中国科学院化学研究所导师教师师资介绍简介-赵进才

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课题组长

赵进才研究员中国科学院院士

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联系方式
北京市海淀区中关村北一街2号
中国科学院化学研究所
光催化及环境光化学课题组
Tel：
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Email：jczhao@iccas.ac.cn

课题组简介
低浓度、高毒性、难降解有机污染物（如卤代物、染料、农药、抗生素药物等）引起的环境问题已经严重影响人类的健康。这些主要源自人工合成的污染物毒性大，即使浓度很低也容易引起动物及人类致癌、致畸、致突变性。更重要的是现有环境技术（如生物技术，物理化学技术等）很难将其除去。光催化降解技术以其高效、绿色及有效利用太阳能等优点成为最有产业化应用前景的环境技术之一。课题组长期从事低浓度、高毒性、难降解有机污染物的新型光催化体系以及光催化机理方面的研究。重点研究方向如下：污染物光催化降解新材料、新原理和新方法、大气颗粒物表面光化学过程、微量污染物光化学检测新方法和新原理、光催化绿色有机合成等。课题组职工包括6名研究员及1名副研究员，其中包括中国科学院院士1人，国家****获得者3人，国家优秀青年基金获得者2人，目前在读研究生36人，在站博士后2人。
温暖的大家庭：

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课题组座右铭：
幼儿般的好奇，探险家般的勇敢，麂鹿般的敏捷，
炼金士般的持久，梦幻般的激情，
通融、谦虚、欢乐及幽默

最新研究进展
黑碳的非均相光化学老化过程研究取得新进展
黑碳（soot）一经排放到大气中，就会与大气中的无机、有机气体相互作用，该过程不仅显著影响大气中气体组分的含量与寿命，也会显著改变黑碳的化学组成、结构、光学性质、亲水性等。在这些性质中，黑碳的化学组成对其亲水性、光学性质等有显著的影响。因此研究黑碳非均相老化中化学组成的变化具有重要的意义。
在该工作中，我们首次研究了黑碳与O₂在水中的非均相光化学反应。该非均相反应将黑碳表面非极性的C-H物种氧化成极性的C=O物种，极性物种具有更大的水溶性，因此伴随着光化学反应的发生，黑碳向水中释放溶解性有机物，提高了水相的吸光能力。更重要的是，我们发现黑碳的悬浊液特别是水溶性部分，是产生¹O₂的高效光敏剂，水溶性黑碳在377 nm光照下，¹O₂的量子产率达到33 ±2％，比水中大多数溶解性有机物的¹O₂量子产率高出一个数量级。黑碳在光照下可以有效地降解双酚A，说明黑碳可以显著影响水相共存有机污染物的环境寿命。因此，黑碳在水相中的光老化可通过有机物的释放和降解显著影响水相化学组成。该工作不仅研究了黑碳在水中非均相光化学老化过程，也揭示了该过程对水环境的影响：黑碳通过向水中释放溶解性有机物和利用产生的¹O₂降解水中共存的污染物来影响水环境的化学组成，进而影响水环境的性质。研究结果发表在Environmental Science & Technology（2019，DOI：10.1021/acs.est.9b02773）上。

课题组动态
名称日期

黑碳的非均相光化学老化过程研究取得进展 2019-09-30
课题组长赵进才院士当选欧洲科学院外籍院士 2018-12-12
黑碳光化学老化机制研究取得新进展 2018-07-24
α-Fe2O3光阳极表面水氧化过程研究取得进展 2018-02-02
染料污染物光催化降解过程表面Ti-H物种的发现及其重要作用 2017-02-15

更多

课题组成员
课题组组长
在职员工马万红
陈春城
车延科
宋文静
盛桦
章宇超
籍宏伟
硕博在读
已毕业学生

课题组成员
课题组现有研究员6人，副研究员1人，包括中国科学院院士1人，国家****获得者3人，国家优秀青年基金获得者2人。另外，有在站博士后2人，博士生24人，硕士生12人。

课题组成员
课题组组长
在职员工马万红
陈春城
车延科
宋文静
盛桦
章宇超
籍宏伟
硕博在读
已毕业学生

课题组长

赵进才，1960年生，中科院化学所研究员，中国科学院院士，发展中国家科学院（TWAS）院士，欧洲科学院（EurASc）外籍院士，国家生态环境保护专家委员会委员，科技部重点专项指南编制专家。
1982年毕业于内蒙古大学，1986年获该校硕士学位，1994年获日本Meisei大学博士学位。1995年回国，现任中科院化学所研究员。长期从事低浓度、高毒性、难降解有机污染物光催化降解及其机理方面的研究。提出并确立了不同于传统紫外光光催化的染料污染物可见光光催化降解机理，将TiO₂光催化从紫外光区拓展到可见光区域。提出了金属/非金属二元协同改性的光催化材料设计新思路，设计合成了系列新型高效高稳定性可见光光催化材料；发现了光催化反应过程中氧原子转移的新途径，揭示了分子氧在光催化反应中的新作用。将光催化原理用于环境中的重要光化学过程研究，阐明了环境中铁物种的光化学循环规律及其环境效应。
在Acc. Chem. Res.、PNAS、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Environ. Sci. Technol.等SCI刊物上发表论文300余篇，被SCI他引28000余次。承担科学院先导项目、973项目、基金委重大及重点项目等。1997年获国家****基金，2005年获国家自然科学奖二等奖（第一完成人），2010年获日本光化学协会“亚洲及太平洋光化学家讲座奖”，应邀担任Environ. Sci. Technol.、Energy Environ. Sci.等7个国际期刊的编委或顾问编委，任《环境科学》、《化学进展》刊物主编，英国皇家化学会Fellow等。

课题组成员
课题组组长
在职员工马万红
陈春城
车延科
宋文静
盛桦
章宇超
籍宏伟
硕博在读
已毕业学生

在职职工

马万红陈春城车延科 宋文静 盛桦

章宇超籍宏伟

课题组成员
课题组组长
在职员工马万红
陈春城
车延科
宋文静
盛桦
章宇超
籍宏伟
硕博在读
已毕业学生

在读研究生
热沙来提·海里里 熊伟 赵玉坤 彭伟 朱其建 刘晓玲 郭永先
丁立勇 魏燕 张悦 黄笛 林雨涵 夏红玲 赵鑫 邱长坤
王今朝孟涤 陈建华程传钦姜竑宇乔效峰王伟崔林丰
于新婷谢世杰杜晓鸣 刘天娇黎少林主一汎邓朝元李杨凡
姬晓洁段梦宇贾通通武磊 李佳春张晚依

课题组成员
课题组组长
在职员工马万红
陈春城
车延科
宋文静
盛桦
章宇超
籍宏伟
硕博在读
已毕业学生

已毕业学生
已毕业研究生及出站博士后：
陈峰、刘光明、何建军、瞿萍、吴太兴、吴凯群、张天永、黄应平
谢银德、李祥忠、陶霞、李静谊、陈春城、何惧、李静、雷鹏翔
程明明、宋文静、刘丽丽、马家海、赵丹、籍宏伟、塔里克、王一峰
段苒、王兆慧、张苗、王齐、孙春燕、刘桂林、温博、郎贤军
文晟、张丰雷、马万红、赵伟、原弘、任延军、车延科、胡学峰
杨娟、陈希、余春、赵玉宝、李悦、孙亦然、李宁、于笑潇
杨昌军、陈其凤、郭贵宝、曹霄峰、王建朝、李骎、盛桦、程实
李莉娜、王颖、庞喜斌、吕艳阳、李佑稷、常巍、师涛、章宇超
张一帆、马小杰、张一斌、马东阁、龚原正、彭澄、周鹏、万震
张红娜、胡艳勇、杨纯、朱倩、周子超、刘阿楠、汪园园、包凤霞
李萌、商锦亭、郑英璇、巩彦君、胡珂
联合培养
刘峰、郭承志、刘海波、王雪松、王效平、于书平、孙振英、冯晔
王静、郭军波、夏永良、薛凤丽、卓黎阳、赖晓红、孙业乐、郑国锋
刘华源、刘新刚、陈军、范颖、管臣、王菲、吴威、刘冠男
鄂月、叶伟东、闫研

研究领域
污染物光催化降解新原理和新方法
大气颗粒物表面光化学过程
新型环境纳米材料及纳米光催化
微量污染物光化学检测新方法新原理
光催化绿色有机合成

污染物光催化降解新原理和新方法
低浓度、高毒性、难降解有机污染物是国际上十分关注的一类新型污染物，用传统技术很难处理，因此，建立和发展新的消除原理和方法是环境化学领域重要的研究课题之一。课题组通过长期系统研究染料污染物可见光光催化降解，提出并确立了不同于传统紫外光光催化的可见光光催化反应新原理，提供了一个实现宽带隙半导体的可见光光催化的新途径；构建了系列基于铁配合物的可见光光催化体系，可在温和条件下、宽pH范围内将有机污染物高效降解；针对难氧化降解的（全）卤代污染物，构建了基于质子耦合电子转移的光催化还原降解的新体系。

染料污染物可见光光催化降解

质子耦合电子转移的光催化还原机理

研究领域
污染物光催化降解新原理和新方法
大气颗粒物表面光化学过程
新型环境纳米材料及纳米光催化
微量污染物光化学检测新方法新原理
光催化绿色有机合成

大气颗粒物表面光化学过程
大气气溶胶颗粒在大气环境中经历复杂的物理化学变化从而影响全球气候和空气质量。大气气溶胶颗粒表面HNO₃/NO₃^-的光化学反硝化过程是一个重要的大气变化过程。这一反硝化过程会释放HONO和NO_x，它们分别是·OH和O₃的前体物，这将对大气氧化能力以及生物地球氮循环产生重要的影响。课题组聚焦于北京城市PM2.5气溶胶上HNO₃/NO₃-的光化学反硝化过程，通过在北京市区采集2016年4月至2018年4月的PM2.5气溶胶样品，研究分析了PM2.5上HNO₃/NO₃^-光解过程中所释放的HONO对大气HONO未知来源的贡献，研究了环境因素对这一过程的影响。此外，研究了PM2.5在光照下发生反硝化过程的机理，指出了PM2.5不同组分包括吸光物质、水溶性无机盐、水溶性有机酸在PM2.5上HNO₃/NO₃^-光解过程中的作用。

另一方面，黑碳是由化石燃料和生物质的不完全烧产的，是大气溶胶的重要组成部分。黑碳一经排放到大气中，就会与大气中的无机、有体相互作用，自身发生老化过程，进而影响其环境效应。黑碳与空气中O₂的非均相光化学反应是黑碳光化学老化的重要途径。课题组利用原位衰减全反射红外、傅里叶转换离子回旋共振质谱和电子顺磁共振等手段研究了黑碳与O₂非均相光化学反应过非均相光化学反应过程中黑碳基团的变化、分子组成以及活性氧物种产生，揭示了程中黑碳基团的变化、分子组成以及活性氧物种产生，揭示了程中黑碳基团的变化、分子组成以及活性氧物种产生，揭示了非均相光化学老的机制及其对环境的影响。

研究领域
污染物光催化降解新原理和新方法
大气颗粒物表面光化学过程
新型环境纳米材料及纳米光催化
微量污染物光化学检测新方法新原理
光催化绿色有机合成

新型环境纳米材料及纳米光催化
利用TiO₂光催化降解有毒有机污染物是目前国际上十分关注的研究领域，但TiO₂只能吸收波长小于387nm的紫外光，在可见光照射下没有光催化活性。因太阳光中只有不足4%的光能为紫外光，而人造紫外光源又有耗电大，设备昂贵，稳定性差等缺陷，因此研制新的光催化剂使得它能够吸收太阳光中的可见光，利用空气中的氧作为氧化剂，有效地降解有毒有机污染物成为光催化领域关键的科学难题。该研究方向主要包括新型基于TiO₂修饰与改性的光催化材料及基于金属配合物的可见光光催化材料两大部分。如课题组成功地利用简单的溶胶-凝胶(Sol-Gel）方法研制出新型可见光光催化剂Ni₂O₃/TiO_2-xB_x。用非金属元素B置换TiO₂晶格中的部分氧，可以有效地将TiO₂的吸收光谱扩展到可见光区域，同时用过渡金属氧化物Ni₂O₃对TiO₂表面改性，可以极大地提高可见光光催化活性。非金属元素B或Ni₂O₃单一组分改性的光催化剂都没有可见光光催化活性，而二元协同改性，同时实现了扩展光催化剂吸收波长到可见光区域和抑制空穴/电子对复合的双重目的。用该光催化剂在可见光（波长大于420nm）照射下，以空气中氧分子为氧化剂，可将有毒有机污染物2,4,6-三氯苯酚，2,4-二氯苯酚等有效地降解为二氧化碳、水和氯离子。

新型可见光光催化剂（Ni₂O₃/TiO_2-xB_x）及其降解机理

系列Fe配合物可见光光催化材料

研究领域
污染物光催化降解新原理和新方法
大气颗粒物表面光化学过程
新型环境纳米材料及纳米光催化
微量污染物光化学检测新方法新原理
光催化绿色有机合成

微量污染物光化学检测新方法新原理
构建了一系列基于自组装一维有机纳米材料的新型荧光和光电导检测方法，应用于检测微量有毒、有害气相目标分子和重金属离子。研究的核心包括具有分子识别功能的构筑单元的分子设计与超分子自组装构建高荧光发射效率与光电导率有机纳米材料。与传统高分子膜传感材料相比，构建的荧光有机纳米传感材料对有毒、有害气相分子包括各类有机胺（如苯胺等），硝基芳烃化合物，苯酚等的灵敏度提高几个数量级。同样的原理也成功应用于超选择性检测重金属汞离子。开创的光电导检测方法则利用污染物分子与传感材料界面的光诱导电荷分离与传输的敏感性，实现选择性地检测同类污染物中具体不同分子。

一维荧光有机纳米材料高灵敏度和高选择性地检测有机胺蒸气

研究领域
污染物光催化降解新原理和新方法
大气颗粒物表面光化学过程
新型环境纳米材料及纳米光催化
微量污染物光化学检测新方法新原理
光催化绿色有机合成

光催化绿色有机合成
光催化选择性有机合成由于其条件温和、绿色、利用太阳能等有毒近年来得到了越来越多的关注。通过选择合适的底物分子、溶剂火堆光催化剂进行设计改性，我们可以得到很高的选择性，课题组近期在醇类及胺类分子选择性合成相应的醛酮及亚胺等方面取得了重要的突破，并且对O₂参与的反应机理进行了深入的研究。

TiO₂光催化氧化伯胺为相应的亚胺类化合物

发表论文
代表性论文
2019
2018
2017
2016
2008-2015

发表论文
在Acc. Chem. Res.、PNAS、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Environ. Sci. Technol.等SCI刊物上发表论文300余篇，被SCI他引28000余次，H因子83，单篇最高他人引用1200余次。 1. 封面论文

2. 代表性论文
Lang, X. J.;W. H. Ma; C. C. Chen; H. W. Ji;J. C. Zhao*. Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res.2014, 47(2), 355–363.
C. C. Chen; W. H. Ma; J. C. Zhao* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation.Chem. Soc. Rev.2010, 39, 4206-4219.
Meng Li, Fengxia Bao, Yue Zhang, Wenjing Song, Chuncheng Chen*, Jincai Zhao. Role of Elemental Carbon in the Photochemical Aging of Soot.Proc. Natl. Acad. Sci.USA,2018, 115, 30, 7717-7722
Zhang, Yuchao; Zhang, Hongna; Liu, Anan; Chen, Chuncheng*; Song, Wenjing*; Zhao, Jincai. Rate-?Limiting O-?O Bond Formation Pathways for Water Oxidation on Hematite Photoanode.J. Am. Chem. Soc.,2018, 140(9), 3264-3269
Yan Yan, Weidong Shi, Zhen Yuan, Shenggui He, Dongmei Li, Qingbo Meng, Hongwei Ji, Chuncheng Chen, Wanhong Ma*, Jincai Zhao* The Formation of Ti–H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices.J. Am. Chem. Soc.2017, 139, 2083-2089
Yuchao Zhang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, and Jincai Zhao*. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes.J. Am. Chem. Soc., 2016, 138 (8), 2705–2711
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O.J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Ma, Xiaojie; Zhang, Yibin; Zhang, Yifan; Liu, Yin; Che, Yanke*; Zhao, Jincai. Fabrication of Chiral-?Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization.Angew. Chem. Int. Ed.2016, 55(33), 9539-9543.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway.Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study.Angew. Chem. Int. Ed.2015, 54, 5905-5909
W. Zhao; W. H. Ma; C. C. Chen; J. C. Zhao* and Z. G. Shuai Efficient degradation of toxic organic pollutants with Ni₂O₃/TiO_2-xB_xunder visible irradiation.J. Am. Chem. Soc.2004, 126, 4782-4783.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway.Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen,* Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study.Angew. Chem. Int. Ed.2015, 54, 5905-5909
Y. Li, H. Ji, C. Chen*, W. Ma, J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640.
Sheng, H.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Direct Four-Electron Reduction of O₂to H₂O on TiO₂Surface by Pendant Proton Relay.Angew. Chem. Int. Ed., 2013,52, 9686 –9690.
Y. B. Zhao; W. H. Ma; Y. Li; H. Ji; C. C. Chen; H. Zhu; J. C. Zhao* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction.Angew. Chem. Int. Ed., 2012, 51(13), 3188 –3192.
Q. Wang; M. Zhang; C. C. Chen; W. H. Ma; J. C. Zhao* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Bronsted acid.Angew. Chem. Int. Ed.2010, 49, 7976-7979. (Very Important Paper, Inside Cover Paper)
Y. K. Che;X. M. Yang; G. Liu; C. Yu; H. W. Ji; J. Zuo; J. C. Zhao*; L. Zang* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives.J. Am. Chem. Soc.,2010, 132(16), 5743-5750.
M. Zhang; Q. Wang; C. C. Chen; L. Zang; W. H. Ma*; J. C. Zhao* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies.Angew. Chem. Int. Ed.2009,48, 6081-6084. (Highly Important Paper, Cover Paper)
M. Zhang; C. C. Chen; W. H. Ma*; J. C. Zhao* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂and TEMPO.Angew. Chem. Int. Ed.2008, 47, 9730-9733. (Hot Paper)

