摘要/Abstract

N-错位卟啉既是卟啉的同分异构体又是异卟啉的典型代表，也是一类非常重要的卟啉类化合物.因其独特的化学结构及反应活性，近年来引起化学工作者的广泛关注.介绍了N-错位卟啉研究的意义、N-错位卟啉的结构和性质.重点综述了N-错位卟啉的合成及其在催化化学、生物化学和材料化学领域的应用进展.同时对N-错位扩展卟啉和其它错位异卟啉的发展现状作了简要概述，并对N-错位卟啉化学的发展进行了展望.
关键词: 异卟啉, N-错位卟啉, 合成, 应用, 研究进展, 扩展卟啉
N-Confused porphyrin, as the typical representative of porphyrinoids, is an isomer of porphyrin. It is an important member of porphyrins, which has attracted extensive attention of chemists recently because of its unique chemical structure and reactivity. Significance, structures and properties of N-confused porphyrins are briefly introduced. Progress in the synthesis of N-confused porphyrins and their applications in the area of catalytic chemistry, biological chemistry and materials chemistry are reviewed emphatically. The development status of expanded N-confused porphyrins and other confused porphyrinoids are also briefly introduced. Further development of N-confused porphyrin chemisty is proposed in the end.
Key words: porphyrinoids, N-confused porphyrin, synthesis, application, research progress, expanded porphyrin


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