中文关键词:离子液体电解液粘度电导率 英文关键词:ionic liquidselectrolyteviscosityconductivity 基金项目:河北省高等学校科学技术研究项目（ZD2015118）

作者	单位	E-mail
张文林	河北工业大学化工学院	ctstzwl@163.com
兰晓艳	河北工业大学化工学院
史紫微	河北工业大学化工学院
李春利	河北工业大学化工学院

摘要点击次数:2068 全文下载次数:0 中文摘要: 传统碳酸酯电解液在高压条件下持续氧化分解,严重制约了高压锂电池的发展。因此需要结合绿色、安全、经济效益等因素,设计、合成并筛选新型的高压电解液,本文介绍了传统碳酸酯电解液的现状以及在高压条件下被氧化主要因素；综述了新型碳酸酯类、腈类、砜类以及离子液体类等高压电解液的研究进展。阐述了电解液高压条件下的作用效果及研究机理，为改善电解液稳定性、降低粘度、提高电导率及安全性能等方面的研究提出方向，为实现高压电解液的工业化奠定基础。 英文摘要: Traditional carbonate electrolyte can be easily oxidized and decomposed continuously under high pressure condition, which seriously restricts the development of high voltage lithium battery. Therefore,it is necessary for designers to design and synthesize new high-pressure electrolytes, in order to be up to the concept of sustainable development and green chemistry to a certain extent. The dominating reasons why carbonate-based electrolyte under high pressure condition can be oxidized and the status of the traditional electrolytes are described in this paper. In addition to that, the recent advances of new several high-pressure electrolytes such as carbonates,nitriles, sulfones and ionic liquids are reviewed. The effect and mechanism of the electrolyte under high pressure are discussed in detail, which provided the direction for enhancing the stability of electrolyte, reducing the viscosity, improving the conductivity as ell as safety performance,based on these ways,which accurately lay the foundation for the further industrialization of high-pressure electrolyte. 查看全文查看/发表评论下载PDF阅读器 相关附件：版权转让声明书 -->