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2008-2015

代表性论文
Lang, X. J.;W. H. Ma; C. C. Chen; H. W. Ji;J. C. Zhao*. Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res. 2014, 4
Yuchao Zhang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, and Jincai Zhao*. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes. J. A
7(2), 355–363.
C. C. Chen; W. H. Ma; J. C. Zhao* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation.Chem. Soc. Rev.2010, 39, 4206-4219. (1080 citations by others)
Meng Li, Fengxia Bao, Yue Zhang, Wenjing Song, Chuncheng Chen*, Jincai Zhao. Role of Elemental Carbon in the Photochemical Aging of Soot.Proc. Natl. Acad. Sci.USA,2018, 115, 30, 7717-7722
Zhang, Yuchao; Zhang, Hongna; Liu, Anan; Chen, Chuncheng*; Song, Wenjing*; Zhao, Jincai. Rate-?Limiting O-?O Bond Formation Pathways for Water Oxidation on Hematite Photoanode.J. Am. Chem. Soc.,2018, 140(9), 3264-3269
Yan Yan, Weidong Shi, Zhen Yuan, Shenggui He, Dongmei Li, Qingbo Meng, Hongwei Ji, Chuncheng Chen, Wanhong Ma*, Jincai Zhao* The Formation of Ti–H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices.J. Am. Chem. Soc.2017, 139, 2083-2089
m. Chem. Soc., 2016, 138 (8), 2705–2711
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O. J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Ma, Xiaojie; Zhang, Yibin; Zhang, Yifan; Liu, Yin; Che, Yanke*; Zhao, Jincai. Fabrication of Chiral-?Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization. Angew. Chem. Int. Ed. 2016, 55(33), 9539-9543.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂ Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed. 2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao. Activation of Water in TiO₂ Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study. Angew. Chem. Int. Ed.2015, 54, 5905-5909
Hai-Ying Jiang, Peng Zhou, Yuanyuan Wang, Chuncheng Chen, Wenjing Song*, and Jincai Zhao. Copper-Based Coordination Polymer Nanostructure for Visible Light Photocatalysis. Adv. Mater. 2016, 28 (44), 9776–9781
Yifan Zhang, Cheng Peng, Bin Cui, Zhengfei Wang, Xibin Pang, Renmin Ma, Feng Liu*, Yanke Che*, Jincai Zhao. Direction-Controlled Light-Driven Movement of Microribbons. Adv. Mater. 2016, 28 (38), 8538–8545
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers. Adv. Mater. 2015, 27, 320–325.
Xiaojie Ma, Yibin Zhang, Yifan Zhang, Cheng Peng, Yanke Che* Jincai Zhao. Stepwise Formation of Photoconductive Nanotubes through a New Top-Down Method.Adv. Mater. 2015, 27, 7746–7751
Yuchao Zhang, Shiqi Jiang, Wenjing Song, Peng Zhou, Hongwei Ji, Wanhong Ma, Weichang Hao, Chuncheng Chen* and Jincai Zhao. Nonmetal P-doped hematite photoanode with enhanced electron mobility and high water oxidation activity. Energy Environ. Sci. 2015,8, 1231-1236
W. Zhao; W. H. Ma; C. C. Chen; J. C. Zhao* and Z. G. Shuai Efficient degradation of toxic organic pollutants with Ni₂O₃/TiO_2-xB_x under visible irradiation. J. Am. Chem. Soc. 2004, 126, 4782-4783. (Top paper selected by ISI Web of Knowledge, 950 citations by others)
Y. Li, H. Ji, C. Chen*, W. Ma, J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂ Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640.
Sheng, H.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Direct Four-Electron Reduction of O₂ to H₂O on TiO₂ Surface by Pendant Proton Relay. Angew. Chem. Int. Ed., 2013,52, 9686 –9690.
Y. B. Zhao; W. H. Ma; Y. Li; H. Ji; C. C. Chen; H. Zhu; J. C. Zhao* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction. Angew. Chem. Int. Ed., 2012, 51(13), 3188 –3192.
Q. Wang; M. Zhang; C. C. Chen; W. H. Ma; J. C. Zhao* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Bronsted acid. Angew. Chem. Int. Ed. 2010, 49, 7976-7979. (Very Important Paper, Inside Cover Paper)
Y. K. Che;X. M. Yang; G. Liu; C. Yu; H. W. Ji; J. Zuo; J. C. Zhao*; L. Zang* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives. J. Am. Chem. Soc., 2010, 132(16), 5743-5750.
M. Zhang; Q. Wang; C. C. Chen; L. Zang; W. H. Ma*; J. C. Zhao* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies. Angew. Chem. Int. Ed. 2009,48, 6081-6084. (Highly Important Paper, Cover Paper)
M. Zhang; C. C. Chen; W. H. Ma*; J. C. Zhao* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂ and TEMPO. Angew. Chem. Int. Ed. 2008, 47, 9730-9733. (Hot Paper)
X. J. Lang; H. W.Ji; C. C. Chen; W. H. Ma; J. C. Zhao* Selective formation of imines via aerobic photocatalytic oxidation of amines on TiO₂. Angew. Chem. Int. Ed.,2011, 50(17), 3934-3937.(Very Important Paper)
W. H. Ma; J. Li; X. Tao; J. He; Y. M. Xu; J. C. Yu; J. C. Zhao* Efficient degradation of organic pollutants by using dioxygen activated by resin-exchanged iron(II) bipyridine under visible irradiation. Angew. Chem. Int. Ed. 2003, 42, 1029-1032.

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2019
Li, Meng; Bao, Fengxia; Zhang, Yue; Sheng, Hua; Chen, Chuncheng*; Zhao, Jincai. Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of ¹O₂. Environmental Science & Technology, 2019, 53, 21, 12311-12319.
Zhang, Yue; Bao, Fengxia; Li, Meng; Chen, Chuncheng*; Zhao, Jincai. Nitrate Enhanced Oxidation of SO₂ on Mineral Dust: A Vital Role of Proton. Environmental Science & Technology, 2019, 53, 10139?10145
Yan Yan, Weidong Shi, Wei Peng, Yuhan Lin, Chunxi Zhang, Lailai Li, Young Sun, Huanxin Ju, Junfa Zhu, Wanhong Ma*, Jincai Zhao*. Proton-free electron-trapping feature of titanium dioxide nanoparticles without the characteristic blue color. Communications Chemistry. 2019, 88. DOI: s42004-019-0191-7
Yu, Xinting; Gong, Yanjun; Xiong, Wei; Li, Mei*; Zhao, Jincai; Che, Yanke*. Turn-?on Fluorescent Detection of Hydrogen Peroxide and Triacetone Triperoxide via Enhancing Interfacial Interactions of a Blended System. Anal. Chem. 2019, 91, 6967?6970
Qiu, Changkun; Liu, Xiaoling; Cheng, Chuanqin; Gong, Yanjun; Xiong, Wei; Guo, Yongxian; Wang, Chen; Zhao, Jincai; Che, Yanke*. Ultrasensitive Detection of Sulfur Mustard via Differential Noncovalent Interactions. Anal. Chem. 2019, 91, 6408?6412
Xiong, Wei; Gong, Yanjun; Che, Yanke*; Zhao, Jincai. Sensitive Discrimination of Nerve Agent and Sulfur Mustard Simulants Using Fluorescent Coassembled Nanofibers with Fo?rster Resonance Energy Transfer-?Enhanced Photostability and Emission. Anal. Chem. 2019, 91, 1711?1714
Liu, Xiaoling; Gong, Yanjun; Xiong, Wei; Cui, Linfeng; Hu, Ke; Che, Yanke*; Zhao, Jincai. Highly Selective Detection of Benzene, Toluene, and Xylene Hydrocarbons Using Coassembled Microsheets with Fo?rster Resonance Energy Transfer-?Enhanced Photostability. Anal. Chem. 2019, 91, 768?771
Hu, Ke; Liu, Yin; Xiong, Wei; Gong, Yanjun; Che, Yanke*; Zhao, Jincai. Fabrication of Single-?Handed Nanocoils with Controlled Length via a Living Supramolecular Self-?Assembly. Chem. Mater. 2019, 31, 1403?1407
Guo, Yongxian; Liu, Yin; Gong, Yanjun; Xiong, Wei; Zhang, Chuang*; Zhao, Jincai; Che, Yanke*. Kinetic control of a self-?assembly pathway towards hidden chiral microcoils. Chem. Eur. J. 2019, 25, 7463 – 7468
Zhong, Junbo; Zhao, Yukun; Ding, Liyong; Ji, Hongwei; Ma, Wanhong; Chen, Chuncheng*; Zhao, Jincai*. Opposite photocatalytic oxidation behaviors of BiOCl and TiO₂: Direct hole transfer vs. indirect ·OH oxidation. Applied Catalysis B: Environmental. 2019, 241, 514–520
Wei, Yan; Gong, Yanjun; Zhao, Xin; Wang, Yuanyuan; Duan, Ran; Chen, Chuncheng; Song, Wenjing*; Zhao, Jincai. Ligand directed debromination of tetrabromodiphenyl ether mediated by nickel under visible irradiation. Environ. Sci.: Nano, 2019, 6, 1585–1593.
Wei Peng, Yuhan Lin, Zhen Wan, Hongwei Ji, Wanhong Ma*, Jincai Zhao*. An Unusual Dependency on the Hole-Scavengers in Photocatalytic Reductions Mediated by a Titanium-Based Metal-Organic Framework. An Unusual Dependency on the Hole-Scavengers in Photocatalytic Reductions Mediated by a Titanium-Based Metal-Organic Framework. Catalysis Today. 2019, DOI:10.1016/j.cattod.2018.11.038
Yuanyuan Wang, Yan Wei, Wenjing Song*, Chuncheng Chen, Jincai Zhao*. Photocatalytic Hydrodehalogenation for the Removal of Halogenated Aromatic Contaminants. ChemCatChem, 2019, 11, 258–268.

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2018

Zhang, Y. C.; Zhang, H. N.; Liu, A. N.; Chen, C. C.; Song, W. J.; Zhao, J. C. Rate-Limiting O-O Bond Formation Pathways for Water Oxidation on Hematite Photoanode. J. Am. Chem. Soc. 2018, 140(9), 3264-3269.
Li, M.; Bao, F. X.; Zhang, Y.; Song, W. J.; Chen, C. C.; Zhao, J. C. Role of elemental carbon in the photochemical aging of soot. Proc. Natl. Acad. Sci. USA 2018, 115(30), 7717-7722.
Bao, F. X.; Li, M.; Zhang, Y.; Chen, C. C.; Zhao, J. C. Photochemical Aging of Beijing Urban PM2.5: HONO Production. Environ. Sci. Technol. 2018, 52(11), 6309-6316.
Xiong, W.; Zhu, Q. J.; Gong, Y. J.; Wang, C.; Che, Y. K.; Zhao, J. C. Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives.Anal. Chem. 2018, 90(7), 4273-4276.
Liu, X. L.; Gong, Y. J.; Zheng, Y. X.; Xiong, W.; Wang, C.; Wang, T.; Che, Y. K.; Zhao, J. C. Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement. Anal. Chem. 2018, 90(3), 1498-1501.
Sun, C. Y.; Xiong, W.; Ye, W. D.; Zheng, Y. X.; Duan, R.; Che, Y. K.; Zhao, J. C. Fast and Ultrasensitive Detection of a Nerve Agent Simulant Using Carbazole-Based Nanofibers with Amplified Ratiometric Fluorescence Responses. Anal. Chem. 2018, 90(12), 7131-7134.
Yang, C.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C. Desulfurization of thiophenes in oils into H₂SO₄ using molecular oxygen. Appl. Catal. B-Environ. 2018, 235, 207-213.
Wang, Y. Y.; Zhu, Q.; Wei, Y.; Gong, Y. J.; Chen, C. C.; Song, W. J.; Zhao, J. C. Catalytic hydrodehalogenation over supported gold: Electron transfer versus hydride transfer. Appl. Catal. B-Environ. 2018, 231, 262-268.
Zhang, H. N.; Zhou, P.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Enhancement of photocatalytic decarboxylation on TiO₂ by water-induced change in adsorption-mode. Appl. Catal. B-Environ. 2018, 224, 376-382.
Lang, X. J.; Zhao, J. C. Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis. Chem. Asian J. 2018, 13(6), 599-613.
Liu, A. N.; Zhang, Y. C.; Ma, W. H.; Song, W. J.; Chen, C. C.; Zhao, J. C. Facial boron incorporation in hematite photoanode for enhanced photoelectrochemical water oxidation. J. Photochem. Photobiol. A-Chem. 2018, 355, 290-297.
Hou, X. J.; Huang, X. P.; Li, M. L. ; Zhang, Y. S. ; Yuan, S. H. ; Ai, Z. H. ; Zhao, J. C. ; Zhang, L. Z. Fenton oxidation of organic contaminants with aquifer sediment activated by ascorbic acid. Chem. Eng. J. 2018, 348, 255-262.
Mao, C. L.; Cheng, H. G.; Tian, H.; Li, H.; Xiao, W. J.; Xu, H.; Zhao, J. C.; Zhang, L. Z. Visible light driven selective oxidation of amines to imines with BiOCl: Does oxygen vacancy concentration matter? Appl. Catal. B-Environ. 2018, 228, 87-96.
Mao, C. L.; Yu, L. H.; Li, J.; Zhao, J. C.; Zhang, L. Z. Energy-confined solar thermal ammonia synthesis with K/Ru/TiO_2-xH_x. Appl. Catal. B-Environ. 2018, 224, 612-620.

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1. Gong, Y. J.; Zhang, Y. F.; Xiong, W.; Zhang, K.; Che, Y. K.; Zhao, J. C. Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals. J. Am. Chem. Soc. 2017, 139(31), 10649-10652.
2. Yan, Y.; Shi, W. D.; Yuan, Z.; He, S. G.; Li, D. M.; Meng, Q. B.; Ji, H. W.; Chen, C. C.; Ma. W. H.; Zhao, J. C. The Formation of Ti-H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices. J. Am. Chem. Soc. 2017, 139(5), 2083-2089.
3. Liu, Y.; Peng, C.; Xiong, W.; Zhang, Y. F.; Gong, Y. J.; Che, Y. K.; Zhao, J. C. Two-Dimensional Seeded Self-Assembly of a Complex Hierarchical Perylene-Based Heterostructure. Angew. Chem. Int. Ed. 2017, 56(38), 11380-11384.
4. Zhu, Q.; Wang, Y. Y.; Zhang, H. N.; Duan, R.; Chen, C. C.; Song, W. J.; Zhao, J. C. Localized TiIII mediated dissociative electron transfer for carbon halogen bond activation on TiO₂. Appl. Catal. B-Environ. 2017, 219, 322-328.
5. Shang, J. T.; Tang, H. Y.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Synthesis, characterization, and activity of a covalently anchored heterogeneous perylene diimide photocatalyst. Chin. J. Catal. 2017, 38(12), 2094-2101.
6. Zhu, Q. J.; Xiong, W.; Gong, Y. J.; Zheng, Y. X.; Che, Y. K.; Zhao, J. C. Discrimination of Five Classes of Explosives by a Fluorescence Array Sensor Composed of Two Tricarbazole-Nanostructures. Anal. Chem. 2017, 89(22), 11908-11912.
7. Zhao, Y. K.; Wang, Y. Y.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Photocatalytic Reductive Debromination of Polybrominated Diphenyl Ethers. Prog. Chem. 2017, 29(9), 911-918.
8. Gong, Y. Z.; Yang, C.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C. Aqueous Oxidations Started by TiO₂ Photoinduced Holes Can Be a Rate-Determining Step. Chem. Asian J. 2017, 12(16), 2048-2051.
9. Zhang, Y. F.; Zhou, Z. C.; Peng, C.; Duan, R.; Che, Y. K.; Zhao, J. C. Increasing the interlayer distance in layered microribbons enhances the electrically driven twisting response. Phys. Rev. Mater. 2017, 1(3), 033601.
10. Zheng, Y. X.; Peng, C.; Xiong, W.; Zhang, Y. F.; Liu, Y.; Che, Y. K.; Zhao, J. C. Nanoscale Aggregates as Building Elements in a Biomimetic Living Self-Assembly. J. Phys. Chem. C 2017, 121(27), 14907-14913.
11. Xue, J. J.; Li, Y. F.; Xie, X. B.; Xiong, C. Q.; Liu, H. H.; Chen, S. M.; Nie, Z. X.; Chen, C. C.; Zhao, J. C. Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry. Atmos. Environ. 2017, 159, 55-65.
12. Hou, X. J.; Huang, X. P.; Jia, F. L.; Ai, Z. H.; Zhao, J. C. Zhang, L. Z. Hydroxylamine Promoted Goethite Surface Fenton Degradation of Organic Pollutants. Environ. Sci. Technol. 2017, 51(9), 5118-5126.
13. Hou, X. J.; Huang, X. P.; Ai, Z. H.; Zhao, J. C.; Zhang, L. Z. Ascorbic acid induced atrazine degradation. J. Hazard. Mater. 2017, 327, 71-78.
14. Zhou, Z. C.; Xiong, W.; Zhang, Y. F.; Yang, D. J.; Wang, T.; Che, Y. K.; Zhao, J. C. Internanofiber Spacing Adjustment in the Bundled Nanofibers for Sensitive Fluorescence Detection of Volatile Organic Compounds. Anal. Chem. 2017, 89(7), 3814-3818.
15. Huang, X. P.; Hou, X. J.; Jia, F. L.; Song, F. H.; Zhao, J. C.; Zhang, L. Z. Ascorbate-Promoted Surface Iron Cycle for Efficient Heterogeneous Fenton Alachlor Degradation with Hematite Nanocrystals. ACS Appl. Mater. Interf. 2017, 9(10), 8751-8758.
16. Peng, C.; Zhang, Y. F.; Zhang, Y. B.; Zhou, Z. C.; Che, Y. K.; Zhao, J. C. Diverse macroscopic helical motions of microribbons driven by electrons. Chem. Comm. 2017, 53(17). 2578-2581.
17. Zhang, H. N.; Zhou, P.; Chen, Z. F.; Song, W. J.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Hydrogen-Bond Bridged Water Oxidation on {001} Surfaces of Anatase TiO₂. J. Phys. Chem. C 2017, 121(4), 2251-2257.
18. Huang, X. P.; Hou, X. J.; Song, F. H.; Zhao, J. C.; Zhang, L. Z. Ascorbate Induced Facet Dependent Reductive Dissolution of Hematite Nanocrystals. J. Phys. Chem. C 2017, 121(2), 1113-1121.
19. Zhou, P.; Zhang, H. N.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Modulating the photocatalytic redox preferences between anatase TiO₂ {001} and {101} surfaces. Chem. Comm. 2017, 53(4), 787-790.

