD Analysis of Carbon Nanotubes Synthesised from Flame[J].[J].Key Engineering Materials,, 2017, 723:470-475 [41]张晓峰, 李金铃, 于溯源.燃烧法合成碳纳米管[J].过程工程学报, 2004, 4(z1):496-501 [42]Zhang X F, Li J L, Yu S Y.Flame Synthesis of Carbon Nanotubes[J].The Chinese Journal of Process Engineering, 2004, 4(z1):496-501 [43]Baker R T K, Harris P S, Thomas R B, et al.Formation of Filamentous Carbon From Iron,Cobalt and Chromium Catalyzed Decomposition of Acetylene[J].Journal of Catalysis, 1973, 30(1):86-95 [44]Baker R T K.The Formation of Filamentous Carbon[J].Carbon, 1978, 21(5):463-468 [45]Yuan L, Li T, Saito K.Growth Mechanism of Carbon Nanotubes in Methane Diffusion Flames[J].Carbon, 2003, 41(10):1889-1896 [46]Amelinckx S, Zhang X B, Bernaerts D, et al.A Formation Mechanism for Catalytically Grown Helix-shaped Graphite Nanotubes[J].Science, 1994, 265(5172):635-639 [47]Baker R T K.Catalytic Growth of Carbon Filaments[J].Carbon, 1989, 27(3):315-323 [48]Merchan-Merchan W, Saveliev A V, Kennedy L, et al.Combustion synthesis of carbon nanotubes and related nanostructures[J].Progress in Energy & Combustion Science, 2010, 36(6):696-727 [49]Pan C, Liu Y, Cao F, et al.Synthesis and Growth Mechanism of Carbon Nanotubes and Nanofibers from Ethanol Flames[J].Micron, 2004, 35(6):461-468 [50]Liu T C, Li Y Y.Synthesis of Carbon Nanocapsules and Carbon Nanotubes by an Acetylene Flame Method[J].Carbon, 2006, 44(10):2045-2050 [51]Motojima S, Chen Q.Three-dimensional Growth Mechanism of Cosmo-mimetic Carbon Microcoils Obtained by Chemical Vapor Deposition[J].Journal of Applied Physics, 1999, 85(7):3919-3921 [52]刘远超, 孙保民, 丁兆勇, 等.型热解火焰合成碳纳米管的催化剂选择与分析[J].工程热物理学报, 2009, 30(4):703-706 [53]Liu Y C, Sun B M, Ding Z Y, et al.Catalyst Selection and Analysis in V-Type Pyrolysis Flame Synthesis Carbon Nanotubes[J].Journal of Engineering Thermophysics, 2009, 30(4):703-706