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优化稀土上转换纳米材料发光的方法

本站小编 Free考研考试/2021-12-27

中文关键词:稀土 上转换 纳米粒子 发光优化 生物医用 英文关键词:Rare earth,upconversion,nanoparticles,luminescence optimization,biomedical 基金项目:国家自然科学基金项目(No.51801001;No.11747061),陕西省****青年项目,陕西省自然科学基础研究计划(No.2015JM5215),中国博士后科学基金面上项目(No.2016M601878),宝鸡市科技计划项目(No.16RKX1-29)
作者单位E-mail
徐榕宝鸡文理学院1053349180@qq.com
冯爱玲宝鸡文理学院ailing@mail.xjtu.edu.cn
王彦妮宝鸡文理学院
夏侯平宝鸡文理学院
摘要点击次数:1372 全文下载次数:0 中文摘要: 稀土上转换纳米材料(Upconversion Nanoparticles,UCNPs)可将近红外光转换为可见光,其发光性能优异、化学性质稳定、激发光能有效避免自荧光,因此在生物医学领域应用广泛。但UCNPs的低发光效率限制了其进一步发展。本文综述了近年来研究较多的几种优化稀土上转换纳米材料发光的方法,主要包括:调整基质材料和掺杂离子、过渡金属离子与镧系离子共掺杂、引入协同敏化剂减少热效应、有机染料与UCNPs协同作用以及金属表面等离子体共振增强法等。分别论述了上述方法的最新研究进展,并总结了这些方法目前存在的问题,指出上转换发光领域的研发重点:一是着重分析各种优化发光方法的作用机理,提出更加完备清晰的理论体系;二是探索更容易被生物体降解的UCNPs,使其副作用降到最低。 英文摘要: ? Rare earth upconversion nanoparticles (UCNPs), which can convert visible light into near infrared light, have excellent luminescence properties, stable chemical properties, and can avoid self-fluorescence interference. Therefore, they can be widely used in biomedical fields. However, the low luminescence efficiency of UCNPs restricts its further development. In this paper, several methods for optimizing the luminescence of rare earth upconversion nanoparticles are reviewed, including adjusting matrix and doping ions, co-doping transition metal ions with lanthanide ions, introducing the synergistic sensitizers to reduce the thermal effect, and synergistic effect of organic dyes and UCNPs, metal surface plasmon resonance enhancement method, etc. This review discusses the latest research progress of the above methods, summarizes the problems existing in these methods, and points out the research and development focus on upconversion luminescence field. One is to analyze the mechanism of various optimized luminescence methods, and put forward a more complete and clear theoretical system. The other is to explore UCNPs which are degradable by organisms, in order to minimize the side effects. 查看全文查看/发表评论下载PDF阅读器 相关附件:版权转让声明书附件1 -->
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