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2015
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen,* Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study. Angew. Chem. Int. Ed.2015, 54, 5905-5909
Jialei Du, Zuofeng Chen*, Chuncheng Chen*, Thomas J. Meyer. A Half-Reaction Alternative to Water Oxidation: Chloride Oxidation to Chlorine Catalyzed by Silver Ion.J. Am. Chem. Soc., 2015, 137 (9), pp 3193–3196
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers. Adv. Mater.2015, 27, 320–325.
Yuchao Zhang, Shiqi Jiang, Wenjing Song, Peng Zhou, Hongwei Ji, Wanhong Ma, Weichang Hao, Chuncheng Chen and Jincai Zhao. Nonmetal P-doped hematite photoanode with enhanced electron mobility and high water oxidation activity . Zhang, Y. C. Environ. Energy Sci.2015,8, 1231-1236
Lang, X. J.; Leow, W. R.; Zhao, J. C.*; Chen, X. D.* Synergistic photocatalytic aerobic oxidation of sulfides and amines on TiO₂under visible-light irradiation. Chem. Sci., 2015, 6, 1075–1082
Tao Shi, Wei Chang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen, and Jincai Zhao . H₂O-Involved Two-Electron Pathway for Photooxidation of Aldehydes on TiO₂: An Isotope Labeling Study. Environ. Sic. Technol.2015, 49 (5), pp 3024–3031
Xiaoling Liu , Yibin Zhang , Xibin Pang , Yue E , Yifan Zhang, Dongjiang Yang , Jianguo Tang, Jing Li , Yanke Che, Jincai Zhao. Nanocoiled Assembly of Asymmetric Perylene Diimides: Formulation of Structural Factors. J. Phys. Chem. C.2015, DOI: 10.1021/acs.jpcc.5b00720
Chen, C. C.; Shi, T.; Chang, W.; Zhao, J. C.* Essential Roles of Proton Transfer in Photocatalytic Redox Reactions. ChemCatChem, 2015, 7(5), 724–731
2014
Lang, X. J.;W. H. Ma; C. C. Chen;H. W. Ji; J. C. Zhao*.Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res.2014, 47(2), 355–363.
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O. J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Lang, X.; Chen, X.D.*, Zhao, J. C.* Heterogeneous Visible Light Photocatalysis for Selective Organic Transformations.Chem. Soc. Rev.2014, 43 (1), 473 - 486.
Wang, Z.*, Bush, R.,. Sullivan L., Chen, C. C.* Liu, J. Selective oxidation of arsenite by peroxymonosulfate with high utilization efficiency of oxidant. Environ. Sci. Technol. 2014, 48, 3978-3985.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.;Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed.2014, DOI: 10.1002/anie..
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers. Adv. Mater. 2014, DOI: 10.1002/adma..
Zhao, Y. B.; Zhang, Y. F.; Liu, H. W.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhu, H. Y.; Zhao J. C. Control of Exposed Facet and Morphology of Anatase Crystals through TiO_xF_y Precursor Synthesis and Impact of the Facet on Crystal Phase Transition. Chem. Mater. 2014, 26 (2), 1014–1018.
Sun, Y.; Chang, W.; Ji, H. W.; Chen, C. C.; Ma, W. H. *; Zhao, J. C*. An Unexpected Fluctuating Reactivity for Odd and Even Carbon Numbers in the TiO₂ Photocatalytic Decarboxylation of C2-C6 Dicarboxylic Acids. Chem. Eur. J. 2014, 20, 1861–1870(Cover Paper).
Li, L. N.; Chang, W.; Wang, Y.; Ji, H. W.; Chen, C. C.*; Ma, W. H.;Zhao, J. C. Rapid Photocatalytic Deep-Debromination of Polybrominated Diphenyl Ethers on Pd-TiO₂: Intermediates and Pathways. Chem. Eur. J. 2014, 20(35), 11163–11170.
Yang, C. J.; Lang, X. J.; Ma, W. H.; Chen, C. C.*; Ji, H. W. ; Zhao, J. C. UV-Assisted Removal of Inactive Peroxide Species for Sustained Epoxidation of Cyclooctene on Anatase TiO₂. Chem. Eur. J. 2014, 20(21), 6277–6282.
Ying Wang, Lina Li, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao. Iron(III)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency. Chem. Commun. 2014, 50, 2344-2346.
E, Y,; Ma, X. J.; Zhang, Y. F.; Zhang, Y. B.; Duan, R.; Ji, H. W.; Li, J.*; Che, Y. K.*; Zhao, J. C. Fluorescent bilayer nanocoils assembled from an asymmetric perylene diimide molecule with ultrasensitivity for amine vapors. Chem. Commun. 2014, 50, 13596-13599.
Zhang, Y. C.; Zhou, Z. C.; Chen, C. C.*; Che, Y.; Ji, H.; Ma, W.; Zhang, J.; Song, D.; Zhao, J. C. Gradient FeO_x(PO₄)_yLayer on Hematite Photoanodes: Novel Structure for Efficient Light Driven Water Oxidation. ACS Appl. Mater. Interfaces, 2014, 6 (15), 12844–12851.
Wang, J.; Lang, X. J.; Bao, Z.*; Jia, M. L.; Wang, J.; Guo, X.; Zhao, J. C.* Aerobic Oxidation of Alcohols on Au Nanocatalyst: Insight to the Roles of the Ni–Al Layered Double Hydroxides Support. ChemCatChem, 2014, 6, 1737 – 1747.
Pang, X. B.; Chen, C. C.*; Ji, H. W.; Che, Y. K.; Ma W. H.; Zhao, J. C*. Unraveling the Photocatalytic Mechanisms on TiO₂Surfaces Using the Oxygen-18 Isotopic Label Technique. Molecules, 2014, 19(10), 16291-16311.
Li, Q.; Che, Y. K.; Ji, H. W.; Chen, C. C.; Zhu, H.; Ma, W. H.*; Zhao J. C.* ortho-Dihydroxyl-9,10-anthraquinone dyes as visible-light sensitizers that exhibit a high turnover number for hydrogen evolution. Phys. Chem. Chem. Phys., 2014, 16, 6550--6554.
Wang, G. X.; Che, Y. K.*; Jiang, H.* Single Molecular Rotary Machine. Prog. Chem., 2014, 26(6), 909-918.
2013
Y. Li, H. Ji, C. Chen*, W. Ma,J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640
Sheng, H.; Ji, H. W.; Chen, C. C.*; Ma, W. H.; Zhao, J. C. Switching Single-Electron to Four-Electron Oxygen Reduction on TiO₂Surface by Pendant Proton Relay.Angew. Chem. Int. Ed., 2013,52, 9686 –9690.
Sun, C. Y.; Chang, W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Photoreductive debromination of decabromodiphenyl ethers in the presence of carboxylates under visible light irradiation. Environ. Sci. Technol. 2013, 47, 2370−2377.
Sheng, H.; Li, Q.; Ma, W. H.; Ji, H. W.; Chen, C. C.*; Zhao, J. C. Photocatalytic degradation of organic pollutants on surface anionized TiO₂: Common effect of anions for high hole-availability by water. Appl. Catal. B: Environ. 2013, 138– 139, 212– 218.
Cheng, S.; Li, J.; Yu, X.; Chen, C.; Ji, H.; Ma, W. H.* Zhao, J. C.* Selective Activation of Secondary C-H Bonds by an Iron Catalyst: Insight into Possibilities Created by the Use of a Carboxyl-Containing Bipyridine Ligand. New J. Chem., 2013, 37 (10), 3267 - 3273
Zhang, Y.; Bao Z.*; Jia M.; Chen, C. C.; Zhao, J. C.* Clay-based SiO₂ as active support of gold nanoparticles for CO oxidation catalyst: Pivotal role of residual Al. Catal. Commun. 2013, 35, 72–75.
Li, N.; Lang, X.; Ma, W. H.; Ji, H. W.; Chen, C. C.*; Zhao, J. C. Selective Aerobic Oxidation of Amines to Imines by TiO₂Photocatalysis in Water.Chem. Commun., 2013, 49 (44), 5034 – 5036.
Yang, D. J.*; Zhao, J.; Liu H. W.; Zheng, Z.; Adebajo, M. O.; Wang, H.; Liu, X.; Zhang, H.; Zhao, J. C.* Bell, J.; Zhu, H. Y.* Enhancing Photoactivity of TiO₂(B)/Anatase Core-Shell Nanofibers by Selectively Doping Cerium Ions into the TiO₂(B) Core. Chem. Eur. J. 2013, 19, 5113 – 5119.
Sun, Y.; Chang, W.; Ji, H. W.; Chen, C. C.; Ma, W. H. *; Zhao, J. C*. An Unexpected Fluctuating Reactivity for Odd and Even Carbon Numbers in the TiO₂ Photocatalytic Decarboxylation of C2-C6 Dicarboxylic Acids. Chem. Eur. J. 2013, accepted (Cover Paper).
Li, J. H.*; He H.; Hu, C.; Zhao, J. C.* The abatement of major pollutants in air and water by environmental catalysis. Front. Environ. Sci. Eng. 2013, 7(3): 302–325
2012
Zhao, Y. B.; Ma, W. H.; Li, Y.; Ji, H. W.; Chen, C. C.; Zhu, H.; Zhao, J. C.* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction, Angew. Chem. Int. Ed., 2012, 51, 3188 –3192.
Lang, X.; Ma, W. H.; Zhao, Y.; Chen, C. C.; Ji, H. W.; Zhao, J. C.*. Visible-light-induced selective photocatalytic aerobic oxidation of amines into imines on TiO₂, Chem. Eur. J., 2012, 18, 2624 – 2631.
Liu, G. L.; Chen, C. C.*; Ma, W. H.; Ji, H. W.; Zhao, J. C.*Photo-electrochemical water splitting system with three-layer n-type organic semiconductor film as photoanode under visible irradiation, Sci. China Chem., 2012, 55(9), 1953–1958
Li, Y.; Wen, B.; Yu, C.; Chen, C. C.*; Ji, H. W.; Ma, W. H.; Zhao, J. C.* Pathway of oxygen incorporation from O₂ inTiO₂ photocatalytic hydroxylation of aromatics: oxygen isotope labeling studies, Chem. Eur. J., 2012, 18, 2030-2039. (Cover paper)
Li, Y.; Wen B.; Chen, C. C.*; Ma, W. H.; Zhao, J. C. Photocatalytic degradation of aromatic pollutants: a pivotal role of e_cb^- in distribution of hydroxylated intermediates, Environ. Sci. Technol., 2012, 46 (9), 5093-5099.
Wang, Z. Chen, C. C.*; Ma, W. H.; Zhao, J. C.* Photochemical coupling of iron redox reactions and transformation of low-molecular-weight organic matter.J. Phys. Chem. Lett.2012, 3, 2044−2051.
Sun, C.; Zhao, J. C.; Ji, H. W.; Ma, W. H.; Chen, C. C.* Photocatalytic debromination of preloaded decabromodiphenyl ether on the TiO₂ surface in aqueous system. Chemosphere, 2012, 89, 420–425.
Chen, Q.; Ma, W. H.; Chen, C. C.; Ji, H. W.; Zhao, J. C.*Anatase TiO₂ mesocrystals enclosed by (001) and (101) facets: Synergistic effects between Ti³⁺ and facets for their photocatalytic performance. Chem. Eur. J., 2012, 18, 12584-12589.
Sun, C.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic debromination of decabromodiphenyl ether by graphitic carbon nitride. Sci. China Chem., 2012, 55(12), 2532-2536.
Sarina Sarina, Huaiyong Zhu,* Zhanfeng Zheng, Steven Bottle, Jin Chang, Xuebin Ke, Jin-Cai Zhao,Yining Huang, Andre Sutrisno, Mathew Willans and Guoran Li, Driving selective aerobic oxidation of alkyl aromatics by sunlight on alcohol grafted metal hydroxides, Chem. Sci., 2012, 3, 2138-2146
Ping Lei, Feng Wang,, Xiaowei Gao, Yanfen Ding, Shimin Zhang, Jincai Zhao, Shaoren Liu, Mingshu Yang∗, Immobilization of TiO2 nanoparticles in polymeric substrates bychemical bonding for multi-cycle photodegradation of organic pollutants, Journal of Hazardous Materials, 2012, 227-228,185-194
Hanzhong Jia, Jincai Zhao, Xiaoyun Fan, Kamila Dilimulati, Chuanyi Wang,∗Photodegradation of phenanthrene on cation-modified clays under visible light, Applied Catalysis B: Environmental 2012, 123-124, 43-51
Wang, L; Zang, L.; Zhao, J. C.; Wang, C. Y. Green synthesis of shape-defined anatase TiO₂ nanocrystals wholly exposed with {001} and {100} facets. Chem. Commun., 2012, 48, 11736–11738.
Shang, Y.; Chen. C.; Li, Y.; Zhao, J. C.; Zhu, T. Hydroxyl radical generation mechanism during the redox cycling process of 1, 4-naphthoquinone. Environ. Sci. Technol.2012, 46, 2935–2942.
2011
Lang, X. J.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Selective formation of imines via aerobic photocatalytic oxidation of amines on TiO₂. Angew. Chem. Int. Ed.,50(17) (2011), 3934-3937.
Ma, J.;Ma, W. H.; Chen, C. C.; Ji, H.W.;Zhao, J. C.*.An efficient anthraquinone–resin hybrid co-catalyst for fenton-like reactions: Acceleration of the iron cycle using a quinone cycle under visible-light irradiation.Chem. Asian J., 6(9)(2011), 2264-2268
Wang, Z.; Chen, C. C.; Ma, W. H.; Zhao, J. C.*, Probing paramagnetic species in titania-based heterogeneous photocatalysis by electron spin resonance(ESR) spectroscopy-A mini reviewChem. Eng. J., 170(2-3) (2011), 353-362. (Invited Review)
Yang D.; Chen, C. C.; Zheng, Z.; Liu, H.; Eric R. Yan, W., Huang, Y., Zhang H., Zhao, J. C.*; Zhu, H.*. Grafting silica species on anatase surface for visible light photocatalytic activity, Energy Environ. Sci. 4(6)(2011), 2279-2287.
Chen, X.; Ma, W. H.*; Li, J.; Wang, Z. H.; Chen, C. C.; Ji, H. W.Zhao, J. C.*. Photocatalytic oxidation of organic pollutants catalyzed by an iron complex at biocompatible pH values: Using O₂ as main oxidant in a Fenton-like reaction. J. Phys. Chem C, 115 (2011), 4089-4095.
Yuan, H.; Ma, W. H.; Chen, C. C.; Zhu H.; Gao X.; Zhao, J. C.*. Controllable synthesis of 3D thorny plasmonic gold nanostructures and their tunable optical properties,J. Phys. Chem. C, 115(47)(2011), 23256-23260.
Sun, C. Y.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photodegradation of organic pollutants catalyzed by iron species under visible light irradiation. Phys. Chem. Chem. Phys.,13 (2011), 1957-1969. (Invited Review)
Wen, B.; Ma, J.; Chen, C. C.; Ma, W. H.; Zhu H.; Zhao, J. C.*. Supported noble metal nanoparticles as photo/sono-catalysts for synthesis of chemicals and degradation of pollutants, Sci. China Chem., 54(6) (2011), 887-897.
Liu, G. L.; Yu C. L.; Chen, C. C.*; Ma, W. H.; Ji, H. W.; Zhao, J. C.*. A new type of covalent-functional graphene donor-acceptor hybrid andits improved photoelectrochemical performance, Sci. China Chem., 54(10)(2011), 1622-1626.
2010
Wang, Q.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Brønsted acid. Angew. Chem. Int. Ed., 49(43)(2010), 7976-7979.(inside cover paper)
Mu, Q.; Yang, L.; Davis, J. C.; Vankayala, R.; Hwang, K. C.; Zhao, J. C.; Yan, B. Biocompatibility of polymer grafted core/shell iron/carbon nanoparticles. Biomaterials, 31(19)(2010), 5083-5090.
Chen, C. C.; Ma, W. H.;Zhao, J. C.* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. Chem. Soc. Rev., 39(11)(2010), 4206-4219.（Invited Review）
Wen, B.; Li, Y.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* An unexplored O₂-involved pathway for the decarboxylation of saturated carboxylic acids by TiO₂ photocatalysis: An isotopic probe study. Chem.-Eur. J., 16(39)(2010), 11859-11866.（Cover Paper）
Feng, W.; Xiangfu, M.; Bin, W.; Junhua, Z.; Yanfen, D.; Shimin, Z.; Zhao, J. C.; Shaoren, L.; Mingshu, Y. Preparation and photocatalytic activity of PET/TiO₂ hybrid nanofibers via in-situ growth method. Chinese Sci. Bull., 55 (2010), 1873-1878.
Yang, J.; Dai, J.; Zhao, J. C.; Miao, J. Mechanism of photocatalytic degradation of dye MG by TiO₂-film electrode with cathodic bias potential. Chinese Sci. Bull., 55(2)(2010), 131-139.
Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic degradation of organic pollutants by co-doped TiO₂ under visible light irradiation. Curr. Org. Chem., 14(7)(2010), 630-644. （Invited Review）
Liu, H.; Zheng, Z.; Yang, D.; Ke, X.; Jaatinen, E.; Zhao, J. C.; Zhu, H. Y. Coherent interfaces between crystals in nanocrystal composites. ACS Nano, 4(10)(2010), 6219-6227.
Liu, J.; Liu, G.; Li, M.; Shen, W.; Liu, Z.; Wang, J.; Zhao, J. C.; Jiang, L.; Song, Y. Enhancement of photochemical hydrogen evolution over Pt-loaded hierarchical titania photonic crystal. Energy Environ. Sci., 3(10)(2010), 1503-1506.
Wang, Z. H.; Chen, X.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Photochemical cycling of iron mediated by dicarboxylates: Special effect of malonate. Environ. Sci. Technol., 44(1)(2010), 263-268.
Yu, C.; Zhang, Y.; Quan, X.; Chen, S.; Han, J.; Ou, X.; Zhao, J. C. Photochemical effect of humic acid components separated using molecular imprinting method applying porphyrin-like substances as templates in aqueous solution. Environ. Sci. Technol., 44(15)(2010), 5812-5817.
Chen, X.; Zheng, Z. F.; Ke, X. B.; Jaatinen, E.; Xie, T. F.; Wang, D. J.; Guo, C.; Zhao, J. C.; Zhu, H. Y. Supported silver nanoparticles as photocatalysts under ultraviolet and visible light irradiation. Green Chem., 12(3)(2010), 414-419.
Che, Y. K.; Yang, X.; Liu, G.; Yu, C.; Ji, H. W.; Zuo, J.; Zhao, J. C.*; Zang, L.* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives. J. Am. Chem. Soc., 132(16)(2010), 5743-5750.
Zheng, Z.; Liu, H.; Ye, J.; Zhao, J. C.; Waclawik, E. R.; Zhu, H. Structure and contribution to photocatalytic activity of the interfaces in nanofibers with mixed anatase and TiO₂(B) phases. J. Mol. Catal. A-Chem., 316(1-2)(2010), 75-82.
Wang, Y.; Zhao, D.; Ji, H. W.; Liu, G.; Chen, C. C.; Ma, W. H.; Zhu, H.; Zhao, J. C.* Sonochemical hydrogen production efficiently catalyzed by Au/TiO₂. J. Phys. Chem C, 114(41)(2010), 17728-17733.
2009
Zhang, M.; Wang, Q.; Chen, C. C.; Zang, L.; Ma, W. H.*; Zhao, J. C.* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies. Angew. Chem. Int. Ed., 48(33)(2009), 6081-6084.
Yang, J.; Dai, J.; Miao, J.; Li, J. T.; Zhao, J. C. Mechanism on photocatalytic degradation of benzoic acid with TiO₂-film electrode. Acta Chim. Sinica, 67(17)(2009), 1973-1980.
Zhang, L.; Wong, K.-H.; Chen, Z.; Yu, J. C.; Zhao, J. C.; Hu, C.; Chan, C.-Y.; Wong, P.-K. AgBr-Ag-Bi₂WO₆ nanojunction system: A novel and efficient photocatalyst with double visible-light active components. Appl. Catal. A- Gen, 363(1-2)(2009), 221-229.
Zhu, H.; Chen, X.; Zheng, Z.; Ke, X.; Jaatinen, E.; Zhao, J. C.; Guo, C.; Xie, T.; Wang, D. Mechanism of supported gold nanoparticles as photocatalysts under ultraviolet and visible light irradiation. Chem. Commun., (48)(2009), 7524-7526.
Wang, Q.; Chen, C.*; Ma, W. H.; Zhu, H.; Zhao, J. C.* Pivotal role of fluorine in tuning band structure and visible-light photocatalytic activity of nitrogen-doped TiO₂. Chem.-Eur. J., 15(19) (2009), 4765-4769.
Sun, C.; Zhao, D.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* TiO₂-Mediated photocatalytic debromination of decabromodiphenyl ether: Kinetics and intermediates. Environ. Sci. Technol., 43(1)(2009), 157-162.
Yang, D.; Liu, H.; Zheng, Z.; Yuan, Y.; Zhao, J. C.; Waclawik, E. R.; Ke, X.; Zhu, H. An efficient photocatalyst structure: TiO₂(B) nanofibers with a shell of anatase nanocrystals. J. Am. Chem. Soc., 131(49)(2009), 17885-17893.
Mahmood, T.; Chen, C. C.; Liu, L. L.; Zhao, D.; Ma, W. H.; Lin, J.; Zhao, J. C.* Effect of dye-metal complexation on photocatalytic decomposition of the dyes on TiO₂ under visible irradiation. J. Environ. Sci.-China, 21(2)(2009), 263-267.
Wang, Z.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Light-assisted decomposition of dyes over iron-bearing soil clays in the presence of H₂O₂. J.Hazard. Mater., 168(2-3)(2009), 1246-1252.
Zhao, D.; Chen, C.*; Yu, C.; Ma, W. H.; Zhao, J. C.* Photoinduced electron storage in WO₃/TiO₂ nanohybrid material in the presence of oxygen and postirradiated reduction of heavy metal ions. J. Phys. Chem. C, 113(30)(2009), 13160-13165.
Yang, J.; Dai, J.; Chen, C. C.; Zhao, J. C. Effects of hydroxyl radicals and oxygen species on the 4-chlorophenol degradation by photoelectrocatalytic reactions with TiO₂-film electrodes. J.Photochem. Photobio. A: Chem, 208(1)(2009), 66-77.
Zhao, D.; Sun, C.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photochemical degradation of organic pollutants polybrominated piphenyl ether congeners and cyanuric acid. Prog. Chem., 21(2009), 400-405.
Shang, Y.; Zhu, T.; Li, Y.; Zhao, J. C. Size-dependent hydroxyl radicals generation induced by SiO₂ ultra-fine particles: The role of surface iron. Sci. China Ser B: Chem., 52(7)(2009), 1033-1041.
2008
Zhang, M.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂ and TEMPO. Angew. Chem. Int. Ed., 47(50)(2008), 9730-9733.
Chen, X.; Zhu, H. Y.; Zhao, J. C., Zheng, Z. F.; Gao, X. P. Visible-light-driven oxidation of organic contaminants in air with gold nanoparticle catalysts on oxide supports. Angew. Chem. Int. Ed., 47(29)(2008), 5353-5356.
Cheng, M. M.; Song, W. J.; Ma, W. H.; Chen, C. C.; Zhao, J. C.*; Lin, J.; Zhu, H. Y. Catalytic activity of iron species in layered clays for photodegradation of organic dyes under visible irradiation. Appl. Catal. B-Environ., 77(3-4)(2008), 355-363.
Chang, Q. Y.; He, H.; Qu, J. H.; Zhao, J. C. Influencing factors in catalytically bactericidal process of Ag-Ce/AlPO₄ catalyst in water. Chinese J. Catal., 29(3)(2008), 215-220.
Wang, Z.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Photochemical coupling reactions between Fe(III)/Fe(II), Cr(VI)/Cr(III), and polycarboxylates: Inhibitory effect of Cr species. Environ. Sci. Technol., 42(19)(2008), 7260-7266.
Wang, Y.; Zhao, D.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Enhanced sonocatalytic degradation of azo dyes by Au/TiO₂. Environ. Sci. Technol., 42(16)(2008), 6173-6178.
Zhang, H.; Zong, R.; Zhao, J. C.; Zhu, Y. Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO₂ with PANI. Environ. Sci. Technol., 42(10)(2008), 3803-3807.
Chang, Q. Y.; He, H.; Zhao, J. C.; Yang, M.; Qu, J. H. Bactericidal activity of a Ce-promoted Ag/AIPO₄ catalyst using molecular oxygen in water. Environ. Sci. Technol., 42(5)(2008), 1699-1704.
Zhao, D.; Chen, C.*; Wang, Y.; Ma, W. H.; Zhao, J. C.*; Rajh, T.; Zang, L. Enhanced photocatalytic degradation of dye pollutants under visible irradiation on Al(III)-modified TiO₂: Structure, interaction, and interfacial electron transfer. Environ. Sci. Technol., 42(1)(2008), 308-314.
Zhao, D.; Chen, C. C.*; Wang, Y. F.; Ji, H. W.; Ma, W. H.; Zang, L.; Zhao, J. C.* Surface modification of TiO₂ by phosphate: Effect on photocatalytic activity and mechanism implication. J. Phys. Chem. C, 112(15)(2008), 5993-6001.
Wang, Q.; Chen, C.*; Zhao, D.; Ma, W. H.; Zhao, J. C.* Change of adsorption modes of dyes on fluorinated TiO₂ and its effect on photocatalytic degradation of dyes under visible irradiation. Langmuir, 24(14) (2008), 7338-7345.
Liu, L. L.; Chen, C. C.; Hu, X. F.; Mohamood, T.; Ma, W. H.; Lin, J.; Zhao, J. C.* A role of ionic liquid as an activator for efficient olefin epoxidation catalyzed by polyoxometalate. New J. Chem., 32(2)(2008), 283-289.
Ding, X. J.; An, T. C.; Li, G. Y.; Chen, J. X.; Sheng, G. Y.; Fu, J. M.; Zhao, J. C. Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO₂ pillared montmorillonite photocatalyst. Res.Chem. Intermediat., 34(1)(2008), 67-83.

