陈志敏


1、 基本信息
姓名：陈志敏
职称：长聘教轨副教授 博士生导师
邮箱：chenzhimin221@sjtu.edu.cn
电话：
主页：scce.sjtu.edu.cn
通讯地址：上海市东川路800号上海交通大学建工楼322A室，邮编:200240

欢迎热爱有机合成化学的青年学子加入课题组，共同学习、成长！
2、 教育经历
2005-2009 福州大学，理学学士
2009-2014 兰州大学，理学博士，专业：有机化学，导师：涂永强院士
3、 工作经历
2014.7-2017.11 上海交通大学，专职科研博士后，合作导师：涂永强院士
2015.7-2017.8 美国犹他大学，博士后，导师：Prof. Matthew S. Sigman
2017.12 -至今 上海交通大学化学化工学院，长聘教轨副教授
4、 研究方向
1）不对称催化反应（有机小分子、过渡金属）
2）新型氟试剂及硫试剂的设计、合成及应用
3）有机电化学合成方法学的研究及其在天然产物全合成中的应用
5、 教育教学
本科生：《大学化学》
研究生：《现代有机合成》


6、 荣誉奖励
2019 上海市高等学校****计划
2018 上海交通大学博士后奖励基金 二等奖
2013 博士研究生国家奖学金
2012 博士研究生国家奖学金
2012 唐敖庆化学奖学金
2012 第五届“翰宇奖学金”

7、近期发表论文
2020：

1.Xu-Feng Song, Tong-Mei Ding, Deng Zhu, Jie Huang, Zhi-Min Chen*
Lewis-Acid-Mediated Intramolecular Tri?uoromethylthiolation of Alkenes with Phenols: Access to SCF3?Containing Chromane and Dihydrobenzofuran Compounds
Org. Lett. 2020, 22, 7052-7056.

2.Deng Zhu, Tong-Mei Ding, Hui-Yun Luo, Hua Ke, Zhi-MinChen*
Divergent Synthesis of Trifluoromethyl Sulfoxides and β-SCF₃ Carbonyl Compounds by TandemTrifluoromethylthiolation/Rearrangement of Allylic and Propargylic Alcohols
Org. Lett. 2020,22, 7699-7703.


3. Chao-ChaoXi, Xiao-Jing Zhao, Jin-Miao Tian*, Zhi-Min Chen*, Kun Zhang,Fu-Min Zhang, Yong-Qiang Tu*, and Jia-Wei Dong
AtroposelectiveSynthesis of Axially Chiral 3-Arylindoles by Copper-Catalyzed AsymmetricCross-Coupling of Indoles with Quinones and Naphthoquinones
Org. Lett. 2020, 22, 4995-5000.


2019：
1. Yu-Yang Xie, Zhi-Min Chen,* Hui-Yun Luo, HuiShao, Yong-Qiang Tu,* Xiaoguang Bao,* Ren-Fei Cao, Shu-Yu Zhang, Jin-Miao Tian
Lewis Base/Br?nsted Acid Cocatalyzed EnantioselectiveSulfenylation/Semipinacol Rearrangement of Di- and Trisubstituted AllylicAlcohols
Angew. Chem. Int. Ed.2019,58, 12491-12496.
Featured by Benjamin List, Joyce A. A. Grimm in SYNFACTS 2019, 15, 1175.

2. Hui-Yun Luo, Jia-Wei Dong, Yu-Yang Xie, Xu-Feng Song, Deng Zhu,Tongmei Ding, Yuanyuan Liu,* Zhi-Min Chen *
Lewis Base/Br?nsted Acid Co-catalyzed Asymmetric Thiolation ofAlkenes with Acid-Controlled Divergent Regioselectivity
Chem. Eur. J. 2019, 25, 15411-15418.

3. Hui-Yun Luo, Yu-Yang Xie, Xu-Feng Song, Jia-Wei Dong, Deng Zhu, Zhi-Min Chen *
Lewis base-catalyzed asymmetric sulfenylation of alkenes:construction of sulfenylated lactones and application to the formal syntheses of(-)-nicotlactone B and (-)-galbacin
Chem. Commun., 2019,55, 9367-9370.

4. Ai-Hui Ye, Ye Zhang, Yu-Yang Xie, Hui-Yun Luo, Jia-Wei Dong,Xiao-Dong Liu, Xu-Feng Song, Tongmei Ding, Zhi-Min Chen*
TMSCl-Catalyzed Electrophilic Thiocyano Oxyfunctionalization ofAlkenes Using N-Thiocyano-dibenzenesulfonimide
Org. Lett., 2019, 21, 5106-5110.

5. Xu-Feng Song,^? Ai-Hui Ye,^? Yu-Yang Xie,Jia-Wei Dong, Chao Chen, Ye Zhang,* Zhi-Min Chen* (^?equalcontribution)
Lewis Acid Mediated Thiocyano Semipinacol Rearrangement of Allylic Alcohols for the Construction of α-Quaternary Center β-Thiocyano Carbonyls
Org. Lett., 2019, 21, 9550-9554.

