姓名:曹洁 职称:副教授
联系电话:010-**
电子邮箱:jcao@bit.edu.cn学科专业:质谱分析
研究方向:
质谱
结构表征
反应机理研究
手性识别
界面催化及反应质谱
色谱
色谱法分离手性化合物
纳米催化剂的可控合成及其在环境污染物去除等方面的应用
承担及作为主要学术骨干参加的科研项目:国家自然科学基金(**);教育部留学回国基金(环糊精对盐酸司来吉兰手性药物的质谱研究);教育部重点项目(手性药物分子识别的质谱研究);973计划前期研究专项(大气中持久性有机污染物的污染成因研究);中国科学院院长基金(伯胺类手性药物分子识别的质谱研究);吉林省科技发展计划项目(大气中氯苯类持久性有机污染物的污染成因和对策探讨)等。
个人概况:
1986 年、1989 年获得南开大学学士和硕士学位,2001 年获得加拿大渥太华大学博士学位。2000年 11 月至 2002 年 4 月加拿大渥太华大学从事博士后研究,2002 年 4 月回国。2004 年至 2009 年中国科学院研究生院从事手性药物色谱拆分的方法学研究及手性分子识别的质谱研究;2009 年至今北京理工大学主要从事无机-有机超分子体系结构与性能的质谱研究。讲授过《分析化学》、《现代材料分析技术》、《生命分析化学》、《分析化学实验》、《近代仪器分析》、《现代化学专题讲座》、《有机结构分析》、《有机质谱原理及应用》、《色谱和光谱实验课》、《现代色谱质谱分析方法及实验》和《有机波谱分析》等本科生和研究生课程。曾获中国科学院研究生院优良课程奖、研究生院首批集中教学突出贡献奖和 2008 年中国科学院教学成果奖二等奖。以第一作者发表 SCI 论文 26 余篇。
发表论文信息:
J. Cao*, C. Liu, Q.Q. Wang, Y.Z. Li, Q. Yu. A novel catalytic application of heteropolyacids: chemical transformation of major ginsenosides into rare ginsenosides exemplified by Rg1 . Sci. China Chem., 2017, 60 (6) : 748–753.
C. Liu, J. Cao*, Q.Q. Wang, and J.C. Zang, C.G. Ci*. Effect of vanadium valence state on the solution chemistry and the stability of vanadium substituted polyoxometalates. RSC Adv., 2016, 110922-110927.
J. Cao*, C. Liu and Q.D. Jia. Complex solution chemistry behind the simple “one-pot” synthesis of vanadium-substituted polyoxometalates unraveled by electrospray ionization mass spectrometry. Rapid Commun. Mass Spectrom., 2016, 30 (Suppl. 1), 14-19.
L.Y. Fan, Y.Y. Hong, J. Cao* and C.W. Hu*. Investigation into the mechanism of polyoxotungstates-catalyzed cyclooctene epoxidation by ESI-MS. RSC Adv., 2016, 6, 56656-56660.
J. Cao*, C. Xu, C. Liu, W.Q. Liu. Cation-anion interactions and synergistic catalysis by supramolecular polyoxometalate complexes [C10 H18 N]n [XM12 O40 ]. ChemistrySelect, 2016, 6, 1268-1272.
L.Y. Fan?, Z.G. Lin?, J. Cao* and C.W. Hu*. Probing the self-Assembly mechanism of Lanthanide-containing sandwich-Type silicotungstates [{Ln(H2 O)n }2 {Mn4 (B-α-SiW9 O34 )2 (H2 O)2 }]6– using time-resolved mass spectrometry and X-ray crystallography. Inorg. Chem., 2016, 55 (6), 2900-2908 (?Equal contribution).
L.Y. Fan, J. Cao* and C.W. Hu*. What Can Electrospray Mass Spectrometry of Paratungstates in An Equilibrating Mixture Tell us? RSC Adv., 2015, 5, 83377-83382.
Y.X. Fan, Y. Zhang, Q.D. Jia, J. Cao*, W.J. Wu*. The stabilizing role of cyclodextrins on Keggin phosphotungstic acid by complexation unveiled by electrospray mass spectrometry. Mass Spectrom. Lett., 2015, 6(1), 13-16.
Q.D. Jia, Y. Zhang, J. Cao*. Characterization of polyoxometalates by electrospray ionization mass spectrometry. Sci. China Chem., 2015, 58(7), 1206-1210.
Q.D. Jia, J. Cao*, Y.P. Duan and C.W. Hu*. The solution chemistry and reactivity of lacunary Keggin silicotungstates monitored in real-time by a combination of mass spectrometry and electrochemistry. Dalton Trans., 2015, 44, 553-559.
J. Cao*, C. Xu, Y.X. Fan, L.Y. Fan, X.H. Zhang* and C.W. Hu. Selective production of electrostatically-bound adducts of alkyl cations/polyoxoanions by the collision induced fragmentations of their quaternary ammonium counterparts. J. Am. Soc. Mass Spectrom., 2013, 24, 884-894.
J. Cao*, C.C Li, Z.X. Zhang, C. Xu, J. Yan, F.Y. Cui, C.W. Hu*. Intriguing role of a quaternary ammonium cation in the dissociation chemistry of Keggin polyoxometalate anions. J. Am. Soc. Mass Spectrom., 2012, 23, 366-374.
X.F. Wang?, J. Cao?, K.L. Huang, Y.Q. Xu, Y.N. Chi*, C.W. Hu*. A novel 3D coordination polymer from [HW7 O24 ]5– stabilized by copper(II)-complex and sodium sations: structure, solid-state stability and aqueous solution behavior. Eur. J. Inorg. Chem., 2013, 1788-1792 (?Equal contribution).
J. Cao*, R.F Xu, H. Tang, S.S. Tang, M.H. Cao*. Synthesis of monodispersed CMC-stabilized Fe–Cu bimetal nanoparticles for in situ reductive dechlorination of 1, 2, 4-trichlorobenzene. Sci. Total Environ., 2011, 409, 2336-2341.
X.M. Hu, Q. Chen, D. Zhou, J. Cao*, Y.J. He*, B.H. Han*. One-step preparation of fluorescent inorganic–organic hybrid material used for explosive sensing. Polym. Chem., 2011, 2, 1124-1128.
X.M. Hu, Q. Chen, J.X. Wang, Q.Y. Cheng, C.G. Yan, J. Cao*, Y.J. He*, B.H. Han*. Tetraphenylethylene-based glycoconjugate as a fluorescence “turn-on” sensor for cholera toxin. Chem. Asian J., 2011, 6, 2376-2381.
Q. Chen, Y. Cui, T.L. Zhang, J. Cao*, B.H. Han*. Fluorescent conjugated polyfluorene with pendant lactopyranosyl ligands for studies of Ca2+-mediated carbohydrate-carbohydrate interaction. Biomacromolecules, 2010, 11, 13-19.
Q. Yu, J. Cao*, T. Liu, Z.X. Wang*. Fluorescence-quenching of tryptophan ion-18-crown-6 complex. A different observation from its neutral counterpart. Chem. Res. Chinese U., 2009, 25(3), 362-367.
Q. Yu, J. Cao*, G. Lu, Z.X. Wang*. The role of central ion in the chiral recognition by taking phenylalanine as an example. Sci. China Chem., 2009, 52(8), 1136-1141.
徐冲, 范艳璇, 范琳媛, 曹洁 *, 胡长文*. 质谱在多金属氧簇化学中的应用. 化学进展, 2013, 25(5), 809-820.