科研成果
授权专利
荣誉获奖

科研成果
荣获奖励
2005年获国家自然科学二等奖
2010年获日本光化学协会"Lectureship Award for Asian and OceanianPhotochemist"奖
2002年获中科院-拜尔（德国）青年科学家奖
2002年获北京市科技进步（自然科学）一等奖
2002年获军队科技进步二等奖
2013年获中国科学院朱李月华优秀教师奖
1999、2002、2006年分别获得中科院优秀研究生导师奖
授权发明专利
车延科; 刘阿楠; 章宇超; 宋文静; 赵进才; 马万红; 陈春城; 籍宏伟。一种硼掺杂三氧化二铁光电极的制备方法。专利号：ZL 9.0。
赵进才; 龚原正; 籍宏伟; 陈春城; 马万红。一种利用光催化实现胺类化合物N-甲基化的方法。专利号：ZL 1.8。
赵进才; 籍宏伟; 马万红; 陈春城; 车延科; 宋文静。一种光催化原位表征系统。专利号：ZL 4.2。
赵进才; 马东阁; 刘阿楠; 陈春城; 籍宏伟。一种醇脱氢制醛酮的光化学氧化方法。专利号：ZL 0.7。
车延科; 胡艳勇; 赵进才。对有机胺类气体具有荧光响应的一维有机半导体纳米管及其制备方法和应用。专利号：ZL 2.4。
赵进才; 彭澄; 车延科。一维有机半导体纳米管及其制备方法和应用。专利号：ZL 7.6。
赵进才; 吕艳阳; 陈春城; 马万红; 籍宏伟。一种在纳米赤铁矿表面形成的Fe-O活性物种及其制备方法和应用。专利号：ZL 7.9。
赵进才; 常巍; 马万红; 籍宏伟; 陈春城。一种强还原性纳米材料的制备方法及其在地下水污染处理中的应用。专利号：ZL 9.2。
车延科; 马小杰; 张义斌; 张一帆; 赵进才。一维有机半导体纳米管及其制备方法和应用。专利号：ZL 3.5。
赵进才; 马万红; 闫研; 籍宏伟; 陈春城; 车延科。纯化SiCl4和/或SiHCl3的粗品的液固相光催化净化方法。专利号：ZL 5.X。
车延科; 张一帆; 鄂月; 马小杰; 籍宏伟; 赵进才。对有机胺类气体具有荧光响应的一维有机半导体螺旋纳米线及其制备方法和应用。专利号：ZL 1.2。
车延科; 张义斌; 赵进才。1, 7-二氰基修饰的苝酰亚胺的衍生物及其制备方法。专利号：ZL 9.6。
车延科; 张一帆; 庞喜斌; 籍宏伟; 赵进才。单分散性的激光响应光致移动的一维有机半导体微米带及其制备方法和应用。专利号：ZL 3.3。
车延科; 张一帆; 周子超; 籍宏伟; 赵进才。对有机胺类气体具有荧光和光电导双响应的一维有机半导体纳米线及其制备方法和应用。专利号：ZL 5.2。
赵进才; 王颖; 陈春城; 籍宏伟; 马万红。一种卤素转换反应制备氯代芳香化合物的光化学合成方法。专利号：ZL 2.3。
赵进才; 孙亦然; 李悦; 陈春城; 籍宏伟。一种环氧化合物脱氧制烯烃的光化学还原方法。专利号：ZL 5.4。
赵进才; 程实; 马万红; 籍宏伟; 陈春城。具有选择性氧化二级碳氢键的配位键合的铁配合物光催化剂及其制备方法和应用。专利号：ZL 9.7。
赵进才; 师涛; 籍宏伟; 陈春城; 马万红。一种利用光催化选择性氧化醛合成酸的方法。专利号：ZL 1.6。
赵进才; 李骎; 籍宏伟; 陈春城; 马万红。有机蒽醌染料敏化负载贵金属的无机半导体可见光光催化剂及其制备方法和应用。专利号：ZL 4.7。
赵进才; 籍宏伟; 马万红; 陈春城。多级连续式光催化水净化反应器。专利号：ZL 0.5。
赵进才; 马万红; 陈希; 籍宏伟; 陈春城。共价键合的具有广谱配位功能的固体光催化前躯体材料及应用。专利号：ZL 7.3。
赵进才; 刘桂林; 陈春城; 籍宏伟; 马万红。膜状结构的有机半导体可见光光催化剂及其制法和应用。专利号：ZL 8.1。
赵进才; 孙春燕; 陈春城; 马万红。用羧酸或羧酸盐降解有机卤代物的光化学还原方法。专利号：ZL 2.2。
赵进才; 余春; 王齐; 马万红; 陈春城。利用光催化选择性氧化一级醇或二级醇制备醛或酮的方法。专利号：ZL 0.1。
赵进才，塔里克，王齐，籍宏伟，陈春城，马万红；无需外加还原剂和牺牲剂的处理含铬废水的光化学还原方法；专利号：ZL 2008 1 **.5。
赵进才王一峰赵丹马万红陈春城；超声波催化降解有机污染物的方法；专利号：ZL 9.4。
赵进才，杨娟，张苗，马万红，陈春城，张新志，钱新华，张士博；表面修饰有助催化剂的半导体TiO2光催化剂及其制备方法和用途；专利号：ZL 3.4。
赵进才，籍宏伟，马万红，陈春城，张新志；类氢醌体构筑非氮铁配合物的可见光光催化剂和用途；专利号：ZL 0.4。
赵进才，马家海, 马万红, 陈春城；固相催化助剂及其制备方法和用途；专利号：ZL 7.X。
赵进才、陈春城、籍宏伟，张新志；石油产品的一种催化氧化脱硫方法；专利号：ZL2005 1 **.0。
赵进才，程明明，马万红，陈春城，钱新华，张士博；一种光催化降解有机污染物的方法及其专用固相光催化剂；专利号：ZL 6.X。
赵进才，车延科，马万红；用氧气光氧化烷基苯制备芳香醛和酸的方法；专利号：ZL 8.X。
赵进才，车延科，马万红，张士博，钱新华；酯类反应性溶剂制备碘化N-甲基喹啉类化合物的方法；专利号：ZL 2.4。
赵进才，任岩军，马万红，钱新华，张士博；一种烯烃合成含氧化合物的光化学方法；专利号：ZL 6.4。
赵进才，赵伟，马万红；具有可见光响应的光催化剂及其制备方法和应用；专利号：ZL **.2。
赵进才，陈锋；可见光催化净化空气及杀菌的有机基底双层膜及其制法；专利号：ZL **.8。
赵进才，马万红，李静；一种固相可见光仿生催化剂及其制备方法；专利号：ZL **.8。
赵进才，马万红；一种固相光催化剂及其制备方法；专利号：ZL **.6。
赵进才，张天永；可连续均相光氧化净化含有机污染物的方法及设备；专利号：ZL **.3。
赵进才，陈锋，何建军；可磁分离的光催化剂及其制法；专利号：ZL**.4。
赵进才，陈锋。可光催化净化空气及杀菌的有机基底双层膜及其制法；专利号：申请号：**.8
赵进才，陈锋，何建军；多层包膜的可磁分离的光催化剂及其制法；专利号：ZL **.8。
赵进才，张天永；可连续光催化净化含有机污染物废水及饮用水的方法及设备；专利号：ZL **.2。

