摘要/Abstract

近年来，具有独特反应性、选择性、易得性和稳定性的联烯胺类化合物受到化学工作者们的关注，尤其是关于联烯胺环化反应的报道与日俱增.总结归纳了涉及过渡金属催化的联烯胺环化反应，主要分为钯、钌、铑、金、钴、银、铂、镍八部分介绍，并详细讨论了多数转化的反应机理.
关键词: 联烯胺, 环化反应, 杂环化合物, 过渡金属催化
With the especial reactivity, selectivity, availability and stability, the allenamides have got more and more attention, and the reports on allenamides cyclization grow rapidly. This review gives an up-to-date overview of transition-metal-catalyzed allenamides cyclization, which are sorted by metal catalysts in eight categories of Pd, Ru, Rh, Au, Co, Ag, Pt and Ni. For most of these transformations, the plausible mechanisms are demonstrated in details. Clarification of these issues is the key point for understanding the transition-metal-catalyzed allenamides cyclization and developing new high performance methodologies for chemists.
Key words: allenamides, cyclization, heterocyclic compounds, transition metal catalysis


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