6. Zhi-Min Chen^?, Jianbo Liu^?,Jing-Yao Guo, Maximilian Loch, Ryan Deluca, Matthew S. Sigman* (^?equalcontribution)
Palladium-catalyzed enantioselective alkenylation ofalkenylbenzene derivatives
Chemical Science, 2019, 10, 7246-7250

7. Chao Chen, Jun-Chen Kang, Chen Mao, Jia-Wei Dong, Yu-Yang Xie,Tong-Mei Ding, Yong-Qiang Tu, Zhi-Min Chen*, Shu-Yu Zhang*
Electrochemical Halogenation/Semi-pinacol Rearrangement of AllylicAlcohols Using Inorganic Halide Salt: An Eco-friendly Route to Synthesis ofβ-halocarbonyls
Green Chemistry, 2019, 21, 4014-4019.(Inside front cover)

8. Jun-Chen Kang, Yong-Qiang Tu, Jia-Wei Dong, Chao Chen, JiaZhou, Tong-Mei Ding, Jian-Tao Zai, Zhi-Min Chen*, Shu-YuZhang*.
Electrochemical semipinacol rearrangements of allylic alcohols:construction of all-carbon quaternary stereocenters.
Org. Lett., 2019, 21, 2536–2540. (Most downloaded)



2018：

1. Jia‐Wei Dong,Tongmei Ding, Shu‐Yu Zhang*, Zhi‐Min Chen*, Yong‐Qiang Tu*.
A Facile Approachto Oximes and Ethers by a Tandem NO⁺‐Initiated SemipinacolRearrangement and H‐Elimination.
Angew. Chem. Int.Ed.2018, 57, 13192-13196.

2. Chao-Chao Xi, Zhi-MinChen*, Shu-Yu Zhang, Yong-Qiang Tu*.
ElectrophilicTrifluoromethylthiolation/Semipinacol Rearrangement: Preparation of β-SCF₃ Carbonyl Compounds with α-Quaternary Carbon Center.
Org. Lett., 2018, 20,4227–4230.



感谢国家自然科学面上基金、青年基金、上海市教委及上海交通大学经费支持！

Prior to SJTU:
1. Zhi-Min Chen, Christine S. Nervig, Ryan J. DeLuca, and Matthew S. Sigman*. Palladium-catalyzed enantioselective redox-relay Heck alkynylation of alkenols to access propargylic stereocenters
Angew. Chem. Int. Ed. 2017, 56, 6651-6654.

2. Zhi-Min Chen, Margaret J. Hilton, and Matthew S. Sigman*.
Palladium-catalyzed enantioselective redox-relay Heck arylation of 1,1-disubstituted homoallylic alcohols
J. Am. Chem. Soc. 2016, 138, 11461-11464.

3. Zhi-Min Chen,? Xiao-Ming Zhang?, and Yong-Qiang Tu* (?equal contribution). Radical aryl migration reactions and synthetic applications
Chem. Soc. Rev. 2015, 44, 5220-5245.

4. Zhi-Min Chen, Zhen Zhang, Yong-Qiang Tu,* Ming-Hui Xu, Fu-Min Zhang, Chen-Chen Li, and Shao-Hua Wang*.
A Mn(III)/TEMPO-co-mediated tandem azidation/1,2-carbon migration reaction of allylic silyl ethers
Chem. Commun. 2014, 50, 10805-10808.

5. Zhi-Min Chen, Wei Bai, Shao-Hua Wang, Bin-Miao Yang, Yong-Qiang Tu,* and Fu-Min Zhang.
Copper-catalyzed tandem trifluoromethylation/semipinacol rearrangement of allylic alcohols
Angew. Chem. Int. Ed. 2013, 52, 9781-9785.

6. Zhi-Min Chen, Bin-Miao Yang, Zhi-Hua Chen, Qing-Wei Zhang, Min Wang, and Yong-Qiang Tu*.
Organocatalytic asymmetric fluorination/semipinacol rearrangement: An efficient approach to chiral β-fluoroketones
Chem. Eur. J. 2012, 18, 12950-12954.

7. Zhi-Min Chen, Qing-Wei Zhang, Zhi-Hua Chen, Hui Li, Yong-Qiang Tu,* Fu-Min Zhang, and Jin-Miao Tian.
Organocatalytic asymmetric halogenation/semipinacol rearrangement: highly efficient synthesis of chiral α-oxa-quaternary β-haloketones
J. Am. Chem. Soc. 2011, 133, 8818-8821.

8、 其他
热诚欢迎对1）不对称催化；2）过渡金属催化；3）天然产物合成等方向感兴趣的本科生、硕士生、博士生和博士后加入本课题组。申请者请将个人简历及研究简介发到chenzhimin221@sjtu.edu.cn。