科研成果
授权专利
荣誉获奖

授权发明专利
车延科; 刘阿楠; 章宇超; 宋文静; 赵进才; 马万红; 陈春城; 籍宏伟。一种硼掺杂三氧化二铁光电极的制备方法。专利号：ZL 9.0。
赵进才; 龚原正; 籍宏伟; 陈春城; 马万红。一种利用光催化实现胺类化合物N-甲基化的方法。专利号：ZL 1.8。
赵进才; 籍宏伟; 马万红; 陈春城; 车延科; 宋文静。一种光催化原位表征系统。专利号：ZL 4.2。
赵进才; 马东阁; 刘阿楠; 陈春城; 籍宏伟。一种醇脱氢制醛酮的光化学氧化方法。专利号：ZL 0.7。
车延科; 胡艳勇; 赵进才。对有机胺类气体具有荧光响应的一维有机半导体纳米管及其制备方法和应用。专利号：ZL 2.4。
赵进才; 彭澄; 车延科。一维有机半导体纳米管及其制备方法和应用。专利号：ZL 7.6。
赵进才; 吕艳阳; 陈春城; 马万红; 籍宏伟。一种在纳米赤铁矿表面形成的Fe-O活性物种及其制备方法和应用。专利号：ZL 7.9。
赵进才; 常巍; 马万红; 籍宏伟; 陈春城。一种强还原性纳米材料的制备方法及其在地下水污染处理中的应用。专利号：ZL 9.2。
车延科; 马小杰; 张义斌; 张一帆; 赵进才。一维有机半导体纳米管及其制备方法和应用。专利号：ZL 3.5。
赵进才; 马万红; 闫研; 籍宏伟; 陈春城; 车延科。纯化SiCl4和/或SiHCl3的粗品的液固相光催化净化方法。专利号：ZL 5.X。
车延科; 张一帆; 鄂月; 马小杰; 籍宏伟; 赵进才。对有机胺类气体具有荧光响应的一维有机半导体螺旋纳米线及其制备方法和应用。专利号：ZL 1.2。
车延科; 张义斌; 赵进才。1, 7-二氰基修饰的苝酰亚胺的衍生物及其制备方法。专利号：ZL 9.6。
车延科; 张一帆; 庞喜斌; 籍宏伟; 赵进才。单分散性的激光响应光致移动的一维有机半导体微米带及其制备方法和应用。专利号：ZL 3.3。
车延科; 张一帆; 周子超; 籍宏伟; 赵进才。对有机胺类气体具有荧光和光电导双响应的一维有机半导体纳米线及其制备方法和应用。专利号：ZL 5.2。
赵进才; 王颖; 陈春城; 籍宏伟; 马万红。一种卤素转换反应制备氯代芳香化合物的光化学合成方法。专利号：ZL 2.3。
赵进才; 孙亦然; 李悦; 陈春城; 籍宏伟。一种环氧化合物脱氧制烯烃的光化学还原方法。专利号：ZL 5.4。
赵进才; 程实; 马万红; 籍宏伟; 陈春城。具有选择性氧化二级碳氢键的配位键合的铁配合物光催化剂及其制备方法和应用。专利号：ZL 9.7。
赵进才; 师涛; 籍宏伟; 陈春城; 马万红。一种利用光催化选择性氧化醛合成酸的方法。专利号：ZL 1.6。
赵进才; 李骎; 籍宏伟; 陈春城; 马万红。有机蒽醌染料敏化负载贵金属的无机半导体可见光光催化剂及其制备方法和应用。专利号：ZL 4.7。
赵进才; 籍宏伟; 马万红; 陈春城。多级连续式光催化水净化反应器。专利号：ZL 0.5。
赵进才; 马万红; 陈希; 籍宏伟; 陈春城。共价键合的具有广谱配位功能的固体光催化前躯体材料及应用。专利号：ZL 7.3。
赵进才; 刘桂林; 陈春城; 籍宏伟; 马万红。膜状结构的有机半导体可见光光催化剂及其制法和应用。专利号：ZL 8.1。
赵进才; 孙春燕; 陈春城; 马万红。用羧酸或羧酸盐降解有机卤代物的光化学还原方法。专利号：ZL 2.2。
赵进才; 余春; 王齐; 马万红; 陈春城。利用光催化选择性氧化一级醇或二级醇制备醛或酮的方法。专利号：ZL 0.1。
赵进才，塔里克，王齐，籍宏伟，陈春城，马万红；无需外加还原剂和牺牲剂的处理含铬废水的光化学还原方法；专利号：ZL 2008 1 **.5。
赵进才王一峰赵丹马万红陈春城；超声波催化降解有机污染物的方法；专利号：ZL 9.4。
赵进才，杨娟，张苗，马万红，陈春城，张新志，钱新华，张士博；表面修饰有助催化剂的半导体TiO2光催化剂及其制备方法和用途；专利号：ZL 3.4。
赵进才，籍宏伟，马万红，陈春城，张新志；类氢醌体构筑非氮铁配合物的可见光光催化剂和用途；专利号：ZL 0.4。
赵进才，马家海, 马万红, 陈春城；固相催化助剂及其制备方法和用途；专利号：ZL 7.X。
赵进才、陈春城、籍宏伟，张新志；石油产品的一种催化氧化脱硫方法；专利号：ZL2005 1 **.0。
赵进才，程明明，马万红，陈春城，钱新华，张士博；一种光催化降解有机污染物的方法及其专用固相光催化剂；专利号：ZL 6.X。
赵进才，车延科，马万红；用氧气光氧化烷基苯制备芳香醛和酸的方法；专利号：ZL 8.X。
赵进才，车延科，马万红，张士博，钱新华；酯类反应性溶剂制备碘化N-甲基喹啉类化合物的方法；专利号：ZL 2.4。
赵进才，任岩军，马万红，钱新华，张士博；一种烯烃合成含氧化合物的光化学方法；专利号：ZL 6.4。
赵进才，赵伟，马万红；具有可见光响应的光催化剂及其制备方法和应用；专利号：ZL **.2。
赵进才，陈锋；可见光催化净化空气及杀菌的有机基底双层膜及其制法；专利号：ZL **.8。
赵进才，马万红，李静；一种固相可见光仿生催化剂及其制备方法；专利号：ZL **.8。
赵进才，马万红；一种固相光催化剂及其制备方法；专利号：ZL **.6。
赵进才，张天永；可连续均相光氧化净化含有机污染物的方法及设备；专利号：ZL **.3。
赵进才，陈锋，何建军；可磁分离的光催化剂及其制法；专利号：ZL**.4。
赵进才，陈锋。可光催化净化空气及杀菌的有机基底双层膜及其制法；专利号：申请号：**.8
赵进才，陈锋，何建军；多层包膜的可磁分离的光催化剂及其制法；专利号：ZL **.8。
赵进才，张天永；可连续光催化净化含有机污染物废水及饮用水的方法及设备；专利号：ZL **.2。

科研成果
授权专利
荣誉获奖

获奖
2005年获国家自然科学二等奖（第一完成人）
2010年获日本光化学协会“Lectureship Award for Asian and OceanianPhotochemist”奖（个人国际奖项）
2002年获中科院-拜尔（德国）青年科学家奖
2002年获北京市科技进步（自然科学）一等奖
2002年获军队科技进步二等奖
2013年获中国科学院朱李月华优秀教师奖
1999、2002、2006年分别获得中科院优秀研究生导师奖

仪器设备

气质联用仪
Thermo Trace DSQ
液质联用仪
Agilent 6310 Ion Trap

膜质谱
Agilent 5975C
红外/质谱联用
Hicube™RGA
总有机碳测定仪
AnalytikJena 2100

半制备色谱
Agilent 1260
离子色谱
DIONEX 120
气相色谱（FPD）
HITACHI GC-3900
液相色谱（DAD）
Agilent 1200
反射红外光谱
Nicolet 6700

气相色谱（μ-ECD）
Agilent 7890
漫反射吸收光谱
HITACHI G-3010
液相色谱（VWD）
SHIMADZU LC20
电化学分析仪
EGεG 283
光解水装置
AULTT CEL-SPH2N

Principle Investigator

Professor Jincai Zhao, Academician of CAS

Contact
Zhongguancun North First Street 2
Beijing, 100190, PR China
Institute of Chemistry,CAS
Group of Photocatalysis and Environmental Photochemistry
Tel：
Fax：
Email：jczhao@iccas.ac.cn

Links
Institute of Chemistry,CAS
National Science Library, CAS
Academic Search Engines
ISI Web of Science
Ministry of Sciece and Technology or P.R.China

Introduction
The environmental problems caused by organic pollutants are becoming more and more serious all over the world. The interests of our group are focused on the novel approaches for the photodegradation of environmental pollutants, photochemical cycling of iron species and the relative environmental photochemical processes, novel photochemical approaches for the detection of trace hazardous compounds, and photocatalytic selective oxidation of organic compounds. We have published over 300 papers in well-known international journals, such as J. Am. Chem. Soc., Environ. Sci. Technol., Angew. Chem. Int. Ed., and have more than 28000 citations by others（H-index, 83）. We have been awarded with several prizes such as the Second Grade National Prize of Natural Science of China (2005), the Japanese Photochemistry Association Lectureship Award for Asian and Oceanian Photochemist (2010) and the Award of Excellent Young Scientists of Chinese Academy of Sciences- Bayer (2002, Germany). Team members include 6 professors, 1associate professors, 2 postdoctors and 36 graduatestudents.

Latest Research Progress
Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of ¹O₂ The photochemical aging of soot in the aqueous phase could have an important influence on water environments such as fog water and wet aerosols in the atmosphere, as well as lakes and oceans. In this study, we systematically investigated the photochemistry of soot in the aqueous phase. Soot releases dissolved black carbon into the aqueous phase during photoreactions, which is attributed to the phototransformation of the nonpolar unsaturated C-H species in soot to polar carbonyl-containing species. More importantly, we found that soot suspensions, particularly those of the dissolved part of soot, were effective photosensitizers for the generation of singlet oxygen (¹O₂). The ¹O₂ apparent quantum yield of the dissolved part reached 33 ± 2% under 377 nm irradiation, which is an order of magnitude higher than those of most types of well-studied dissolved organic matter in water. As a result, soot could impact the environmental fate of coexisting organic contaminants, such as the photodegradation of bisphenol A. This study will not only give insight into the photochemistry of soot in the liquid phase but also reveal the significant implications of soot photoaging in the aqueous phase by the release and degradation of organic matter. （Environmental Science & Technology, 2019, DOI:10.1021/acs.est.9b02773）

Research Progress
名称日期

Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of 1O2 2019-09-30
Nitrate Enhanced Oxidation of SO2 on Mineral Dust: A Vital Role of Proton 2019-08-25
Proton-free electron-trapping feature of titanium dioxide nanoparticles without the characteristic blue color 2019-07-30
Elemental Carbon in the Photochemical Aging of Soot 2018-07-24
Photochemical Aging of Beijing Urban PM2.5: HONO Production 2018-05-25

更多

Research Interests
New Methods and Principles of Photocatalytic Degradation of Organic Pollutants
Study onSurface Photochemical Process of Atmospheric Particulate matter
Nano-materials and Photocatalysis
Novel Photochemical Approaches for the Detection ofTrace Hazardous Compounds
Photocatalytic Organic Synthesis

Group Members
Principle Investigator
Faculty Wanhong Ma
Chuncheng Chen
Yanke Che
Wenjing Song
Hua Sheng
Yuchao Zhang
Hongwei Ji
Graduate Students
Graduated

Group Members
Group members include 6 professors, 1 associate professors, 2 postdoctors, 36 graduate students.

Group Members
Principle Investigator
Faculty Wanhong Ma
Chuncheng Chen
Yanke Che
Wenjing Song
Hua Sheng
Yuchao Zhang
Hongwei Ji
Graduate Students
Graduated

Jincai Zhao

Resume
1994: Ph. D. Meisei University Japan
1996: A full professor, Institute of Photographic Chemistry
1999-Present: A full Professor, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry CAS; Deputy Director of Key Laboratory of Photochemistry; Deputy Director of Research Center for Energy and Green Chemistry
2011: Has been elected as an Academician of the Chinese Academy of Sciences.
Research Interests and Awards
His research focuses on semiconductor photocatalytic degradation of organic pollutants and the mechanism; photodegradation of organic pollutants via activation of O₂or H₂O₂ by transition metal complexes; photochemical cycling of iron species and the relative environmental processes; photocatalytic selective oxidation of organic compounds; photofunctional nanomaterials. He has published over 220 papers on the international journals such as J. Am. Chem. Soc., Angew. Chem. Int. Ed., Environ. Sci. Technol., Chem. Soc. Rev. and has 23 authorized invention patents. The publications have been cited over 11000 times by others. The selected awards are as follows:
2005 The Second Grade National Prize of Natural Science of China (the first contributor);
2010 Japanese Photochemistry Association Lectureship Award for Asian and Oceanian Photochemist;
2002 The Award of Excellent Young Scientist of Chinese Academy of Sciences-Bayer (Germany);
2002 The First Grade Prize of Science and Technology in Beijing (Natural Science)
2002 The Second Grade Military progress prize in science and technology
1997 National Natural Science Fund for Distinguished Young Scientists
1999, 2002, 2006 The Award of Excellent Advisor of Graduates of CAS

Academic Activities
Be a member of:
Editorial Advisory Board of Environmental Science & Technology (ACS, IF=5.257);
Advisory Board of Energy& Environmental Science (RSC, IF=11.653);
International Advisory Board of ChemCatChem (IF=5.181);
Editorial Advisory Board of ChemPhysChem (IF=3.349);
Editorial Board of Catalysis Communications (IF=2.915);
Editorial Board of International Journal of Photoenergy (IF=2.663);
International Editorial Advisory Board of Journal of Advanced Oxidation Technologies (IF=0.946).
Associate Editor of Acta Scientiae Circumstantiae (Chinese);
Associate Editor of Environmental Chemistry (Chinese);
Projects
National Key Scientific Research Project (Principal Scientist); 863 Project; Key Project and International Cooperation Project of National Natural Science Foundation of China; Major Project of the Chinese Academy of Sciences; Knowledge Innovation Project of the Chinese Academy of Sciences; China National Natural Science Funds for Distinguished Young Scientists.

Group Members
Principle Investigator
Faculty Wanhong Ma
Chuncheng Chen
Yanke Che
Wenjing Song
Hua Sheng
Yuchao Zhang
Hongwei Ji
Graduate Students
Graduated

Faculty

Wanhong MaChuncheng Chen Yanke Che Wenjing Song Hua Sheng

Yuchao Zhang Hongwei Ji

网站地图
Principle Investigator
Faculty Wanhong Ma
Chuncheng Chen
Yanke Che
Wenjing Song
Hua Sheng
Yuchao Zhang
Hongwei Ji
Graduate Students
Graduated

Graduate Students
Qin Li
Hua Sheng
Lina Li

Shi Cheng
Ying Wang

Wei Chang

Xinben Pang

Tao Shi

Dongge Ma
Yuchao Zhang

Yifan Zhang
Yuanzheng Gong
Yanyang Lv
Cheng Peng
Hongna Zhang
Zichao Zhou

Group Members
Principle Investigator
Faculty Wanhong Ma
Chuncheng Chen
Yanke Che
Wenjing Song
Hua Sheng
Yuchao Zhang
Hongwei Ji
Graduate Students
Graduated

Graduated
Feng Chen, Guangming Liu, Jianjun He, Ping Qu, Taixing Wu, Kaiqun Wu, Tianyong Zhang, Yingping Huang, Yinde Xie, Xiangzhong Li, Xia Tao, Jingyi Li, Chuncheng Chen, Ju He, Jing Li, Pengxiang Lei, Mingming Cheng, Wenjing Song, Lili Liu, Jiahai Ma, Dan Zhao, Hongwei Ji, Mohammed Tariq, Ran Duan, Zhaohui Wang, Miao Zhang, Qi Wang, Chunyan Sun, Guilin Liu, Bo Wen, Xianjun Lang, Sheng Wen, Fenglei Zhang, Wanhong Ma, Wei Zhao, Hong Yuan, Yanjun Ren, Yanke Che, Xuefeng Hu, Juan Yang, Xi Chen, Chun Yu, Yubao Zhao, Yue Li, Yiran Sun, Ning Li, Xiaoxiao Yu, Changjun Yang, Qifeng, Chen, Guibao Guo, Xiaofeng Cao
Feng Liu, Chengzhi Guo, Haibo Liu, Xuesong Wang, Xiaoping Wang, Shuping Yu, Zhenying Sun, Ye Feng, Jing Wang, Junbo Guo, Yongliang Xia, Fengli Xue, Liyang Zhuo, Xiaohong Lai, Yele Sun, Guofeng Zheng, Huayuan Liu, Xingang Liu, Jun Chen, Ying Fan, Chen Guan, Fei Wang, Wei Wu, Guannan Liu

Publications
Selected Publications
2017-2019
2008-2016

Publications
Having published over 300 papers in well-known international journals, such as J. Am. Chem. Soc., Environ. Sci. Technol., Angew. Chem. Int. Ed., and has more than 28000 citations by others.
?
Cover Papers

