北京科技大学钢铁冶金新技术国家重点实验室,北京 100083
收稿日期:
2018-01-29修回日期:
2018-04-13出版日期:
2018-12-22发布日期:
2018-12-19通讯作者:
张国华基金资助:
北京科技大学钢铁冶金新技术国家重点实验室自主研发项目Effect of Fe2O3 addition on the carbothermic reduction of titanium-bearing blast furnace slag
Kaifei WANG, Guohua ZHANG*, Lu WANG, Guozhi ZHOUUniversity of Science and Technology Beijing, State Key Laboratory of Advanced Metallurgy, Beijing 100083, China
Received:
2018-01-29Revised:
2018-04-13Online:
2018-12-22Published:
2018-12-19摘要/Abstract
摘要: 以攀枝花含钛高炉渣为原料,针对碳热还原含钛高炉渣的还原产物TiC晶粒粒径较小而难以分离的问题,在原料中添加不同比例的Fe2O3促进TiC与渣相分离. 结果表明,原料中加入Fe2O3后,还原产物中Fe在渣中呈弥散分布,渣中TiC晶粒依附Fe相生长. Fe2O3添加量为5wt%时,依附于Fe相形核长大的TiC明显沉降,富集于还原产物底部,含钛高炉渣还原产物中TiC初步富集.
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王凯飞 张国华 王璐 周国治. 添加Fe2O3对碳热还原含钛高炉渣的影响[J]. 过程工程学报, 2018, 18(6): 1276-1282.
Kaifei WANG Guohua ZHANG Lu WANG Guozhi ZHOU. Effect of Fe2O3 addition on the carbothermic reduction of titanium-bearing blast furnace slag[J]. Chin. J. Process Eng., 2018, 18(6): 1276-1282.
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参考文献
[1]VALIGHAZVINI F, RASHCHI F, NEKOUEI R K.Recovery of titanium from blast furnace slag[J].Industrial & Engineering Chemistry Research, 2013, 52(4):1723-1730 [2] 陈卓笛, 黄凯, 朱鸿民.高钛渣碳热还原-浮选法提取Ti2CO[J].有色金属(冶炼部分), 2015, (4):13-16 [3]CHEN Zhou-Di, HUANG Kai, ZHU Hong-min.Ti2CO extraction by carbothermic reduction and flotation from high grade titanium slag[J].Minerals Engineering, 2006, 19(14):1430-1438 [4]LI Chun, Liang Bin, GUO Ling-hong, Wu Zi-bin.Effect of mechanical activation on the dissolution of Panzhihua ilmenite[J].Minerals Engineering, 2006, 19(14):1430-1438 [5]邹星礼, 鲁雄刚.攀枝花含钛高炉渣直接制备钛合金[J].中国有色金属学报, 2010, 20(9):1829-1835 [6]ZOU Xing-li, LU Xiong-gang.Preparation of alloy by direct reduction of Ti-bearing blast furnace slag[J].The Chinese Journal of Nonferrous Metals, 2010, 20(9):1829-1835 [7]熊瑶, 李春, 梁斌, 谢军.盐酸浸出自然冷却含钛高炉渣[J].中国有色金属学报, 2008, 18(3):557-563 [8]XIONG Yao, LI Chun, LIANG Bin, XIE Jun.Leaching behavior of air cooled Ti-bearing blast-furnace slag in hydrochloric acid[J].The Chinese Journal of Nonferrous Metals, 2008, 18(3):557-563 [9]李玉海, 娄太平, 隋智通.含钛高炉渣中钛组分选择性富集及钙钛矿结晶行为[J].中国有色金属学报, 2000, 10(5):719-722 [10]LI Yu-hai, LOU Tai-ping, SUI Zhi-tong.Selective enrichment of Ti component in Ti-bearing blast furnace slag and precipitation behavior of perovskite phase[J].The Chinese Journal of Nonferrous Metals, 2000, 10(5):719-722 [11] COLEY K S, TERRY B S, GRIEVESON P Simultaneous reduction and carburization of ilmenite[J]. Simultaneous reduction and carburization of ilmenite[J].Metallurgical and Materials Transactions B, 1995, 26(3):485-494 [12]GOU Hai-peng.ZHANG Guo-hua,CHOU Kuo-chih. Phase evolution during the carbothermic reduction process of ilmenite concentrate[J].Metallurgical