删除或更新信息,请邮件至freekaoyan#163.com(#换成@)

可见光催化的丙炔酸酯三氟乙基化反应合成香豆素类似物

本站小编 Free考研考试/2022-02-14

摘要/Abstract



可见光催化下以三氟碘乙烷为三氟乙基试剂,实现了丙炔酸酯的三氟乙基化,合成了三氟乙基取代的香豆素类似物.反应条件温和,后处理方便,环境友好,底物适用范围广泛.
关键词: 光催化, 丙炔酸酯, 三氟乙基化
A practical strategy has been described for the preparation of trifluoroethyl-coumarin derivatives using a visible-light-promoted trifluoroethylation reaction of propiolate with trifluoroethyl iodide. These reactions could be carried out at room temperature in good chemical yields with good functional group tolerance.
Key words: photocatalyst, propiolate, trifluoroethylation


PDF全文下载地址:

点我下载PDF
相关话题/乙基 乙烷 光催化 可见光 适用范围