Selected Publication
Lang, X. J.;W. H. Ma; C. C. Chen; H. W. Ji;J. C. Zhao*. Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res.2014, 47(2), 355–363.
C. C. Chen; W. H. Ma; J. C. Zhao* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation.Chem. Soc. Rev.2010, 39, 4206-4219.
Meng Li, Fengxia Bao, Yue Zhang, Wenjing Song, Chuncheng Chen*, Jincai Zhao. Role of Elemental Carbon in the Photochemical Aging of Soot.Proc. Natl. Acad. Sci.USA,2018, 115, 30, 7717-7722
Zhang, Yuchao; Zhang, Hongna; Liu, Anan; Chen, Chuncheng*; Song, Wenjing*; Zhao, Jincai. Rate-?Limiting O-?O Bond Formation Pathways for Water Oxidation on Hematite Photoanode.J. Am. Chem. Soc.,2018, 140(9), 3264-3269
Yan Yan, Weidong Shi, Zhen Yuan, Shenggui He, Dongmei Li, Qingbo Meng, Hongwei Ji, Chuncheng Chen, Wanhong Ma*, Jincai Zhao* The Formation of Ti–H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices.J. Am. Chem. Soc.2017, 139, 2083-2089
Yuchao Zhang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, and Jincai Zhao*. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes.J. Am. Chem. Soc., 2016, 138 (8), 2705–2711
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O.J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Ma, Xiaojie; Zhang, Yibin; Zhang, Yifan; Liu, Yin; Che, Yanke*; Zhao, Jincai. Fabrication of Chiral-?Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization.Angew. Chem. Int. Ed.2016, 55(33), 9539-9543.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway.Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study.Angew. Chem. Int. Ed.2015, 54, 5905-5909
W. Zhao; W. H. Ma; C. C. Chen; J. C. Zhao* and Z. G. Shuai Efficient degradation of toxic organic pollutants with Ni₂O₃/TiO_2-xB_xunder visible irradiation.J. Am. Chem. Soc.2004, 126, 4782-4783.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway.Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen,* Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study.Angew. Chem. Int. Ed.2015, 54, 5905-5909
Y. Li, H. Ji, C. Chen*, W. Ma, J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640.
Sheng, H.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Direct Four-Electron Reduction of O₂to H₂O on TiO₂Surface by Pendant Proton Relay.Angew. Chem. Int. Ed., 2013,52, 9686 –9690.
Y. B. Zhao; W. H. Ma; Y. Li; H. Ji; C. C. Chen; H. Zhu; J. C. Zhao* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction.Angew. Chem. Int. Ed., 2012, 51(13), 3188 –3192.
Q. Wang; M. Zhang; C. C. Chen; W. H. Ma; J. C. Zhao* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Bronsted acid.Angew. Chem. Int. Ed.2010, 49, 7976-7979. (Very Important Paper, Inside Cover Paper)
Y. K. Che;X. M. Yang; G. Liu; C. Yu; H. W. Ji; J. Zuo; J. C. Zhao*; L. Zang* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives.J. Am. Chem. Soc.,2010, 132(16), 5743-5750.
M. Zhang; Q. Wang; C. C. Chen; L. Zang; W. H. Ma*; J. C. Zhao* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies.Angew. Chem. Int. Ed.2009,48, 6081-6084. (Highly Important Paper, Cover Paper)
M. Zhang; C. C. Chen; W. H. Ma*; J. C. Zhao* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂and TEMPO.Angew. Chem. Int. Ed.2008, 47, 9730-9733. (Hot Paper)

Publications
Selected Publications
2017-2019
2008-2016

Selected Publicaitons
Lang, X. J.;W. H. Ma; C. C. Chen; H. W. Ji;J. C. Zhao*. Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res. 2014, 47(2), 355–363.
C. C. Chen; W. H. Ma; J. C. Zhao* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation.Chem. Soc. Rev. 2010, 39, 4206-4219.
Meng Li, Fengxia Bao, Yue Zhang, Wenjing Song, Chuncheng Chen*, Jincai Zhao. Role of Elemental Carbon in the Photochemical Aging of Soot. Proc. Natl. Acad. Sci. USA, 2018, 115, 30, 7717-7722
Zhang, Yuchao; Zhang, Hongna; Liu, Anan; Chen, Chuncheng*; Song, Wenjing*; Zhao, Jincai. Rate-?Limiting O-?O Bond Formation Pathways for Water Oxidation on Hematite Photoanode. J. Am. Chem. Soc.,2018, 140(9), 3264-3269
Yan Yan, Weidong Shi, Zhen Yuan, Shenggui He, Dongmei Li, Qingbo Meng, Hongwei Ji, Chuncheng Chen, Wanhong Ma*, Jincai Zhao* The Formation of Ti–H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices. J. Am. Chem. Soc. 2017, 139, 2083-2089
Yuchao Zhang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, and Jincai Zhao*. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes. J. Am. Chem. Soc., 2016, 138 (8), 2705–2711
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O. J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Ma, Xiaojie; Zhang, Yibin; Zhang, Yifan; Liu, Yin; Che, Yanke*; Zhao, Jincai. Fabrication of Chiral-?Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization. Angew. Chem. Int. Ed. 2016, 55(33), 9539-9543.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂ Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed. 2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao. Activation of Water in TiO₂ Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study. Angew. Chem. Int. Ed.2015, 54, 5905-5909
Hai-Ying Jiang, Peng Zhou, Yuanyuan Wang, Chuncheng Chen, Wenjing Song*, and Jincai Zhao. Copper-Based Coordination Polymer Nanostructure for Visible Light Photocatalysis. Adv. Mater. 2016, 28 (44), 9776–9781
Yifan Zhang, Cheng Peng, Bin Cui, Zhengfei Wang, Xibin Pang, Renmin Ma, Feng Liu*, Yanke Che*, Jincai Zhao. Direction-Controlled Light-Driven Movement of Microribbons. Adv. Mater. 2016, 28 (38), 8538–8545
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers. Adv. Mater. 2015, 27, 320–325.
Xiaojie Ma, Yibin Zhang, Yifan Zhang, Cheng Peng, Yanke Che* Jincai Zhao. Stepwise Formation of Photoconductive Nanotubes through a New Top-Down Method.Adv. Mater. 2015, 27, 7746–7751
Yuchao Zhang, Shiqi Jiang, Wenjing Song, Peng Zhou, Hongwei Ji, Wanhong Ma, Weichang Hao, Chuncheng Chen* and Jincai Zhao. Nonmetal P-doped hematite photoanode with enhanced electron mobility and high water oxidation activity. Energy Environ. Sci. 2015,8, 1231-1236
W. Zhao; W. H. Ma; C. C. Chen; J. C. Zhao* and Z. G. Shuai Efficient degradation of toxic organic pollutants with Ni₂O₃/TiO_2-xB_x under visible irradiation. J. Am. Chem. Soc. 2004, 126, 4782-4783. (Top paper selected by ISI Web of Knowledge, 950 citations by others)
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen,* Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study. Angew. Chem. Int. Ed.2015, 54, 5905-5909
Y. Li, H. Ji, C. Chen*, W. Ma, J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂ Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640.
Sheng, H.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Direct Four-Electron Reduction of O₂ to H₂O on TiO₂ Surface by Pendant Proton Relay. Angew. Chem. Int. Ed., 2013,52, 9686 –9690.
Y. B. Zhao; W. H. Ma; Y. Li; H. Ji; C. C. Chen; H. Zhu; J. C. Zhao* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction. Angew. Chem. Int. Ed., 2012, 51(13), 3188 –3192.
Q. Wang; M. Zhang; C. C. Chen; W. H. Ma; J. C. Zhao* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Bronsted acid. Angew. Chem. Int. Ed. 2010, 49, 7976-7979. (Very Important Paper, Inside Cover Paper)
Y. K. Che;X. M. Yang; G. Liu; C. Yu; H. W. Ji; J. Zuo; J. C. Zhao*; L. Zang* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives. J. Am. Chem. Soc., 2010, 132(16), 5743-5750.
M. Zhang; Q. Wang; C. C. Chen; L. Zang; W. H. Ma*; J. C. Zhao* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies. Angew. Chem. Int. Ed. 2009,48, 6081-6084. (Highly Important Paper, Cover Paper)
M. Zhang; C. C. Chen; W. H. Ma*; J. C. Zhao* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂ and TEMPO. Angew. Chem. Int. Ed. 2008, 47, 9730-9733. (Hot Paper)
X. J. Lang; H. W.Ji; C. C. Chen; W. H. Ma; J. C. Zhao* Selective formation of imines via aerobic photocatalytic oxidation of amines on TiO₂. Angew. Chem. Int. Ed.,2011, 50(17), 3934-3937.(Very Important Paper)
W. H. Ma; J. Li; X. Tao; J. He; Y. M. Xu; J. C. Yu; J. C. Zhao* Efficient degradation of organic pollutants by using dioxygen activated by resin-exchanged iron(II) bipyridine under visible irradiation. Angew. Chem. Int. Ed. 2003, 42, 1029-1032.

网站地图
Selected Publications
2017-2019
2008-2016

2017-2019
2019 Li, Meng; Bao, Fengxia; Zhang, Yue; Sheng, Hua; Chen, Chuncheng*; Zhao, Jincai. Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of ¹O₂. Environmental Science & Technology, 2019, DOI:10.1021/acs.est.9b02773.
Zhang, Yue; Bao, Fengxia; Li, Meng; Chen, Chuncheng*; Zhao, Jincai. Nitrate Enhanced Oxidation of SO₂ on Mineral Dust: A Vital Role of Proton. Environmental Science & Technology, 2019, 53, 10139?10145
Yan Yan, Weidong Shi, Wei Peng, Yuhan Lin, Chunxi Zhang, Lailai Li, Young Sun, Huanxin Ju, Junfa Zhu, Wanhong Ma*, Jincai Zhao*. Proton-free electron-trapping feature of titanium dioxide nanoparticles without the characteristic blue color. Communications Chemistry. 2019, 88. DOI: s42004-019-0191-7
Yu, Xinting; Gong, Yanjun; Xiong, Wei; Li, Mei*; Zhao, Jincai; Che, Yanke*. Turn-?on Fluorescent Detection of Hydrogen Peroxide and Triacetone Triperoxide via Enhancing Interfacial Interactions of a Blended System. Anal. Chem. 2019, 91, 6967?6970
Qiu, Changkun; Liu, Xiaoling; Cheng, Chuanqin; Gong, Yanjun; Xiong, Wei; Guo, Yongxian; Wang, Chen; Zhao, Jincai; Che, Yanke*. Ultrasensitive Detection of Sulfur Mustard via Differential Noncovalent Interactions. Anal. Chem. 2019, 91, 6408?6412
Xiong, Wei; Gong, Yanjun; Che, Yanke*; Zhao, Jincai. Sensitive Discrimination of Nerve Agent and Sulfur Mustard Simulants Using Fluorescent Coassembled Nanofibers with Fo?rster Resonance Energy Transfer-?Enhanced Photostability and Emission. Anal. Chem. 2019, 91, 1711?1714
Liu, Xiaoling; Gong, Yanjun; Xiong, Wei; Cui, Linfeng; Hu, Ke; Che, Yanke*; Zhao, Jincai. Highly Selective Detection of Benzene, Toluene, and Xylene Hydrocarbons Using Coassembled Microsheets with Fo?rster Resonance Energy Transfer-?Enhanced Photostability. Anal. Chem. 2019, 91, 768?771
Hu, Ke; Liu, Yin; Xiong, Wei; Gong, Yanjun; Che, Yanke*; Zhao, Jincai. Fabrication of Single-?Handed Nanocoils with Controlled Length via a Living Supramolecular Self-?Assembly. Chem. Mater. 2019, 31, 1403?1407
Guo, Yongxian; Liu, Yin; Gong, Yanjun; Xiong, Wei; Zhang, Chuang*; Zhao, Jincai; Che, Yanke*. Kinetic control of a self-?assembly pathway towards hidden chiral microcoils. Chem. Eur. J. 2019, 25, 7463 – 7468
Zhong, Junbo; Zhao, Yukun; Ding, Liyong; Ji, Hongwei; Ma, Wanhong; Chen, Chuncheng*; Zhao, Jincai*. Opposite photocatalytic oxidation behaviors of BiOCl and TiO₂: Direct hole transfer vs. indirect ·OH oxidation. Applied Catalysis B: Environmental. 2019, 241, 514–520
Wei, Yan; Gong, Yanjun; Zhao, Xin; Wang, Yuanyuan; Duan, Ran; Chen, Chuncheng; Song, Wenjing*; Zhao, Jincai. Ligand directed debromination of tetrabromodiphenyl ether mediated by nickel under visible irradiation. Environ. Sci.: Nano, 2019, 6, 1585–1593.
Wei Peng, Yuhan Lin, Zhen Wan, Hongwei Ji, Wanhong Ma*, Jincai Zhao*. An Unusual Dependency on the Hole-Scavengers in Photocatalytic Reductions Mediated by a Titanium-Based Metal-Organic Framework. An Unusual Dependency on the Hole-Scavengers in Photocatalytic Reductions Mediated by a Titanium-Based Metal-Organic Framework. Catalysis Today. 2019, DOI:10.1016/j.cattod.2018.11.038
Yuanyuan Wang, Yan Wei, Wenjing Song*, Chuncheng Chen, Jincai Zhao*. Photocatalytic Hydrodehalogenation for the Removal of Halogenated Aromatic Contaminants. ChemCatChem, 2019, 11, 258–268.
2018 Zhang, Y. C.; Zhang, H. N.; Liu, A. N.; Chen, C. C.; Song, W. J.; Zhao, J. C. Rate-Limiting O-O Bond Formation Pathways for Water Oxidation on Hematite Photoanode. J. Am. Chem. Soc. 2018, 140(9), 3264-3269.
Li, M.; Bao, F. X.; Zhang, Y.; Song, W. J.; Chen, C. C.; Zhao, J. C. Role of elemental carbon in the photochemical aging of soot. Proc. Natl. Acad. Sci. USA 2018, 115(30), 7717-7722.
Bao, F. X.; Li, M.; Zhang, Y.; Chen, C. C.; Zhao, J. C. Photochemical Aging of Beijing Urban PM2.5: HONO Production. Environ. Sci. Technol. 2018, 52(11), 6309-6316.
Xiong, W.; Zhu, Q. J.; Gong, Y. J.; Wang, C.; Che, Y. K.; Zhao, J. C. Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives.Anal. Chem.2018, 90(7), 4273-4276.
Liu, X. L.; Gong, Y. J.; Zheng, Y. X.; Xiong, W.; Wang, C.; Wang, T.; Che, Y. K.; Zhao, J. C. Sensitive Detection of a Nerve-Agent Simulant through Retightening Internanofiber Binding for Fluorescence Enhancement. Anal. Chem. 2018, 90(3), 1498-1501.
Sun, C. Y.; Xiong, W.; Ye, W. D.; Zheng, Y. X.; Duan, R.; Che, Y. K.; Zhao, J. C. Fast and Ultrasensitive Detection of a Nerve Agent Simulant Using Carbazole-Based Nanofibers with Amplified Ratiometric Fluorescence Responses. Anal. Chem. 2018, 90(12), 7131-7134.
Yang, C.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C. Desulfurization of thiophenes in oils into H₂SO₄ using molecular oxygen. Appl. Catal. B-Environ. 2018, 235, 207-213.
Wang, Y. Y.; Zhu, Q.; Wei, Y.; Gong, Y. J.; Chen, C. C.; Song, W. J.; Zhao, J. C. Catalytic hydrodehalogenation over supported gold: Electron transfer versus hydride transfer. Appl. Catal. B-Environ. 2018, 231, 262-268.
Zhang, H. N.; Zhou, P.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Enhancement of photocatalytic decarboxylation on TiO₂ by water-induced change in adsorption-mode. Appl. Catal. B-Environ.2018, 224, 376-382.
Lang, X. J.; Zhao, J. C. Integrating TEMPO and Its Analogues with Visible-Light Photocatalysis. Chem. Asian J. 2018, 13(6), 599-613.
Liu, A. N.; Zhang, Y. C.; Ma, W. H.; Song, W. J.; Chen, C. C.; Zhao, J. C. Facial boron incorporation in hematite photoanode for enhanced photoelectrochemical water oxidation. J. Photochem. Photobiol. A-Chem. 2018, 355, 290-297.
Hou, X. J.; Huang, X. P.; Li, M. L. ; Zhang, Y. S. ; Yuan, S. H. ; Ai, Z. H. ; Zhao, J. C. ; Zhang, L. Z. Fenton oxidation of organic contaminants with aquifer sediment activated by ascorbic acid. Chem. Eng. J.2018, 348, 255-262.
Mao, C. L.; Cheng, H. G.; Tian, H.; Li, H.; Xiao, W. J.; Xu, H.; Zhao, J. C.; Zhang, L. Z. Visible light driven selective oxidation of amines to imines with BiOCl: Does oxygen vacancy concentration matter? Appl. Catal. B-Environ. 2018, 228, 87-96.
Mao, C. L.; Yu, L. H.; Li, J.; Zhao, J. C.; Zhang, L. Z. Energy-confined solar thermal ammonia synthesis with K/Ru/TiO_2-xH_x. Appl. Catal. B-Environ. 2018, 224, 612-620.
2017 Yan, Y.; Shi, W. D.; Yuan, Z.; He, S. G.; Li, D. M.; Meng, Q. B.; Ji, H. W.; Chen, C. C.; Ma. W. H.; Zhao, J. C. The Formation of Ti-H Species at Interface Is Lethal to the Efficiency of TiO₂-Based Dye-Sensitized Devices. J. Am. Chem. Soc. 2017, 139(5), 2083-2089.
Gong, Y. J.; Zhang, Y. F.; Xiong, W.; Zhang, K.; Che, Y. K.; Zhao, J. C. Molecular Interactions Control Quantum Chain Reactions toward Distinct Photoresponsive Properties of Molecular Crystals. J. Am. Chem. Soc. 2017, 139(31), 10649-10652.
Liu, Y.; Peng, C.; Xiong, W.; Zhang, Y. F.; Gong, Y. J.; Che, Y. K.; Zhao, J. C. Two-Dimensional Seeded Self-Assembly of a Complex Hierarchical Perylene-Based Heterostructure. Angew. Chem. Int. Ed. 2017, 56(38), 11380-11384.
Zhu, Q.; Wang, Y. Y.; Zhang, H. N.; Duan, R.; Chen, C. C.; Song, W. J.; Zhao, J. C. Localized TiIII mediated dissociative electron transfer for carbon halogen bond activation on TiO₂. Appl. Catal. B-Environ. 2017, 219, 322-328.
Shang, J. T.; Tang, H. Y.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Synthesis, characterization, and activity of a covalently anchored heterogeneous perylene diimide photocatalyst. Chin. J. Catal. 2017, 38(12), 2094-2101.
Zhu, Q. J.; Xiong, W.; Gong, Y. J.; Zheng, Y. X.; Che, Y. K.; Zhao, J. C. Discrimination of Five Classes of Explosives by a Fluorescence Array Sensor Composed of Two Tricarbazole-Nanostructures. Anal. Chem. 2017, 89(22), 11908-11912.
Zhao, Y. K.; Wang, Y. Y.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Photocatalytic Reductive Debromination of Polybrominated Diphenyl Ethers. Prog. Chem. 2017, 29(9), 911-918.
Gong, Y. Z.; Yang, C.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C. Aqueous Oxidations Started by TiO₂Photoinduced Holes Can Be a Rate-Determining Step. Chem. Asian J. 2017, 12(16), 2048-2051.
Zhang, Y. F.; Zhou, Z. C.; Peng, C.; Duan, R.; Che, Y. K.; Zhao, J. C. Increasing the interlayer distance in layered microribbons enhances the electrically driven twisting response. Phys. Rev. Mater. 2017, 1(3), 033601.
Zheng, Y. X.; Peng, C.; Xiong, W.; Zhang, Y. F.; Liu, Y.; Che, Y. K.; Zhao, J. C. Nanoscale Aggregates as Building Elements in a Biomimetic Living Self-Assembly. J. Phys. Chem. C 2017, 121(27), 14907-14913.
Xue, J. J.; Li, Y. F.; Xie, X. B.; Xiong, C. Q.; Liu, H. H.; Chen, S. M.; Nie, Z. X.; Chen, C. C.; Zhao, J. C. Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry. Atmos. Environ. 2017, 159, 55-65.
Hou, X. J.; Huang, X. P.; Jia, F. L.; Ai, Z. H.; Zhao, J. C. Zhang, L. Z. Hydroxylamine Promoted Goethite Surface Fenton Degradation of Organic Pollutants. Environ. Sci. Technol. 2017, 51(9), 5118-5126.
Hou, X. J.; Huang, X. P.; Ai, Z. H.; Zhao, J. C.; Zhang, L. Z. Ascorbic acid induced atrazine degradation. J. Hazard. Mater. 2017, 327, 71-78.
Zhou, Z. C.; Xiong, W.; Zhang, Y. F.; Yang, D. J.; Wang, T.; Che, Y. K.; Zhao, J. C. Internanofiber Spacing Adjustment in the Bundled Nanofibers for Sensitive Fluorescence Detection of Volatile Organic Compounds.Anal. Chem. 2017, 89(7), 3814-3818.
Huang, X. P.; Hou, X. J.; Jia, F. L.; Song, F. H.; Zhao, J. C.; Zhang, L. Z. Ascorbate-Promoted Surface Iron Cycle for Efficient Heterogeneous Fenton Alachlor Degradation with Hematite Nanocrystals. ACS Appl. Mater. Interf. 2017, 9(10), 8751-8758.
Peng, C.; Zhang, Y. F.; Zhang, Y. B.; Zhou, Z. C.; Che, Y. K.; Zhao, J. C. Diverse macroscopic helical motions of microribbons driven by electrons. Chem. Comm. 2017, 53(17). 2578-2581.
Zhang, H. N.; Zhou, P.; Chen, Z. F.; Song, W. J.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Hydrogen-Bond Bridged Water Oxidation on {001} Surfaces of Anatase TiO₂. J. Phys. Chem. C 2017, 121(4), 2251-2257.
Huang, X. P.; Hou, X. J.; Song, F. H.; Zhao, J. C.; Zhang, L. Z. Ascorbate Induced Facet Dependent Reductive Dissolution of Hematite Nanocrystals. J. Phys. Chem. C 2017, 121(2), 1113-1121.
Zhou, P.; Zhang, H. N.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C. Modulating the photocatalytic redox preferences between anatase TiO₂{001} and {101} surfaces. Chem. Comm. 2017, 53(4), 787-790.

