诸海滨
教授 化学化工学院
联系电话：** 办公时间：
传 真： 主页网址：
办公地点：化学化工楼 电子邮箱：zhuhaibin@seu.edu.cn
通讯地址：东南大学九龙湖校区












研究方向



基础研究方向
1.功能性MOF基材料的设计合成，结构和性能研究（荧光探针，有机催化以及导电等）
2.用于电化学反应（ORR，OER，HER,CO2RR等）的MOF衍生的碳基纳米电催化剂的设计
3.有机电合成方法的研究


应用开发方向
1.药物及其中间体的合成工艺优化研究
2.药物杂质的分离，分析，定向合成和结构确证
3.手性药物及其中间体的不对称合成方法研究



特别提醒：
本课题组可同时招收学术型硕士和工程硕士，学术型博士和工程博士。欢迎各位有志青年报考加入我课题组，共谋发展！
联系方式：zhuhaibin@seu.edu.cn





荣誉奖励






学术成果


基础研究：2007年以来先后主持完成两项国家自然科学基金项目（1.“多孔导电配位聚合物的设计，合成和性能调控” 国家自然科学基金面上项目 （2012.1-2015.12）2. "金属-含硫类联吡啶分子构筑体的研究”国家自然科学青年基金项目 （2009.1-2011.12）），参与多项省部级项目。目前的研究兴趣主要集中于功能性MOF基材料以及MOF衍生的碳基纳米电催化剂方面的研究。


应用开发:目前主要集中（1）药物杂质对照品的分离，分析和定向合成；（2）药物及其关键中间体的工艺优化和开发。自2011年开始先后为合作企业完成了十多个药物近六十多个杂质对照品的定向合成，包括苯达莫斯汀，阿加曲班对映异构体，培美曲赛，氟达拉滨，右雷佐生，雷贝拉唑，奥美拉唑等等；完成数个医药公司委托API合成工作，完成了利伐沙班等多个药物关键中间体的中试放大工艺研究。


文章和专利
“Boosting the oxygen reduction performance of MOF-5-derived Fe-N-C electrocatalysts via a dual strategy of cation-exchange and guest-encapsulation"
Jia-Wei Huang, Yu-Bin Chen, Jing-Meng Yang, Hai-Bin Zhu *, Hui Yang *
Electrochimica Acta, 2021,366,137408.
"Exploring efficient Fe/N/C electrocatalysts for oxygen reduction from noneporous interpenetrated metal-organic framework involving in-situ formation of ZnO templates
Jia-Wei Huang, Yu-Bin Chen, Xiang-Lan Chen, Xiao Liu, Lu-Shan Ma, Wan-Yu Su, Yue Zhao*, Hai-Bin Zhu *,Hui Yang*
ACS Sustainable Chemistry & Engineering,2020,8,3208-3217.
"ZIF-derived Bifunctional Cu@Cu-N-C Composite Electrocatalysts towards Efficient Electroreduction of Oxygen and Carbon Dioxide"
Xiang-Lan Chen, Lu-Shan Ma, Wan-Yu Su,Lin-Fei Ding*, Hai-Bin Zhu*, Hui Yang*
Electrochimica Acta,2020,331，135273.
"Cu dopant triggering remarkable enhancement in activity and durability of Fe-N-C electrocatalysts toward oxygen reduction"
Xiang-Lan Chen, Hai-Bin Zhu *, Lin-Fei Ding *
Journal of Electroanalytical Chemistry, 2020, 873,114389.
"Fabrication of Mn,N-codped carbon electrocatalysts from a cationic Cd(II)-based MOF involving anion-exchange with MnO4- anions"
Jie Yuan, Li Xiao, Gao-Yuan Huang, Jin-Meng Yang, Hai-Bin Zhu *
ChemNanoMat 2020, 6,1776-1781.
"Construction of efficient Mn-N-C oxygen reduciton electrocatalyst from a Mn(II)-based MOF with N-rich organic linker"
Li Xiao, Jin-Meng Yang, Gao-Yuan Huang, Yue Zhao *,Hai-Bin Zhu *
Inorganic Chemistry Communications 2020, 118,107982.
”Significance of the porosity of luminescent metal-organic frameworks for sensitive sensing of metal cations"
Hai-Bin Zhu *， Li Xiao， Yu-Feng Yang，
Inorganic Chemistry Communications 2020，112，117760.

