摘要/Abstract

含有氢键供体基团构筑的大环化合物因其结构中具有可以提供氢键供体的N—H基团，可以为大环化合物的主客体化学提供额外的分子间作用力，在分子识别、自组装以及超分子催化等领域被广泛应用.综述了近十年基于（硫）脲键、酰胺键构筑的大环化合物的合成方法及其在分子识别中的最新研究进展.为今后此类大环化合物的合成及应用提供参考.
关键词: 氢键供体基团, 大环化合物, 合成, 分子识别
Because of the N-H group structure in the macrocyclic compound containing hydrogen bond Donors, it can provide additional intermolecular forces in the host-guest chemistry, and this character is widely used in the molecular recognition, self-assembly, supramolecular catalysis and other fields. The recent progress on the synthetic methods of macrocyclic compounds based on (thio) urea, amide and its molecular recognition in 2010~2019 are summarized. It is hoped that this review can be referred to synthesis and applications of this kind of macrocyclic compounds.
Key words: hydrogen bond donor group, macrocyclic compounds, synthesis, molecular recognition


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