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上海交通大学材料科学与工程学院硕士课程内容介绍《金属凝固原理》

上海交通大学 免费考研网/2012-12-28


《金属凝固原理》

课程代码X050527学分/学时3.0/48开课时间
课程名称金属凝固原理
开课学院材料科学与工程学院
任课教师张佼
面向专业
预修课程
课程讨论时数0 (小时)课程实验数0 (小时)
课程内容简介

本课程介绍了现代材料科学与工程中,围绕材料性能展开的材料成分、微观组织、热加工历史对材料性能产生影响的基本规律及控制机理。重点介绍材料熔体微结构与材料性能之间的关联关系,凝固过程中溶质分配及微观组织的演变与材料性能之间的对应关系。为学生建立起一个系统的熔体-凝固过程-固相有机结合的凝固组织演变体系,正确理解凝固过程中出现的各种基本现象及理论原理,为凝固理论在材料制备过程中的应用奠定基础。基本内容: 本课程从熔体微观结构出发,介绍熔体结构的表征及变化规律,不同合金元素、不同影响因素下熔体结构变化对凝固组织的影响;熔体中团簇结构演变过程,晶核形成及与熔体界面的能量变化对形核长大的影响过程;不同合金凝固过程中的溶质分布与晶体形貌的演化;不同晶体形态的生长机制;凝固过程中溶质分布规律及析出相;微观凝固组织的演变与控制;原理在晶粒细化与提纯过程中的应用。

课程内容简介(英文)

This course provides an introduction to modern materials science and engineering, which has as its central theme how the properties of a material, its microstructure, its processing history, and its performance are inherently interrelated. We shall focus on developing an understanding of melt- microstructure -properties relationships that are very important. Properties are greatly affected by solidification, and microstructure is affected by the processing and composition. I want you to develop an understanding of various fundamental concepts of crystal structures, melt structure, defects forming mechanism, diffusion at the liquid/Solid interface, phase diagrams, and learn how to apply these to the major classes of materials.Abstract: The basic concepts and theories during solidification, as well as structure of melt and crystal are emphasized in courses. The fundamentals of nucleation, growth and microstructure control are introduced in lecture. Some experiments and discusion are planned to carry out according to the application of those fundamentals refered in course.

教学大纲

TOPICS AND READING ASSIGNMENTS:1. Preface and overview 2h1.1 What solidification is ConceptionImportance of solidification (in nature and industry)Conditions for solidification For instance: Water - Ice - Snow 1.2 Essential factors of solidification process Temperature, composition, physical characteristic 1.3 Essential factors of Microstructure Grain size,Morphology,precipitated phase2. Melt structure and characteristics 2h2.1 Experimental ConsiderationChange in volume on meltingLatent heat of meltingEntropy of melting Diffraction studies of liquid structureTransport properties2.2 Theories of Liquid StructureCondensation theoriesLattice theoriesGeometrical theoriesNew development2.3 Synchrotron radiation SAXS and XRD3. Nucleation 4h3.1 Thermodynamic AspectsConditions for NucleationHomogeneous nucleation Rate of nucleation3.2 Nucleation agent heterogeneous nucleation3.3 Interface structureTiB2-Al interfaceNucleation ability4. Growth 4h4.1 Nucleus growth Influencing factorsGrowth by surface nucleationGrowth on imperfections5. Morphological instability of a Solid/Liquid interface Interface instability of pure substanceSolute pile-up at a Planar solid/liquid interface6. Solidification Microstructure: Cells and Dendrites 6h6.1 Constrained and unconstrained growth6.2 Morphology and crystallography of dendrites6.3 Diffusion field at the tip of needle-like crystal6.4 Operating point of the needle crystal - tip radius6.5 Growth style evolution of dendrite 6.6 Primary spacing of dendrites after directional growth6.7 Columnar- Equiaxed transition7. Solidification Microstructure: Hypoeutectic, hypereutectic, Eutectic, Peritectic 6h7.1 Regular and irregular eutectics 7.2 Diffusion - coupled growth7.3 Competitive growth of dendrite and eutectic7.4 Synchrotron radiation imaging8. Solute Redistribution 6h 8.1 Mass-balance in directional solidification8.2 The solute distribution in directional solidification: solid solute and multi-phases alloy8.3 Characterization of segregation Utilization of segregation9. The Structure of casting 6h9.1 Macrostructure9.2 The chill zone9.3 The columnar zone9.4 The equiaxed zone9.5 Theories of the development of the equiaxed zone9.6 Refinement of solidification structure10.Summary Application of fundamentals Discussion: 1 Melt structure and solidification microstructure 2 Methods for refinement Experiment Supercooling in solidificationInterface instability of alloyPerturbation analysis

课程进度计划

1 前言和概述1.1 什么是凝固 - 概念 ;- 凝固的重要性; - 凝固的条件1.2 凝固过程基本参数 - 温度,成分,物性1.3 微观结构的基本参数 - 晶粒,形貌,析出相2 熔体结构和表征2.1 实验上的考虑 - 融化过程中的体积变化,熔解潜热,熔化熵,熔体结构的衍射研究2.2 熔体结构理论 - 凝结理论,晶格理论,几何结构理论,新发展2.3 同步辐射小角散射和XRD分析熔体结构3 形核3.1 热力学方面 - 形核条件,均质形核,形核率,3.2 形核剂 - 异质形核3.3 界面结构 - 形核能力,典型的TiB2-Al界面结构分析4 晶体生长4.1 晶核长大 - 影响参数,表面形核的长大,缺陷处的长大5 固液界面的形貌不稳定性 - 纯物质生长界面的不稳定性,平界面前沿溶质富集,合金生长过程中的界面不稳定性,扰动分析6 凝固微观组织: 胞状晶和枝晶 6.1 受迫生长和非受迫生长 6.2 枝晶的生长形貌 6.3 枝晶尖端的溶质扩散 6.4 枝晶尖端半径对生长的影响 6.5 枝晶形貌演变 6.6 定向凝固过程中一次枝晶间距 6.7 柱状-等轴转变 (CET)7 凝固微观组织:亚共晶,过共晶,共晶,包晶 7.1 规则和不规则共晶 7.2 扩散耦合生长 7.3 枝晶和共晶的竞争生长 7.4 同步辐射成像实验 8 溶质分配8.1 定向凝固过程中的物质平衡8.2 定向凝固过程中的溶质分布8.3 微观偏析特性和偏析的应用9 铸件结构9.1 宏观组织9.2 激冷区9.3 柱状晶区9.4 等轴晶区9.5 等轴晶区发展理论9.6 凝固组织细化10 总结 - 基本原理的应用 讨论: 1 熔体结构与凝固微观组织 2 组织细化方法 实验: 凝固过程中的过冷

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