and Materials Transactions B, 2014, 46(1):48-56 [13] GUPTA S K, RAJAKUMAR V, GRIEVESON P, .Kinetics of reduction of ilmenite with graphite at 1000 to 1100℃[J].Metallurgical Transactions B, 1987, 18(4):713-718 [14] ZHEN Yu-lan, ZHANG Guo-hua, CHOU Kuo-chih., Mechanism and kinetics of the carbothermic reduction of titanium-bearing blast furnace slag[J].Metallurgical Research & Technology, 2016, 113(5):507-516 [15]高运明, 李慈颖, 李亚伟, 李远兵, 聂建华, 杨大兵.碳热还原与高炉钛渣提取碳氮化钛分析[J].武汉科技大学学报自然科学版, 2007, 30(1):5-9 [16]GAO Yun-ming, LI Ci-ying, LI Ya-wei, LI Yuan-bing, NIE Jian-hua, YANG Da-bing.Analysis of carbothermal reduction of TiO2 and extraction of titanium carbonitride from the blast furnace slag bearing titania[J].Journal of Wuhan University of Science and Technology(Natural Science Edition), 2007, 30(1):5-9 [17] 高运明, 李慈颖, 李亚伟, 杨大兵, 聂建华.高炉钛渣碳氮化实验研究[J], 安徽工业大学学报(自然科学版), 2008, 25(1): 1-4.[J].安徽工业大学学报(自然科学版), 2008, 25(1):1-4 [18]GAO Yun-ming, LI Ci-ying, LI Ya-wei, YANG Da-bing, NIE Jian-hua.Experimental study carbothermal reduction of blast furnace slag bearing titania[J].Journal of Anhui University of Technology(Natural Science), 2008, 25(1):1-4 [19] 李慈颖, 李亚伟, 高运明, 杨大兵, 李远兵, 聂建华.高钛渣提取碳氮化钛的研究[J].钢铁钒钛, 2006, (27):5-9 [20]Li Ci-ying, Li Ya-wei, Gao Yun-ming, Yang Da-bing, Li Yuan-bing, Nie Jian-hua.Research on extracting Ti(C, N) from high-titanium slag[J][J].Iron Steel Vanadium Titanium, 2006, (27):5-9 [21]ZHEN Yu-lan, ZHANG Guo-hua, CHOU Kuo-chih.Carbothermic reduction of titanium-bearing blast furnace slag[J].High Temperature Materials and Processes, 2016, 35(3):309-319 [22]ZHANG Guo-hua, CHOU Kuo-chih.Viscosity model for aluminosilicate melt[J].Journal of Mining and Metallurgy, 2012, 48(3):433-442 [23]ZHANG Guo-hua, CHOU Kuo-chih, MILLS K.Modelling viscosities of CaO-MgO-Al2O3-SiO2 molten slags[J].ISIJ International, 2012, 52(3):355-362 [24]ZHANG Guo-hua, CHOU Kuo-chih, MILLS K.A structurally based viscosity model for oxide melts[J].Metallurgical and Materials Transactions B, 2013, 45(2):698-706 [25]ZHANG Guo-hua, CHOU Kuo-chih, XUE Qing-guo, MILLS K C.Modeling viscosities of CaO-MgO-FeO-MnO-SiO2 molten slags[J].Metallurgical and Materials Transactions B, 2012, 43(1):64-72 [26]ZHANG Guo-hua, CHOU Kuo-chih, Zhang J L.Influence of TiO2 on viscosity of aluminosilicate melts[J].Ironmaking & Steelmaking, 2013, 41(1):47-50 [27]ZHEN Yu-lan, ZHANG Guo-hua, CHOU Kuo-chih.Viscosity of CaO-MgO-Al2O3-SiO2-TiO2 melts containing TiC particles[J].Metallurgical and Materials Transactions B, 2014, 46(1):155-161 [28]ZHANG Guo-hua, ZHEN Yu-lan, CHOU Kuo-chih.Influence of TiC on the Viscosity of CaO–MgO–Al2O3–SiO2–TiC Suspension System[J].ISIJ International, 2015, 55(5):922-927 |
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