摘要/Abstract
![](http://sioc-journal.cn/Jwk_hxxb/fileup/0567-7351/PIC/20211108153143.jpg)
近年来, 随着绿色化学和可持续发展等创新理念的提出, 无金属催化剂逐渐成为催化领域的研究热点和前沿. 石墨烯作为一种新型纳米碳材料, 具有机械强度大、比表面积高、稳定性好、电学性质优异等特点, 经过改性或功能化后的衍生物可以作为无金属碳基催化剂, 在有机反应中展现了良好的应用前景. 本文综述了石墨烯衍生物的结构和性质, 探究了石墨烯基材料的结构与催化活性之间的关系, 总结了此类材料作为无金属催化剂在氧化、还原/氢化、偶联、取代反应以及其他有机反应中的应用和反应机理.
关键词: 石墨烯, 石墨烯衍生材料, 碳基催化剂, 有机反应, 无金属催化, 催化机理
The rise in global demand for green chemistry and sustainable development have driven immense research in the fundamental science of catalysis. Metal-free catalysis, serves as an ideal industrial technology, has emerged as a new frontier and hot point in modern catalysis science due to its green and sustainable properties. As a new carbonaceous material, graphene exhibits high surface area, excellent stability, unique mechanical and electronic properties. Its physical and chemical properties can be further modulated by modification and functionalization. Graphene derivatives have been successfully employed in a variety of chemical transformations recently, showing them to be promising metal-free organocatalysts. This review highlights the recent advancements of graphene-derived materials as metal-free carbocatalysts and their application in organic reactions, such as oxidation, reduction or hydrogenation, coupling, substitution, etc. The possible structure-performance relationships of graphene-based carbocatalysts and metal-free organocatalytic mechanisms are also emphasized.
Key words: graphene, graphene-derived material, carbocatalyst, organic reaction, metal-free catalysis, catalytic mechanism
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