摘要/Abstract
利用可见光照射和过氧化叔丁醇作氧化剂的条件，发展了N-芳基苯丙炔胺和磺酰肼类化合物的自由基环化-氧化芳构化反应.该反应提供了一种合成3-磺酰基喹啉衍生物的有效方法，显示出较好的官能团适用性、底物普适性以及很好的化学与区位选择性.
关键词: 可见光, 磺酰肼, 3-磺酰基喹啉衍生物, 区位选择性
A visible-light-induced oxidative cyclization of N-propargylanilines with arylsulfonylhydrazides was developed using tert-butyl hydroperoxide as oxidant. This transformation offers a straightforward route to 3-sulfonated quinoline derivatives with good functional group tolerance, good to excellent yields and high regio-selectivity.
Key words: visible-light, arylsulfonylhydrazides, 3-sulfonated quinoline derivatives, regio-selectivity
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