Anion-exchange of a Cationic Cd(II)-based Metal-Organic Framework with Potassium Ferriccyanide towards Highly Active Fe3C-containing Fe/N/C Catalysts for Oxygen Reduction"
Jia-Wei Huang, Yu-Bin Chen, Xiao Li, Yi-Chen Huang, Ye-Lin Ding, Yang Xu, Hong-Chang Yao,
Hai-Bin Zhu*, Hui Yang*
Chemical Communications 2019,55,6930-6933.

Highly Efficient Fe-N-C Electrocatalysts for Oxygen Reduction Derived from Core-Shell-Structured Fe(OH)3@Zeolitic Imidazolate Framework"
Jia-Wei Huang, Qing-Qing Cheng,Yi-Che Huang, Hong-Chang Yao, Hai-Bin Zhu *, Hui Yang*
ACS Appl. Energy Mater.2019,2,3194-3203.

"Efficient Fe-Co-N-C electrocatalyst towards oxygen reduction derived from a cationic Co(II)-based metal-organic framework modified by anion-exchange with potassium ferricyanide"
Xiang-Lan Chen, Jia-Wei Huang, Yi-Chen Huang, Jie Du, Yu-Fei Jiang, Yue Zhao*, Hai-Bin Zhu*
Chem-Asian J.2019, 14，995-1003.

"A Robust polyoxometalate-templated four-fold interpenerating metal-organic framework showing efficint organic dye degradation in various pH aqueous solutions"
Min Liu, Xu-Feng Yang, Hai-Bin Zhu*，Bao-Sheng Di, Yue Zhao*
Dalton Trans.2018,47,5245-5251.

Syntheses,structures and magnetic properties of two Cu(II)-based coordination polymers involving a crystal-to-crystal structural transformation from a 1D chain to a 3D network"

Xu-Feng Yang,Min Liu, Hai-Bin Zhu*, Cheng Hang, Yue Zhao*
Dalton Trans.2017,46,17025-17031.

Construction of noninterpenetrating and interpenetrating (4-fold and 8-fold) 3-D Cd(II) networks with tris(1,2,4-triazol-4-yl)phenyl)amine modulated by aromatic dicarboxylate coligands"

Yu Shen, Cong-Cong Fan, Yu-Zhen, Wei, Jie Du, Hai-Bin Zhu*, Yue Zhao*
Crystal Growth & Design, 2016,16,5859-5868.

An anionic zeolite-like metal-organic framework （AZMOF）with a Moravia network for organic dye absorption through cation-exchange"
Yu Shen, Cong-Cong Fan, Yu-Zhen, Wei, Jie Du, Hai-Bin Zhu*, Yue Zhao*
Dalton Trans.2016, 45, 10909.

"Construction of a metal-organic framework by octuple intercatenation of discrete icosahedral coordination cages"
Yu Shen，Hai-Bin Zhu*，Jun Hu，Yue Zhao*
CrystEngComm, 2015, 17, 2080-2082.

"A unique 3D metal-organic framework based on 12-connected pentanuclear Cd(II) cluster exhibit proton conduction"
Yu Shen, Xu-Feng Yang Hai-Bin Zhu*，Yue Zhao*，Wei-Si Li
Dalton Trans. 2015, 44, 14741-14746.

"Unprecedented metal-mediated in situ reactions of heterocyclic disulfide of di[4-(pyridin-2-yl)pyrimidinyl]disulfide"
??????????Hai-Bin Zhu*,Yan-Fang Wu, Yue Zhao*,Jun Hu
Dalton Trans, 2014, 43, 17156-17162.

Quasi-planar Organic Synthon and S...X (X = S or H-C)Contacts in Flat Coordination Chains: Syntheses, Structures and Conductive Behaviors"

Hai-Bin Zhu*, Ru-Yu Shan, Yan-Fang, Wu, Yong-Bing, Lou*
Eur. J. Inorg. Chem.2014, 1356-1363.

"Semiconductive tetrahedral M4L4 coordination cages (M = Ni2+ and Co2+) constructed by a rigid conjugated tris(N,N-chelate) tripod"

Hai-Bin Zhu*, Yan-Fang Wu, Yong-Bing Lou*, Jun Hu
Synth. Metal2014,190, 34-38.