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Raman scattering study of magnetic layered MPS3 crystals (M = Mn, Fe, Ni)

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Raman scattering study of magnetic layered MPS3 crystals (M = Mn, Fe, Ni)
文献类型:期刊
通讯作者:Zhang, QM (reprint author), Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China.; Zhang, QM (reprint author), Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China.
期刊名称:CHINESE PHYSICS B影响因子和分区
年:2019
卷:28
期:5
ISSN:1674-1056
关键词:Raman scattering; two-dimensional magnetic van der Waals materials; lattice dynamics; magnetism
所属部门:物理学系
摘要:We report a comprehensive Raman scattering study on layered MPS3 (M = Mn, Fe, Ni), a two-dimensional magnetic compound with weak van der Waals interlayer coupling. The observed Raman phonon modes have been well assigned by the combination of first-principles calculations and the polarization-resolved spectra. Careful symmetry analysis on the angle-dependent spectra demonstrates that the crystal symmetry is strictly described by C-2h but can be simplified to D-3d with good accuracy. Interestingly ...More
We report a comprehensive Raman scattering study on layered MPS3 (M = Mn, Fe, Ni), a two-dimensional magnetic compound with weak van der Waals interlayer coupling. The observed Raman phonon modes have been well assigned by the combination of first-principles calculations and the polarization-resolved spectra. Careful symmetry analysis on the angle-dependent spectra demonstrates that the crystal symmetry is strictly described by C-2h but can be simplified to D-3d with good accuracy. Interestingly, the three compounds share exactly the same lattice structure but show distinct magnetic structures. This provides us with a unique opportunity to study the effect of different magnetic orders on lattice dynamics in MPS3. Our results reveal that the in-plane Neel antiferromagnetic (AF) order in MnPS3 favors a spin-phonon coupling compared to the in-plane zig-zag AF in NiPS3 and FePS3. We have discussed the mechanism in terms of the folding of magnetic Brillouin zones. Our results provide insights into the relation between lattice dynamics and magnetism in the layered MPX3 (M = transition metal, X = S, Se) family and shed light on the magnetism of monolayer MPX(3 )materials. ...Hide

DOI:10.1088/1674-1056/28/5/056301
百度学术:Raman scattering study of magnetic layered MPS3 crystals (M = Mn, Fe, Ni)
语言:外文
人气指数:5
浏览次数:5
基金:Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2016YFA0300504, 2017YFA0302904]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [11474357, 11774419]; Fundamental Research Funds for the Central Universities, ChinaFundamental Research Funds for the Central Universities; Research Funds of Renmin University of China [14XNLQ03]
作者其他论文



Electronic structures of quasi-one-dimensional cuprate superconductors Ba2CuO3+delta.Liu, Kai, Lu, Zhong-Yi, Xiang, Tao,.PHYSICAL REVIEW MATERIALS. 2019, 3(4).
Phonon anomalies and magnetic excitations in BaFe2Se2O.Jin, Feng, Lazarevic, Nenad, Liu, Changle, et al. .PHYSICAL REVIEW B. 2019, 99(14).
Ferromagnetic van der Waals Crystal VI3.Tian, Shangjie, Zhang, Jian-Feng, Li, Chenghe, et al. .JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2019, 141(13), 5326-5333.
Incidence and severity of sexual dysfunction among women with breast cancer: a meta-analysis based on female sexual function index.Jing, Liwei, Zhang, Chao, Li, Wei, et al. .SUPPORTIVE CARE IN CANCER. 2019, 27(4), 1171-1180.
Shubnikov-de Haas and de Haas-van Alphen oscillations in the topological semimetal CaAl4.Xu, Sheng, Zhang, Jian-Feng, Wang, Yi-Yan, et al. .PHYSICAL REVIEW B. 2019, 99(11).

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