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N-杂环卡宾配体在聚合反应中的研究进展

本站小编 Free考研考试/2021-12-27

中文关键词:N-杂环卡宾金属配合物催化剂聚合反应 英文关键词:N-heterocyclic carbeneMetal complex catalystsPolymerization 基金项目:国家科技重大专项(2016ZX05021004-002)和中石化科技部项目(PE19001、P18001-2、P17002-8)资助
作者单位
孔勇中国石化石油工程技术研究院 北京 100101
摘要点击次数:815 全文下载次数:0 中文摘要: N-杂环卡宾(NHC)配体的优异催化性能引起了人们的广泛关注,已成功应用于多种烯烃聚合反应。本文主要介绍NHC及其在开环易位聚合、烯烃配位聚合和原子转移自由基聚合等反应中的应用。在此基础上,指出了今后NHC配体在聚合反应研究的发展方向。 英文摘要: N-heterocyclic carbene ligands have attracted extensive attention due to their excellent catalytic performance, and have been widely utilized in a variety of olefin polymerization reactions. According to the recent reports, N-heterocyclic carbene were briefly introduced, firstly. The recent research advances of the application in ring-opening metathesis polymerization, olefin coordination polymerization, atom transfer radical polymerization, and other polymerization were focused on. The development trends of N-heterocyclic carbene ligands in polymerization were also prospected. 查看全文查看/发表评论下载PDF阅读器 相关附件:版权转让声明书修改稿修改说明 -->
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