Publications
Selected Publications
2017-2019
2008-2016

2008-2016
2016
Yuchao Zhang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, and Jincai Zhao*. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes.J. Am. Chem. Soc., 2016, 138 (8), 2705–2711
Ma, Xiaojie; Zhang, Yibin; Zhang, Yifan; Liu, Yin; Che, Yanke*; Zhao, Jincai. Fabrication of Chiral-?Selective Nanotubular Heterojunctions through Living Supramolecular Polymerization.Angew. Chem. Int. Ed.2016, 55(33), 9539-9543.
Hai-Ying Jiang, Peng Zhou, Yuanyuan Wang, Chuncheng Chen, Wenjing Song*, and Jincai Zhao*. Aqueous-compatible Copper-Phenylacetylide (PhC₂Cu) Coordination Polymer Network for Visible Light Photocatalysis.Adv. Mater.2016, DOI: 10.1002/adma..
Yifan Zhang, Cheng Peng, Bin Cui, Zhengfei Wang, Xibin Pang, Renmin Ma, Feng Liu, Yanke Che*, Jincai Zhao. Direction-Controlled Light-Driven Movement of Microribbons.Adv. Mater.2016, DOI: 10.1002/adma.
Peng, Cheng; Zhang, Yibin; Zhang, Yifan; Hu, Yanyong; Che, Yanke*; Zhao, Jincai. Highly Fluorescent Nanotubes with Tunable Diameter and Wall Thickness Self-?Assembled from Asymmetric Perylene Diimides.Small, 2016, 12(32), 4363-4369.
Lang, X. J.; Zhao, J. C.; Chen, X. D.* Cooperative photoredox catalysis.Chem. Soc. Rev., 2016, 45(11), 3026-3038
Xianjun Lang, Jincai Zhao, Xiaodong Chen*. Visible-Light-Induced Photoredox Catalysis of Dye-Sensitized Titanium Dioxide: Selective Aerobic Oxidation of Organic Sulfides.Angew. Chem. Int. Ed.2016, 55, 4697-4700.
Lv, Y. H.; Cao, X. F.; Jiang, H. Y.; Song, W. J.; Chen, C. C.*; Zhao, J. C.* Rapid photocatalytic debromination on TiO₂with in-situ formed copper co-catalyst: Enhanced adsorption and visible light activity.Appl. Catal. B- Environ.2016, 194, 150-156.
Hu, Yanyong; Ma, Xiaojie; Zhang, Yibin; Che, Yanke*; Zhao, Jincai. Detection of amines with fluorescent nanotubes: Applications in the assessment of meat spoilage.ACS Sensors, 2016, 1(1), 22-25.
Zhang, Y. B.; Zheng, Y. X.; Xiong, W.; Peng, C.; Zhang, Y. F.; Duan, R.; Che, Y. K.*; Zhao, J. C. Morphological Transformation between Nanocoils and Nanoribbons via Defragmentation Structural Rearrangement or Fragmentation-recombination Mechanism.Sci. Rep.2016, 6, 27335
Yuchao Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen, Wenjing Song, Jincai Zhao*. Doping-Promoted Solar Water Oxidation on Hematite Photoanodes.Molecules2016, 21, 868; doi:10.3390/molecules**
Peng, Cheng; Yang, Juan; Zhang, Yifan; Zhang, Yibin; Che*, Yanke. Spontaneously bundled nanotubes exhibit greatly enhanced emission via inter-nanotube energy transfer.Science China: Chemistry, 2016, doi:10.1007/s11426-016-0101-3.
2015
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO₂Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway.Angew. Chem. Int. Ed.2015, 54, 2052 –2056.
Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen,* Jincai Zhao. Activation of Water in TiO₂Photocatalysis by Formation of Surface Hydrogen Bonds: An in situ IR Study.Angew. Chem. Int. Ed.2015, 54, 5905-5909
Jialei Du, Zuofeng Chen*, Chuncheng Chen*, Thomas J. Meyer. A Half-Reaction Alternative to Water Oxidation: Chloride Oxidation to Chlorine Catalyzed by Silver Ion.J. Am. Chem. Soc., 2015, 137 (9), pp 3193–3196
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers.Adv. Mater.2015, 27, 320–325.
Yuchao Zhang, Shiqi Jiang, Wenjing Song, Peng Zhou, Hongwei Ji, Wanhong Ma, Weichang Hao, Chuncheng Chen and Jincai Zhao. Nonmetal P-doped hematite photoanode with enhanced electron mobility and high water oxidation activity . Zhang, Y. C.Environ. Energy Sci.2015,8, 1231-1236
Lang, X. J.; Leow, W. R.; Zhao, J. C.*; Chen, X. D.* Synergistic photocatalytic aerobic oxidation of sulfides and amines on TiO₂under visible-light irradiation.Chem. Sci., 2015, 6, 1075–1082
Tao Shi, Wei Chang, Hongna Zhang, Hongwei Ji, Wanhong Ma, Chuncheng Chen, and Jincai Zhao . H₂O-Involved Two-Electron Pathway for Photooxidation of Aldehydes on TiO₂: An Isotope Labeling Study.Environ. Sic. Technol.2015, 49 (5), pp 3024–3031
Xiaoling Liu , Yibin Zhang , Xibin Pang , Yue E , Yifan Zhang, Dongjiang Yang , Jianguo Tang, Jing Li , Yanke Che, Jincai Zhao. Nanocoiled Assembly of Asymmetric Perylene Diimides: Formulation of Structural Factors.J. Phys. Chem. C.2015, DOI: 10.1021/acs.jpcc.5b00720
Chen, C. C.; Shi, T.; Chang, W.; Zhao, J. C.* Essential Roles of Proton Transfer in Photocatalytic Redox Reactions.ChemCatChem, 2015, 7(5), 724–731
2014
Lang, X. J.;W. H. Ma; C. C. Chen;H. W. Ji; J. C. Zhao*.Selective Aerobic Oxidation Mediated by TiO₂Photocatalysis.Acc. Chem. Res.2014, 47(2), 355–363.
Pang, X. B.; Chang, W.; Chen, C. C.; Ji, H. W.; Ma, W. H.*; Zhao, J. C.* Determining the TiO₂-Photocatalytic Aryl-Ring-Opening Mechanism in Aqueous Solution Using Oxygen-18 Labeled O₂and H₂O. J. Am. Chem. Soc., 2014, 136 (24), 8714–8721
Lang, X.; Chen, X.D.*, Zhao, J. C.* Heterogeneous Visible Light Photocatalysis for Selective Organic Transformations.Chem. Soc. Rev.2014, 43 (1), 473 - 486.
Wang, Z.*, Bush, R.,. Sullivan L., Chen, C. C.* Liu, J. Selective oxidation of arsenite by peroxymonosulfate with high utilization efficiency of oxidant. Environ. Sci. Technol. 2014, 48, 3978-3985.
Chang, W.; Sun, C. Y.; Pang, X. B.; Sheng, H.; Li, Y.; Ji, H. W.; Song, W. J.; Chen, C. C.;Ma, W. H.*; Zhao, J. C.* Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: a Proton-induced Pathway. Angew. Chem. Int. Ed.2014, DOI: 10.1002/anie..
Zhang, Y. F.; Peng, C.; Zhou, Z. C.; Duan, R.; Ji, H. W.; Che, Y. K.*; Zhao, J. C. Giant Morphological Change in Layered Microribbons Featuring Reversible Sliding of Stacking Layers. Adv. Mater. 2014, DOI: 10.1002/adma..
Zhao, Y. B.; Zhang, Y. F.; Liu, H. W.; Ji, H. W.; Ma, W. H.; Chen, C. C.*; Zhu, H. Y.; Zhao J. C. Control of Exposed Facet and Morphology of Anatase Crystals through TiO_xF_y Precursor Synthesis and Impact of the Facet on Crystal Phase Transition. Chem. Mater. 2014, 26 (2), 1014–1018.
Sun, Y.; Chang, W.; Ji, H. W.; Chen, C. C.; Ma, W. H. *; Zhao, J. C*. An Unexpected Fluctuating Reactivity for Odd and Even Carbon Numbers in the TiO₂ Photocatalytic Decarboxylation of C2-C6 Dicarboxylic Acids. Chem. Eur. J. 2014, 20, 1861–1870(Cover Paper).
Li, L. N.; Chang, W.; Wang, Y.; Ji, H. W.; Chen, C. C.*; Ma, W. H.;Zhao, J. C. Rapid Photocatalytic Deep-Debromination of Polybrominated Diphenyl Ethers on Pd-TiO₂: Intermediates and Pathways. Chem. Eur. J. 2014, 20(35), 11163–11170.
Yang, C. J.; Lang, X. J.; Ma, W. H.; Chen, C. C.*; Ji, H. W. ; Zhao, J. C. UV-Assisted Removal of Inactive Peroxide Species for Sustained Epoxidation of Cyclooctene on Anatase TiO₂. Chem. Eur. J. 2014, 20(21), 6277–6282.
Ying Wang, Lina Li, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao. Iron(III)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency. Chem. Commun. 2014, 50, 2344-2346.
E, Y,; Ma, X. J.; Zhang, Y. F.; Zhang, Y. B.; Duan, R.; Ji, H. W.; Li, J.*; Che, Y. K.*; Zhao, J. C. Fluorescent bilayer nanocoils assembled from an asymmetric perylene diimide molecule with ultrasensitivity for amine vapors. Chem. Commun. 2014, 50, 13596-13599.
Zhang, Y. C.; Zhou, Z. C.; Chen, C. C.*; Che, Y.; Ji, H.; Ma, W.; Zhang, J.; Song, D.; Zhao, J. C. Gradient FeO_x(PO₄)_yLayer on Hematite Photoanodes: Novel Structure for Efficient Light Driven Water Oxidation. ACS Appl. Mater. Interfaces, 2014, 6 (15), 12844–12851.
Wang, J.; Lang, X. J.; Bao, Z.*; Jia, M. L.; Wang, J.; Guo, X.; Zhao, J. C.* Aerobic Oxidation of Alcohols on Au Nanocatalyst: Insight to the Roles of the Ni–Al Layered Double Hydroxides Support. ChemCatChem, 2014, 6, 1737 – 1747.
Pang, X. B.; Chen, C. C.*; Ji, H. W.; Che, Y. K.; Ma W. H.; Zhao, J. C*. Unraveling the Photocatalytic Mechanisms on TiO₂Surfaces Using the Oxygen-18 Isotopic Label Technique. Molecules, 2014, 19(10), 16291-16311.
Li, Q.; Che, Y. K.; Ji, H. W.; Chen, C. C.; Zhu, H.; Ma, W. H.*; Zhao J. C.* ortho-Dihydroxyl-9,10-anthraquinone dyes as visible-light sensitizers that exhibit a high turnover number for hydrogen evolution. Phys. Chem. Chem. Phys., 2014, 16, 6550--6554.
Wang, G. X.; Che, Y. K.*; Jiang, H.* Single Molecular Rotary Machine. Prog. Chem., 2014, 26(6), 909-918.
2013
Y. Li, H. Ji, C. Chen*, W. Ma,J. Zhao. Concerted Two-Electron Transfer and High Selectivity of TiO₂Photocatalyzed Deoxygenation of Epoxides.Angew. Chem. Int. Ed.,2013, 52, 12636 –12640.
Sheng, H.; Ji, H. W.; Chen, C. C.*; Ma, W. H.; Zhao, J. C. Switching Single-Electron to Four-Electron Oxygen Reduction on TiO₂ Surface by Pendant Proton Relay. Angew. Chem. Int. Ed., 2013, 52, 9686 –9690.
Sun, C. Y.; Chang, W.; Ma, W. H.; Chen, C. C.*; Zhao, J. C. Photoreductive debromination of decabromodiphenyl ethers in the presence of carboxylates under visible light irradiation. Environ. Sci. Technol. 2013, 47, 2370?2377.
Sheng, H.; Li, Q.; Ma, W. H.; Ji, H. W.; Chen, C. C.*; Zhao, J. C. Photocatalytic degradation of organic pollutants on surface anionized TiO₂: Common effect of anions for high hole-availability by water. Appl. Catal. B: Environ. 2013, 138– 139, 212– 218.
Cheng, S.; Li, J.; Yu, X.; Chen, C.; Ji, H.; Ma, W. H.* Zhao, J. C.* Selective Activation of Secondary C-H Bonds by an Iron Catalyst: Insight into Possibilities Created by the Use of a Carboxyl-Containing Bipyridine Ligand. New J. Chem., 2013, 37 (10), 3267 - 3273
Zhang, Y.; Bao Z.*; Jia M.; Chen, C. C.; Zhao, J. C.* Clay-based SiO₂ as active support of gold nanoparticles for CO oxidation catalyst: Pivotal role of residual Al. Catal. Commun. 2013, 35, 72–75.
Li, N.; Lang, X.; Ma, W. H.; Ji, H. W.; Chen, C. C.*; Zhao, J. C. Selective Aerobic Oxidation of Amines to Imines by TiO₂ Photocatalysis in Water. Chem. Commun., 2013, 49 (44), 5034 – 5036.
Yang, D. J.*; Zhao, J.; Liu H. W.; Zheng, Z.; Adebajo, M. O.; Wang, H.; Liu, X.; Zhang, H.; Zhao, J. C.* Bell, J.; Zhu, H. Y.* Enhancing Photoactivity of TiO₂(B)/Anatase Core-Shell Nanofibers by Selectively Doping Cerium Ions into the TiO₂(B) Core. Chem. Eur. J. 2013, 19, 5113 – 5119
Sun, Y.; Chang, W.; Ji, H. W.; Chen, C. C.; Ma, W. H. *; Zhao, J. C*. An Unexpected Fluctuating Reactivity for Odd and Even Carbon Numbers in the TiO₂ Photocatalytic Decarboxylation of C2-C6 Dicarboxylic Acids. Chem. Eur. J. 2013, accepted (Cover Paper).
Li, J. H.*; He H.; Hu, C.; Zhao, J. C.* The abatement of major pollutants in air and water by environmental catalysis. Front. Environ. Sci. Eng. 2013, 7(3): 302–325
2012
Zhao, Y. B.; Ma, W. H.; Li, Y.; Ji, H. W.; Chen, C. C.; Zhu, H.; Zhao, J. C.* The surface-structural sensitivity of dioxygen activation in anatase photocatalyzed oxidation reaction, Angew. Chem. Int. Ed., 2012, 51, 3188 –3192.
Lang, X.; Ma, W. H.; Zhao, Y.; Chen, C. C.; Ji, H. W.; Zhao, J. C.*. Visible-light-induced selective photocatalytic aerobic oxidation of amines into imines on TiO₂, Chem. Eur. J., 2012, 18, 2624 – 2631.
Liu, G. L.; Chen, C. C.*; Ma, W. H.; Ji, H. W.; Zhao, J. C.*Photo-electrochemical water splitting system with three-layer n-type organic semiconductor film as photoanode under visible irradiation, Sci. China Chem., 2012, 55(9), 1953–1958
Li, Y.; Wen, B.; Yu, C.; Chen, C. C.*; Ji, H. W.; Ma, W. H.; Zhao, J. C.* Pathway of oxygen incorporation from O₂ inTiO₂ photocatalytic hydroxylation of aromatics: oxygen isotope labeling studies,Chem. Eur. J., 2012, 18, 2030-2039. (Cover paper)
Li, Y.; Wen B.; Chen, C. C.*; Ma, W. H.; Zhao, J. C. Photocatalytic degradation of aromatic pollutants: a pivotal role of e_cb^- in distribution of hydroxylated intermediates, Environ. Sci. Technol., 2012, 46 (9), 5093-5099.
Wang, Z. Chen, C. C.*; Ma, W. H.; Zhao, J. C.* Photochemical coupling of iron redox reactions and transformation of low-molecular-weight organic matter.J. Phys. Chem. Lett.2012, 3, 2044?2051.
