外文题目: Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties
作者: Zhang, Jinfang; Jia, Ding; Humphrey, Mark G.; Meng, Suci; Zaworotko, Michael J.; Cifuentes, Marie P.; Zhang, Chi
刊名: Chem. Commun.
年: 2016 卷: 52 期: 19 页： 3797--3800
英文关键词:

NONLINEAR-OPTICAL PROPERTIES; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; HETEROTHIOMETALLIC CLUSTERS; CHEMICAL SENSORS; SOLID-STATE; DESIGN; LIGANDS; SURFACE; UNITS
英文摘要:
An ammonium-crown ether host-guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster-metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3](+) with different connection environments, pentanuclear clusters [WS4Cu4](2+), and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components.


文献类型: 期刊论文
正文语种: English
收录类别: SCI
DOI: 10.1039/c5cc10076c


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