xinf@tju.edu.cn
化工工程
未公开
教授
绿色低碳导向的高效炼油过程基础研究（子课题）

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甲醇制聚甲氧基二甲醚高效催化转化关键问题研究

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10万吨年轻汽油醚化工业化成套技术开发

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加氢反应器设计

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催化烟气脱硝反应器设计

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微通道非均相反应器数量放大效应与操作稳定性的研究

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超细钛硅分子筛环己酮浆态氨肟化反应动力学分析

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狭窄通道对液液固三相催化氨肟化过程的影响及模型化描述

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光催化还原二氧化碳的反应体系设计及其机理研究

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仿光合作用的甲酸甲酯合成及其耦合光催化的研究

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均苯三甲酸中试技术服务

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燕化气体裂解炉烧焦过程模拟

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TDI生产自有技术研发

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齐鲁烯烃厂乙烯装置标定

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烯烃厂丙烯精馏塔改造技术服务

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纤维多孔材料孔隙内物料输运模拟计算与优化控制研究

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疏水微通道反应器强化氢-水同位素催化交换的动力学研究

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生产国Ⅵ柴油的RTS+工艺技术开发及模型研究

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二氧化碳仿光合作用制有机酯的催化剂体系及反应机理研究
一种可见光光催化剂Bi2O3/TiO2的制备方法

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树枝状钛硅分子筛膜及制备方法

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套筒分布式气相光气化反应器及用于合成异氰酸酯的方法

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油包水乳液相变换热的气体水合物制备方法

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直接相变换热的气体水合物制备方法及装置

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一种环流反应器及用之合成均苯三甲酸的方法

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直接相变换热的气体水合物制备方法及装置

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变流向烟气催化还原脱硝反应器及脱硝方法

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油包水气体水合物的制备

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本发明涉及直接相变换热水合方法及装置，首先是制取液态相变材料与水的乳液，并使之在水的凝固点之上，冷却成为含相变材料固体颗粒的浆液；随后，将制得的浆液送入水合器，与通入的小分子气体充分接触，完成水合。利用固体熔化时吸热的特性，将熔化热与水合热相匹配，采用直接相变换热方式，移走水合过程中产生的热量。适用于气体分离和储存。装置包括分散机（7），容器（5），加压泵（3），换热器（2），水合器（1），调节阀（6）；本发明设计的水合器，温度变化可以保持在1℃以内。由于水合器内的温升被抑制，水合速率明显提高。

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本发明涉及一种环流反应器及用之合成均苯三甲酸的方法。该反应器包括环管段和直筒段两部分；环管段和直筒段相互连通，在环管段处设置有加热器和冷却器；环管段底部设置有气液初始分布器，气液初始分布器与物料进口连接；在直筒段中上部设置有出料口，在直筒段上端连接有冷凝器。用此反应器，非均相条件下氧化合成均苯三甲酸。合成的均三甲苯的转化率大于99%，以均三甲苯计的均苯三甲酸质量收率为135～155%，尾气中氧含量小于6%。本发明公开的外循环氧化反应装置内无机械传动装置，结构简单。

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本发明涉及油包水乳液相变换热的气体水合物制备方法。按照原料组成配料，通过高速剪切机或分散设备，形成乳液；乳液中油相的凝固点应低于水的凝固点温度；采用冷却的方式使乳液降温，达到乳液中的水部分或全部凝固成冰以后，维持温度恒定；由此形成的含冰浆液与小分子气体充分接触，进行水合。本发明利用水合过程中冰的熔化可以及时、有效地移走水合热，在不额外引入冷却介质的情况下，保持了水合温度的均匀与稳定，从而提高水合物生成速率。

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本发明涉及变流向烟气催化还原脱硝反应器及脱硝方法。反应器包括第一段催化剂床层、第二段催化剂床层和第三段催化剂床层，在第一段催化剂床层和第二段催化剂床层上设置有流向控制通道，通过两个开关门和的同步调节，控制气体流向；同时，组合了流体倒向区和灰尘捕集与还原剂辅助加入区。采用分段固定床的反应器型式，通过改变反应器入口烟气的流向，从而改善反应期内的温度分布，使低浓度的烟气组分在更均匀且更高的还原温度下进行催化反应。不仅能使各段催化剂床层的催化活性得以充分发挥，还能提高烟气脱硝的效率。
Photocatalytic reduction of CO2 in methanol to methyl formate over CuO-TiO2 composite catalysts

