摘要/Abstract

报道了一类无金属参与、操作简单的合成方法来制备非对称的1，1'-二芳基-2，2'-二胺化合物.与已知的三步合成法比较，该策略将2-萘酚与芳基肼反应，不需要使用过渡金属催化剂和配体，具有操作简单、一步合成的优点.
关键词: 1,1'-二芳基-2,2'-二胺, 2-萘酚, 肼, 合成方法
A metal-free, operationally simple synthetic protocol for the buildup of unsymmetric 1, 1'-biaryl-2, 2'-diamine compounds was reported. This reaction was performed by the treatment of 2-naphthols with aryl hydrazines under no transition metal catalyst and no ligand conditions, which has the advantages of simple operation and one-step synthesis.
Key words: 1,1'-biaryl-2,2'-diamine, 2-naphthol, hydrazine, synthetic methodology


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