摘要/Abstract

有机膦化合物在有机反应、光电材料、阻燃材料以及药物化学等研究领域都具有广泛的用途，因而探索更高效、更绿色的方法实现有机膦化合物的合成是有机膦化学工作者的主要目标之一.通过磷自由基与不饱和化合物的双官能团化反应可以在一步反应中实现含磷杂环以及多环化合物的构建.按磷自由基引发方式的不同，对近年来磷自由基与不饱和化合物的双官能团化反应的研究进展进行了综述.
关键词: 磷自由基, 双官能团化, 不饱和化合物
The scientists have been working on developing more efficient and green ways to synthesize organophosphorus compounds as they have broad utilities such as reagents for chemical reactions, photovoltaic materials, flame retardants, biologically active molecules and so on. The difunctionalization reactions between P-center radicals and unsaturated compounds provide powerful methods for the synthesis of organophosphorus compounds in least and concise steps. This review will summarize the recent development in this area on the basis of different types of P-centered radical initiators.
Key words: phosphorus-centered radical, difunctionalization, unsaturated compounds


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