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Fabrication of nano copper oxide evenly patched on cubic sodium tantalate for oriented photocatalytic reduction of carbon dio

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Synthesis of dendritic TS-1 film on honeycomb cordierite

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Synthesis, characterization, and activities of visible light-driven Bi2O3-TiO2 composite photocatalysts

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Simulation and Optimization of Coil Decoking in Ethane Pyrolysis Furnace

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Numerical Study on Bubble Formation of a Gas-Liquid Flow in a T-Junction Microchannel

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Hydrothermal synthesis of TS-1 film with mixed templates on cordierite support

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Coke deposition and characterization on titanium silicalite-1 catalyst in cyclohexanone ammoximation

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Kinetic study on photocatalytic degradation of 4BS Azo dye over TiO2 in slurry

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In situ calcinations of precursors of mesoporous AlPO4 and application of mesoporous Mn-AlPO4

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Shape-controlled solvothermal synthesis of Bi2S3 for photocatalytic reduction of CO2 to methyl formate in methanol

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Synthesis of hexagonal and cubic ZnIn2S4 nanosheets for the photocatalytic reduction of CO2 with methanol

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A facile method for the fabrication of b-oriented TS-1 film on the surface of glass modified by TS-1 precursor solution

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Hydrothermal crystallization of b-oriented TS-1 films on PVAc-modified glass

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Density functional theory studies on hydroxylamine mechanism of cyclohexanone ammoximation on titanium silicalite-1 catalyst

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Photocatalytically reducing CO2 to methyl formate in methanol over ZnS and Ni-doped ZnS photocatalysts

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Density functional theory studies on hydroxylamine mechanism of cyclohexanone ammoximation on titanium silicalite-1 catalyst

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A quantum chemical and molecular dynamic study on cyclohexanone ammoximation over TS-1

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Uniformity of gas and liquid two phases flowing through two microchannels in parallel

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Storage Capacity and Duration of Methane Hydration in a Slurry of Solid n-Tetradecane

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Modeling of Monolithic Catalyst Washcoated with TS-1 and Reactor for Continuous Cyclohexanone Ammoximation Reaction

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Photocatalytic reduction of carbon dioxide over ZnFe2O4/TiO2 nanobelts heterostructure in cyclohexanol

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Experiments and modeling on bubble uniformity of Taylor flow in T-junction microchannel

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Synthesis of hexagonal and cubic ZnIn2S4 nanosheets for the photocatalytic reduction of CO2 with methanol

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Synthesis, characterization of hierarchical TS-1 and its catalytic performance for cyclohexanone ammoximation

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Continuous Heterogeneous Cyclohexanone Ammoximation Reaction in Monolithic TS-1/Cordierite Catalyst

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Photocatalytic Reduction of CO2 in Cyclohexanol on CdS-TiO2 Heterostructured Photocatalyst

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Simulation and Optimization on Etherification of Light Gasoline in a Process of Two Fixed-Bed Reactors and One Distillation C

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Zonal description and quantitative methodology of air-water distribution in comb-like microchannels

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Synthesis of hexagonal and cubic ZnIn2S4 nanosheets for the photocatalytic reduction of CO2 with methanol

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Trajectory Modeling of Gas-Liquid Flow in Microchannels with Stochastic Differential Equation and Optical Measurement

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Intensification and kinetics of methane hydrate formation under heat removal by phase change of n-tetradecane

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Nonlinear time-series analysis of optical signals to identify multiphase flow behavior in microchannels

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Selective photocatalytic reduction of CO2 to methanol in CuO-loaded NaTaO3 nanocubes in isopropanol

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相变浆液中甲烷水合物的生成过程强化

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ZnFe2O4 deposited on BiOCl with exposed (001) and (010) facets for photocatalytic reduction of CO2 in cyclohexanol

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Distinguishing and Prediction Periodic and Chaotic Multiphase Flow in T-Junction Microchannel Obtained from Optical Time-Seri

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Block copolymer-assisted synthesis of monodisperse colloidal patchy nanoparticles

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Block copolymer as surface modifier to monodisperse patchy silica nanoparticles for superhydrophobic surfaces

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Preparation and evaluation of titanium silicalite-1 utilizing pretreated titanium dioxide as a titanium source