姓名：赵蓓
职称：教授、博士生导师
部门：化学学院
联系方式：
Tel: 86- (Lab)
Fax: 86- (O.)
Email:zhaobei@suda.edu.cn

课题组网站
学历及学术经历：1992年苏州大学化学教育专业本科毕业，1995年苏州大学有机化学专业毕业，获硕士学位，期间赴南开大学做访问****1年。1995年留校工作至今，2006年获有机化学博士学位。
主持国家自然科学基金2项，江苏省高校自然科学研究项目1项，参加2项国家自然科学基金项目和1项省部级项目。在国内外化学核心期刊如Green Chem., Org. Lett., Org. Chem. Front., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等发表论文数十篇，授权发明专利4项。2009年度获江苏省科学技术进步奖二等奖，2010年获得中国石油和化学工业协会科学技术进步奖一等奖。2011年获得江苏政府留学基金资助出国访学。
主要教学成果：
副主编《有机化学实验》（高教出版社），参编《有机化学》（高教出版社）、《有机化学演示实验（音像）》（高教出版社）、《有机化学实验》（南京大学出版社）和《有机硫化学》等教材5部。2000年和2009年两次获得苏州大学利苏奖教金，2006年获得江苏省高校第三届多媒体课件制作大赛三等奖，2012年获得江苏省优秀毕业设计团队奖，2015年获得江苏省高校微课教学本科组三等奖，2015年获苏州大学交行教学奖。2005年主持并完成《有机化学（一）》双语课程建设，2007年起主要承担《有机化学》校精品课程建设，2015和2016年分别主持苏州大学3I工程《有机化学》和《有机化学实验》微课程建设。



研究领域：稀土金属有机化合物的合成、结构及其催化性质，导向有机合成的金属有机化学，不对称合成等。
Representative Publications:
1. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides
L. J. Hu,C. R. Lu,B. Zhao*, Y. M. Yao
Org. Chem. Front., 2018, DOI: 10.1039/C7QO00991G

2. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction
C. Gong, H. Ding, C. R. Lu, B. Zhao*, Y. M. Yao
Dalton Trans., 2017, 46, 6031-6038.

3. Efficient asymmetric hydrophosphonylation of unsaturated amides catalyzed by rare-earth metal amides [(Me₃Si)₂N]₃RE(m-Cl)Li(THF)₃with phenoxy-functionalized chiral prolinols
Z. H. Fei, C. Zeng, C. R. Lu,B. Zhao*, Y. M. Yao
RSC Adv. 2017,7, 19306-19311.

4.Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions
B. Zhao,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao
Dalton Trans.2016, 45, 3880-3887.

5. Asymmetric michael addition of malonates to unsaturated ketones catalyzed by rare earth metal complexes bearing phenoxy functionalized chiral diphenylprolinolate ligands
Q. Q. Qian, W. G. Zhu, C. R. Lu, B. Zhao*, Y. M. Yao
Tetrahedron: Asy. 2016, 27, 911-917.

6. Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from CO₂and 2-aminobenzonitriles
Q. Y. Wang,C. R.Lu,B. Zhao*, Y. M.Yao
Eur. J. Org. Chem., 2016, 2555-2559.

7. Carboxylation of terminal alkynes with CO₂catalyzed by bis(amidate) rare-earth metal amides
H. Cheng, B. Zhao,* Y. M. Yao, C. R. Lu
Green Chem.,2015, 17, 1675-1682.

8. Highly enantioselective epoxidation of α,β-unsaturated ketones catalyzed by rare-earth amides [(Me₃Si)₂N]₃RE(μ-Cl)Li(THF)₃with phenoxy-functionalized chiral prolinols
C. Zeng, D. Yuan, B. Zhao,* Y. M. Yao
Org. Lett., 2015, 17, 2242-2245.

9. Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides
H. Cheng, Y. Xiao, C. R. Lu, B. Zhao,* Y. R. Wang, Y. M. Yao
New J. Chem.,2015, 39, 7667-7671.

10. Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide
Y. Cui, W. K. Gu, Y. R. Wang,* B. Zhao,* Y. M. Yao, Q. Shen
Catal. Sci. Technol.,2015, 5, 3302-3312.

11. Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-b-butyrolactone
T. H. Zeng, Q. Q. Qian, B. Zhao,* D. Yuan, Y. M. Yao*, Q. Shen
RSC Adv. 2015,5, 53161-53171.

12.C-N bond formation reaction catalyzed by Organo-rare-earth metal amides (Invited Review)
Y. Xiao, Q. Y. Wang, B. Zhao*, Y. M. Yao*
Chin. J. Org. Chem. 2015, 35, 1598-1614.

13. Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand
Q. Q. Qian, Y. F. Tan, B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*
Org. Lett., 2014, 16, 4516-4519.

14. Synthesis and characterization of amidate rare-earth metal amides and their catalyticactivities towardhydrophosphonylation of aldehydes and unactivated ketones
L. Zhao, H. Ding, B. Zhao,* C. R. Lu, Y. M. Yao
Polyhedron, 2014, 83, 50-59.

15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes with a-carbonyl esters catalyzed by an indium(III)-PyBox complex
B. Zhao, T. P. Loh
Org. Lett.,2013, 15, 2914-2917.

16. Unexpected C?H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene bridged bis(β-diketiminate) ligand
S. Sun, Q. Sun, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*
Organometallics, 2013, 32, 1876-1881.

17. Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides
S.Sun, K. Nie, Y. F. Tan, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*
Dalton Trans., 2013,42, 2870-2878.

18.Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization of rac-lactide
X.L. Hu, C. R. Lu, B. Wu, H. Ding, B. Zhao*, Y. M. Yao*, Q. Shen
J. Organomet. Chem., 2013, 732, 92-101.

19.Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones
H. Ding, C. R. Lu, X. L. Hu, B. Zhao*, B. Wu, Y. M. Yao*
Synlett, 2013, 24, 1269-1274.

20. Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex
B. Zhao, X. L. Hu, C. R. Lu
J. Appl. Polym. Sci., 2011, 120, 2693.

21. One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation
C. R. Lu, B. Zhao*, Y. P. Jiang, H. Ding, S. Yang
Syn. Commun.,2011, 41, 1257.

22.Ring-opening polymerization of trimethylenecarbonate and its copolymerization with e-caprolactone by lanthanide (II) aryloxide complexes
B. Zhao, C. R. Lu, Q. Shen
J. Appl. Polym. Sci., 2007, 106, 1383.

23. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ₂-p-(Me₃SiN)₂C₆H₄}YbCl(THF)₂]₂and [{μ₂-p-(Me₃SiN)₂C₆H₄}Nd(μ₂-Cl)(THF)]₄?2PhMe
B. Zhao, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu
Organometallics,2006, 25, 1824.

24. Polymerization of N-phenyl maleimide by lanthanide complexes
B. Zhao, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng
J.Polym. Sci. Polym. Chem.,2005, 43, 3966.