@qq.com
国家****科学基金获得者，国家百千****才工程人选者并获得“有突出贡献中青年专家”荣誉称号，中国科学院“引进国外杰出人才（****）”
研究员
天然气水合物物性和分解机理的研究

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“天然气水合物目标预测、开采和应用关键技术”之子课题“天然气水合物开采关键技术”

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水合物技术IGCC合成气中CO2分离及H2提纯的研究

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沉积物中天然气水合物分解过程的多相流动及传热传质机制的研究

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水合物法IGCC合成气中CO2连续分离工艺研究
一种可视化气体水合物实验装置

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一种天然气水合物三维实验装置

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一种气体水合物取样分析方法及装置

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一种气体水合物取样分析装置

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天然气水合物三维多井联合开采实验装置

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一种二氧化碳置换开采天然气水合物模拟方法及实验装置

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一种天然气水合物地质分层模拟实验装置

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一种天然气水合物三维生成开采物性检测实验装置

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冻土区天然气水合物开采方法与装置

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一种基于气体溶剂的气体水合物耦合促进剂及其应用
本发明公开了一种可视化气体水合物实验装置，包括可视化水合物反应器、稳流供气、供液系统、温度控制系统、稳压排气系统、取样分析系统和数据采集与处理系统。本发明的可视化气体水合物实验装置，利用分布器产生微气泡，增大了气液接触面积，增加了气体溶解度，缩短诱导时间提高水合物形成速率，克服了现有实验装置容积小、气泡行程短的弊端，使气泡在上浮的过程中就形成水合物，省却了气体循环设备。可用于多组分混合气体水合物形成/分解动力学、水合物晶体结构、形貌测定的实验装置。

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本发明公开了一种天然气水合物三维多井联合开采实验方法和装置，可以模拟多井联合开采水合物；适用于各种大小的三维反应釜；可以让三维水合物物理模拟装置由受局限的实验室尺度，放大到无限大地层上去。本发明涉及天然气开采过程中开采井的布置以及实验方法，可以为天然气水合物开采提供依据。

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本发明是涉及一种气体水合物取样分析方法及装置，尤其应用于水合物体系中的气相、水溶液相、水合物浆相、水合物相的取样以及多组分混合气体水合物体系各相组分、水的转化率、水合物相气水比、水合物储气量等关键参数的测试和分析。

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本取样分析方法及装置的最大特点是取样器是可运动的，可对釜内任何高度的样品进行任意体积取样。特别是可对水合物浆相进行压缩直接获得水合物相样品，解决了对水合物相取样分析的难题。可应用于水合物体系中的气相、水溶液相、水合物浆相、水合物相的取样以及多组分混合气体水合物体系各相组分、水的转化率、水合物相气水比、水合物储气量等关键参数的测定与分析。该方法及装置操作方便、结果真实可靠、用途广泛、成本低廉。

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本发明公开了一种天然气水合物三维多井联合开采实验方法和装置，可以模拟多井联合开采水合物；适用于各种大小的三维反应釜；可以让三维水合物物理模拟装置由受局限的实验室尺度，放大到无限大地层上去。本发明涉及天然气开采过程中开采井的布置以及实验方法，可以为天然气水合物开采提供依据。

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发明了一种二氧化碳置换开采天然气水合物的实验装置和方法，可真实地模拟外部环境，进行二氧化碳置换天然气水合物模拟开采，可以为天然气水合物的二氧化碳置换开采提供核心技术。

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本发明公开了一种天然气水合物地质分层模拟实验装置，包括三维模型，模拟腔，筒体，上法兰，下法兰，螺栓，半渗透隔板等。本装置可以利用不同种类的半渗透隔板层，实现对实际海底或者冻土带地层内天然气水合物藏地质分层情况的模拟，包括实际天然气水合物藏中上盖层、水合物层、水合物层下部游离气层或者含水层以及下盖层等。

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本发明可真实地再现天然气水合物生成开采过程中的压力、温度、饱和度等物理性质的变化，并对其进行分析，同时本发明所述测试装置可以对已出现的水合物生成分解数学模型进行验证，实现理论与实践的统一。

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本发明提出了一种井下原位燃烧加热与降压联合开采冻土区天然气水合物的方法。该方法包括抽水降压系统、井下原位燃烧加热系统、气体收集系统及控制系统。该开采方法的步骤如下：采用深井泵将水合物分解水抽至地面降低天然气水合物层的压力，同时向天然气水合物储层注入氧气或空气，通过电子点火装置点燃天然气水合物或天然气水合物分解气燃烧加热分解开采冻土区天然气水合物，水合物分解气通过气体采出管收集，加热和开采速率通过监测开采井压力，调节氧气或空气注入速率来控制。

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本发明涉及一种气体水合物耦合促进剂。本发明提供了一种可同时极大的降低水合物生成条件、加速水合物生成速率、提高水合物储气量的气体水合物耦合促进剂。
Raman Spectroscopic Analysis on the Hydrate Formed in the Hydrate-Based Flue Gas Separation Process in Presence of Sulfur Dio

