中文关键词甲醛(HCHO)垂直分布垂直柱浓度广州塔珠三角(PRD) 英文关键词formaldehyde(HCHO)vertical distributionvertical columnCanton TowerPearl River Delta (PRD)

作者	单位	E-mail
黄山	暨南大学环境与气候研究院, 粤港澳环境质量协同创新联合实验室, 广州 511443	shanhuang_eci@jnu.edu.cn
裴成磊	广州市环境监测中心站, 广州 510030
张莹	中国科学院空天信息创新研究院, 遥感科学国家重点实验室, 北京 100094
宋奇聪	暨南大学环境与气候研究院, 粤港澳环境质量协同创新联合实验室, 广州 511443
齐吉朋	暨南大学环境与气候研究院, 粤港澳环境质量协同创新联合实验室, 广州 511443
赵一鸣	暨南大学环境与气候研究院, 粤港澳环境质量协同创新联合实验室, 广州 511443
王鸣	南京信息工程大学环境科学与工程学院, 江苏省大气环境与装备技术协同创新中心, 南京 210044
邵敏	暨南大学环境与气候研究院, 粤港澳环境质量协同创新联合实验室, 广州 511443

中文摘要 为探究珠江三角洲城区大气甲醛的垂直分布特征，本研究首次在广州塔上3个不同高度点开展了甲醛的同步观测.在2018年秋季连续32 d使用2，4-二硝基苯肼（DNPH）法采集午间1 h甲醛样品，并通过高效液相色谱（HPLC）进行分析.结果表明，广州塔地面、118 m点和488 m点的甲醛浓度均值分别为（5.10±1.93）、（6.61±2.84）和（5.33±2.55）μg·m^-3.3个高度观测点的甲醛浓度均与大气氧化剂O_x存在正相关性（R为0.65~0.75），表明光化学过程是广州市城区甲醛的重要来源.甲醛垂直浓度廓线依据分布形状分为3类，出现频率最高的一类为上下低中间高，发生在边界层对流较为温和、光化学反应活跃的状态下，中高层（118 m）可能受到来自较远处的工业高架源传输影响.根据垂直浓度梯度估算出广州塔点的甲醛垂直柱浓度均值为（11.23±4.80）×10¹⁵ molecules·cm^-2，比同期卫星提供的甲醛柱浓度低19%，和已有报道值数量级一致. 英文摘要 To investigate the vertical distribution of atmospheric formaldehyde in the Pearl River Delta (PRD) urban area, simultaneous measurements were performed at three heights on Canton Tower for the first time. Carbonyls including formaldehyde were sampled with 2,4-dinitrophenylhydrazin (DNPH) at noon for 32 days in autumn of 2018, and then analyzed using high-performance liquid chromatography (HPLC). Average mass concentrations of formaldehyde at ground level, 118 m, and 488 m sites at Canton Tower were (5.10±1.93), (6.61±2.84), and (5.33±2.55) μg·m^-3, respectively. The measured formaldehyde was positively correlated with atmospheric oxidant O_x at the three sites (R 0.65-0.75), indicating that photochemical formation is an important source for urban formaldehyde in PRD. Three different profiles were found for formaldehyde vertical distribution during the measurements. The most frequently observed one showed a higher value at 118 m while lower ones at ground level and 488 m, occurring when the boundary layer is in moderate convection state with high photochemical reactivity. The 118 m layer may be also influenced by transported high-chimney emissions from industries in suburban areas. Vertical columns of formaldehyde were also calculated according to its vertical profile. The average value was (11.23±4.80)×10¹⁵ molecules·cm^-2, 19% lower than that from satellite retrieval, while in the same magnitude as values reported in reference papers.

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