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Production behaviors and heat transfer characteristics of methane hydrate dissociation by depressurization in conjunction wit

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Raman analysis on methane production from natural gas hydrate by carbon dioxide–methane replacement

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Evaluation of gas production from Qilian Mountain permafrost hydrate deposits in two-spot horizontal well system

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Phase equilibrium and dissociation Enthalpies of trimethylene sulfide+methane hydrates in brine water systems

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The use of heat-assisted antigravity drainage method in the two horizontal wells in gas production from the Qilian Mountain

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Depressurization induced gas production from hydrate deposits with low gas saturation in a pilot-scale hydrate simulator

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Experimental study on the hydrate dissociation in porous media by five-spot thermal huff and puff method

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Experimental Investigation into Scaling Models of Methane Hydrate Reservoir

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Equilibrium Hydrate Formation Conditions of CO2 + N2 + SO2 Ternary Simulated Flue Gas in SO2 and Tetra？n？butylammonium Bromid

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Study on Pilot-Scale CO2 Separation from Flue Gas by the Hydrate Method

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Preparation of Warm Brine in Situ Seafloor Based on the Hydrate Process for Marine Gas Hydrate Thermal Stimulation

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Replacement of CH4 in Hydrate in Porous Sediments with Liquid CO2 Injection

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Experimental Investigation into Gas Hydrate Formation in Sediments with Cooling Method in Three-Dimensional Simulator

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Research progress of hydrate-based CO2 separation and capture from gas mixtures

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Molecular dynamics simulation of the intercalation behaviors of methane hydrate in montmorillonite

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Kinetic Behaviors of Methane Hydrate Formation in Porous Media in Different Hydrate Deposits

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Numerical Investigation of Hydrate Dissociation Performance in the South China Sea with Different Horizontal Well Configurati

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Methane Hydrate Dissociation using Inverted Five-Spot Water Flooding Method in Cubic Hydrate Simulator

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Kinetic Studies of Methane Hydrate Formation in Porous Media Based on Experiments in a Pilot-Scale Hydrate Simulator and a

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Experimental investigation into methane hydrate production during three-dimensional thermal stimulation with five-spot well

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Similarity Analysis in Scaling a Gas Hydrates Reservoir

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Molecular dynamics simulation of methane hydrate dissociation by depressurization

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Effects of Impermeable Boundaries on Gas Production from Hydrate Accumulations in the Shenhu Area of the South China Sea

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The use of dual horizontal wells in gas production from hydrate accumulations

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Experimental Investigation into Factors Influencing Methane Hydrate Formation and a Novel Method for Hydrate Formation in Por

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Phase Equilibrium and Dissociation Enthalpies for Hydrates of Various Water-Insoluble Organic Promoters with Methane

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Evolution of Hydrate Dissociation by Warm Brine Stimulation Combined Depressurization in the South China Sea

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CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide)

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Experimental study on gas production from methane hydrate in porous media by SAGD method

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A three-dimensional study on methane hydrate decomposition with different methods using five-spot well

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Numerical Simulation of Gas Production Potential from Permafrost Hydrate Deposits by Huff and Puff Method in a Single Horizon

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Gas Production from Methane Hydrate in Pilot-Scale Hydrate Simulator using Huff and Puff Method by Experimental and Numerical

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Experimental Study on Methane Hydrate Dissociation by Depressurization in Porous Sediments

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Experimental and numerical studies on gas production from methane hydrate in porous media by depressurization in pilot-scale

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Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble meth

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Integrated process study on hydrate-based carbon dioxide separation from integrated gasification combined cycle (IGCC) synthe

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Hydrate-based Methane Separation from the Drainage Coal-bed Methane with Tetrahydrofuran Solution in the Presence of Sodium D

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Experimental investigation into gas production from methane hydrate in sediment by depressurization in a novel pilot-scale hy

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Numerical Simulation of Gas Production from Natural Gas Hydrate Using a Single Horizontal Well by Depressurization in Qilian

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Experimental Investigations into Gas Production Behaviors from Methane Hydrate with Different Methods in a Cubic Hydrate Sim

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Synergic effect of cyclopentane and tetra-n-butyl ammonium bromide on hydrate-based carbon dioxide separation from fuel gas

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Experimental study on gas production from methane hydrate in porous media by huff and puff method in Pilot-Scale Hydrate Simu

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Effects of Tetrabutyl-(ammonium/phosphonium) Salts on Clathrate Hydrate Capture of CO2 from Simulated Flue Gas

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Experimental Investigation of the Formation of Cyclopentane-Methane Hydrate in a Novel and Large-Size Bubble Column Reactor

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Hydrate-based carbon dioxide capture from simulated integrated gasification combined cycle gas

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Thermodynamic Equilibrium Conditions for Simulated Landfill Gas Hydrate Formation in Aqueous Solutions of Additives

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Experimental Investigation into Methane Hydrate Production during Three-Dimensional Thermal Huff and Puff