Sun, C.; Zhao, J. C.; Ji, H. W.; Ma, W. H.; Chen, C. C.* Photocatalytic debromination of preloaded decabromodiphenyl ether on the TiO₂ surface in aqueous system. Chemosphere, 2012, 89, 420–425.
Chen, Q.; Ma, W. H.; Chen, C. C.; Ji, H. W.; Zhao, J. C.*Anatase TiO₂ mesocrystals enclosed by (001) and (101) facets: Synergistic effects between Ti³⁺ and facets for their photocatalytic performance. Chem. Eur. J., 2012, 18, 12584-12589.
Sun, C.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic debromination of decabromodiphenyl ether by graphitic carbon nitride. Sci. China Chem., 2012, 55(12), 2532-2536.
Sarina Sarina, Huaiyong Zhu,* Zhanfeng Zheng, Steven Bottle, Jin Chang, Xuebin Ke, Jin-Cai Zhao,Yining Huang, Andre Sutrisno, Mathew Willans and Guoran Li, Driving selective aerobic oxidation of alkyl aromatics by sunlight on alcohol grafted metal hydroxides, Chem. Sci., 2012, 3, 2138-2146
Ping Lei, Feng Wang,, Xiaowei Gao, Yanfen Ding, Shimin Zhang, Jincai Zhao, Shaoren Liu, Mingshu Yang?, Immobilization of TiO₂ nanoparticles in polymeric substrates bychemical bonding for multi-cycle photodegradation of organic pollutants, Journal of Hazardous Materials, 2012, 227-228,185-194
Hanzhong Jia, Jincai Zhao, Xiaoyun Fan, Kamila Dilimulati, Chuanyi Wang*, Photodegradation of phenanthrene on cation-modified clays under visible light, Applied Catalysis B: Environmental 2012, 123-124, 43-51
Wang, L; Zang, L.; Zhao, J. C.; Wang, C. Y. Green synthesis of shape-defined anatase TiO₂ nanocrystals wholly exposed with {001} and {100} facets. Chem. Commun., 2012, 48, 11736–11738.
Shang, Y.; Chen. C.; Li, Y.; Zhao, J. C.; Zhu, T. Hydroxyl radical generation mechanism during the redox cycling process of 1, 4-naphthoquinone. Environ. Sci. Technol.2012, 46, 2935–2942.
2011
Lang, X. J.; Ji, H. W.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Selective formation of imines via aerobic photocatalytic oxidation of amines on TiO₂. Angew. Chem. Int. Ed.,50(17) (2011), 3934-3937.
Ma, J.;Ma, W. H.; Chen, C. C.; Ji, H.W.;Zhao, J. C.*.An efficient anthraquinone–resin hybrid co-catalyst for fenton-like reactions: Acceleration of the iron cycle using a quinone cycle under visible-light irradiation.Chem. Asian J., 6(9)(2011), 2264-2268
Wang, Z.; Chen, C. C.; Ma, W. H.; Zhao, J. C.*, Probing paramagnetic species in titania-based heterogeneous photocatalysis by electron spin resonance(ESR) spectroscopy-A mini reviewChem. Eng. J., 170(2-3) (2011), 353-362. (Invited Review)
Yang D.; Chen, C. C.; Zheng, Z.; Liu, H.; Eric R. Yan, W., Huang, Y., Zhang H., Zhao, J. C.*; Zhu, H.*. Grafting silica species on anatase surface for visible light photocatalytic activity, Energy Environ. Sci. 4(6)(2011), 2279-2287.
Chen, X.; Ma, W. H.*; Li, J.; Wang, Z. H.; Chen, C. C.; Ji, H. W.Zhao, J. C.*. Photocatalytic oxidation of organic pollutants catalyzed by an iron complex at biocompatible pH values: Using O₂ as main oxidant in a Fenton-like reaction. J. Phys. Chem C, 115 (2011), 4089-4095.
Yuan, H.; Ma, W. H.; Chen, C. C.; Zhu H.; Gao X.; Zhao, J. C.*. Controllable synthesis of 3D thorny plasmonic gold nanostructures and their tunable optical properties,J. Phys. Chem. C, 115(47)(2011), 23256-23260.
Sun, C. Y.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photodegradation of organic pollutants catalyzed by iron species under visible light irradiation. Phys. Chem. Chem. Phys.,13 (2011), 1957-1969. (Invited Review)
Wen, B.; Ma, J.; Chen, C. C.; Ma, W. H.; Zhu H.; Zhao, J. C.*. Supported noble metal nanoparticles as photo/sono-catalysts for synthesis of chemicals and degradation of pollutants, Sci. China Chem., 54(6) (2011), 887-897.
Liu, G. L.; Yu C. L.; Chen, C. C.*; Ma, W. H.; Ji, H. W.; Zhao, J. C.*. A new type of covalent-functional graphene donor-acceptor hybrid andits improved photoelectrochemical performance, Sci. China Chem., 54(10)(2011), 1622-1626.
2010
Wang, Q.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic aerobic oxidation of alcohols on TiO₂: The acceleration effect of a Br?nsted acid. Angew. Chem. Int. Ed., 49(43)(2010), 7976-7979.(inside cover paper)
Mu, Q.; Yang, L.; Davis, J. C.; Vankayala, R.; Hwang, K. C.; Zhao, J. C.; Yan, B. Biocompatibility of polymer grafted core/shell iron/carbon nanoparticles. Biomaterials, 31(19)(2010), 5083-5090.
Chen, C. C.; Ma, W. H.;Zhao, J. C.* Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. Chem. Soc. Rev., 39(11)(2010), 4206-4219.（Invited Review）
Wen, B.; Li, Y.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* An unexplored O₂-involved pathway for the decarboxylation of saturated carboxylic acids by TiO₂ photocatalysis: An isotopic probe study. Chem.-Eur. J., 16(39)(2010), 11859-11866.（Cover Paper）
Feng, W.; Xiangfu, M.; Bin, W.; Junhua, Z.; Yanfen, D.; Shimin, Z.; Zhao, J. C.; Shaoren, L.; Mingshu, Y. Preparation and photocatalytic activity of PET/TiO₂ hybrid nanofibers via in-situ growth method.Chinese Sci. Bull., 55 (2010), 1873-1878.
Yang, J.; Dai, J.; Zhao, J. C.; Miao, J. Mechanism of photocatalytic degradation of dye MG by TiO₂-film electrode with cathodic bias potential. Chinese Sci. Bull., 55(2)(2010), 131-139.
Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photocatalytic degradation of organic pollutants by co-doped TiO₂under visible light irradiation. Curr. Org. Chem., 14(7)(2010), 630-644. （Invited Review）
Liu, H.; Zheng, Z.; Yang, D.; Ke, X.; Jaatinen, E.; Zhao, J. C.; Zhu, H. Y. Coherent interfaces between crystals in nanocrystal composites. ACS Nano, 4(10)(2010), 6219-6227.
Liu, J.; Liu, G.; Li, M.; Shen, W.; Liu, Z.; Wang, J.; Zhao, J. C.; Jiang, L.; Song, Y. Enhancement of photochemical hydrogen evolution over Pt-loaded hierarchical titania photonic crystal. Energy Environ. Sci.,3(10)(2010), 1503-1506.
Wang, Z. H.; Chen, X.; Ji, H. W.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Photochemical cycling of iron mediated by dicarboxylates: Special effect of malonate. Environ. Sci. Technol., 44(1)(2010), 263-268.
Yu, C.; Zhang, Y.; Quan, X.; Chen, S.; Han, J.; Ou, X.; Zhao, J. C. Photochemical effect of humic acid components separated using molecular imprinting method applying porphyrin-like substances as templates in aqueous solution. Environ. Sci. Technol., 44(15)(2010), 5812-5817.
Chen, X.; Zheng, Z. F.; Ke, X. B.; Jaatinen, E.; Xie, T. F.; Wang, D. J.; Guo, C.; Zhao, J. C.; Zhu, H. Y. Supported silver nanoparticles as photocatalysts under ultraviolet and visible light irradiation. Green Chem.,12(3)(2010), 414-419.
Che, Y. K.; Yang, X.; Liu, G.; Yu, C.; Ji, H. W.; Zuo, J.; Zhao, J. C.*; Zang, L.* Ultrathin n-type organic nanoribbons with high photoconductivity and application in optoelectronic vapor sensing of explosives. J. Am. Chem. Soc., 132(16)(2010), 5743-5750.
Zheng, Z.; Liu, H.; Ye, J.; Zhao, J. C.; Waclawik, E. R.; Zhu, H. Structure and contribution to photocatalytic activity of the interfaces in nanofibers with mixed anatase and TiO₂(B) phases. J. Mol. Catal. A-Chem., 316(1-2)(2010), 75-82.
Wang, Y.; Zhao, D.; Ji, H. W.; Liu, G.; Chen, C. C.; Ma, W. H.; Zhu, H.; Zhao, J. C.* Sonochemical hydrogen production efficiently catalyzed by Au/TiO₂. J. Phys. Chem C, 114(41)(2010), 17728-17733.
2009
Zhang, M.; Wang, Q.; Chen, C. C.; Zang, L.; Ma, W. H.*; Zhao, J. C.* Oxygen atom transfer in the photocatalytic oxidation of alcohols by TiO₂: Oxygen isotope studies. Angew. Chem. Int. Ed., 48(33)(2009), 6081-6084.
Yang, J.; Dai, J.; Miao, J.; Li, J. T.; Zhao, J. C. Mechanism on photocatalytic degradation of benzoic acid with TiO₂-film electrode. Acta Chim. Sinica, 67(17)(2009), 1973-1980.
Zhang, L.; Wong, K.-H.; Chen, Z.; Yu, J. C.; Zhao, J. C.; Hu, C.; Chan, C.-Y.; Wong, P.-K. AgBr-Ag-Bi₂WO₆ nanojunction system: A novel and efficient photocatalyst with double visible-light active components. Appl. Catal. A- Gen, 363(1-2)(2009), 221-229.
Zhu, H.; Chen, X.; Zheng, Z.; Ke, X.; Jaatinen, E.; Zhao, J. C.; Guo, C.; Xie, T.; Wang, D. Mechanism of supported gold nanoparticles as photocatalysts under ultraviolet and visible light irradiation. Chem. Commun.,(48)(2009), 7524-7526.
Wang, Q.; Chen, C.*; Ma, W. H.; Zhu, H.; Zhao, J. C.* Pivotal role of fluorine in tuning band structure and visible-light photocatalytic activity of nitrogen-doped TiO₂. Chem.-Eur. J., 15(19) (2009), 4765-4769.
Sun, C.; Zhao, D.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* TiO₂-Mediated photocatalytic debromination of decabromodiphenyl ether: Kinetics and intermediates. Environ. Sci. Technol., 43(1)(2009), 157-162.
Yang, D.; Liu, H.; Zheng, Z.; Yuan, Y.; Zhao, J. C.; Waclawik, E. R.; Ke, X.; Zhu, H. An efficient photocatalyst structure: TiO₂(B) nanofibers with a shell of anatase nanocrystals. J. Am. Chem. Soc., 131(49)(2009), 17885-17893.
Mahmood, T.; Chen, C. C.; Liu, L. L.; Zhao, D.; Ma, W. H.; Lin, J.; Zhao, J. C.* Effect of dye-metal complexation on photocatalytic decomposition of the dyes on TiO₂ under visible irradiation. J. Environ. Sci.-China, 21(2)(2009), 263-267.
Wang, Z.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Light-assisted decomposition of dyes over iron-bearing soil clays in the presence of H₂O₂. J.Hazard. Mater., 168(2-3)(2009), 1246-1252.
Zhao, D.; Chen, C.*; Yu, C.; Ma, W. H.; Zhao, J. C.* Photoinduced electron storage in WO₃/TiO₂nanohybrid material in the presence of oxygen and postirradiated reduction of heavy metal ions. J. Phys. Chem. C, 113(30)(2009), 13160-13165.
Yang, J.; Dai, J.; Chen, C. C.; Zhao, J. C. Effects of hydroxyl radicals and oxygen species on the 4-chlorophenol degradation by photoelectrocatalytic reactions with TiO₂-film electrodes. J.Photochem. Photobio. A: Chem, 208(1)(2009), 66-77.
Zhao, D.; Sun, C.; Chen, C. C.; Ma, W. H.; Zhao, J. C.* Photochemical degradation of organic pollutants polybrominated piphenyl ether congeners and cyanuric acid. Prog. Chem., 21(2009), 400-405.
Shang, Y.; Zhu, T.; Li, Y.; Zhao, J. C. Size-dependent hydroxyl radicals generation induced by SiO₂ ultra-fine particles: The role of surface iron. Sci. China Ser B: Chem., 52(7)(2009), 1033-1041.
2008
Zhang, M.; Chen, C. C.; Ma, W. H.*; Zhao, J. C.* Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO₂ and TEMPO. Angew. Chem. Int. Ed., 47(50)(2008), 9730-9733.
Chen, X.; Zhu, H. Y.; Zhao, J. C., Zheng, Z. F.; Gao, X. P. Visible-light-driven oxidation of organic contaminants in air with gold nanoparticle catalysts on oxide supports. Angew. Chem. Int. Ed., 47(29)(2008), 5353-5356.
Cheng, M. M.; Song, W. J.; Ma, W. H.; Chen, C. C.; Zhao, J. C.*; Lin, J.; Zhu, H. Y. Catalytic activity of iron species in layered clays for photodegradation of organic dyes under visible irradiation. Appl. Catal. B-Environ., 77(3-4)(2008), 355-363.
Chang, Q. Y.; He, H.; Qu, J. H.; Zhao, J. C. Influencing factors in catalytically bactericidal process of Ag-Ce/AlPO₄ catalyst in water. Chinese J. Catal., 29(3)(2008), 215-220.
Wang, Z.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Photochemical coupling reactions between Fe(III)/Fe(II), Cr(VI)/Cr(III), and polycarboxylates: Inhibitory effect of Cr species. Environ. Sci. Technol., 42(19)(2008), 7260-7266.
Wang, Y.; Zhao, D.; Ma, W. H.; Chen, C. C.; Zhao, J. C.* Enhanced sonocatalytic degradation of azo dyes by Au/TiO₂. Environ. Sci. Technol., 42(16)(2008), 6173-6178.
Zhang, H.; Zong, R.; Zhao, J. C.; Zhu, Y. Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO₂ with PANI. Environ. Sci. Technol., 42(10)(2008), 3803-3807.
Chang, Q. Y.; He, H.; Zhao, J. C.; Yang, M.; Qu, J. H. Bactericidal activity of a Ce-promoted Ag/AIPO₄catalyst using molecular oxygen in water. Environ. Sci. Technol., 42(5)(2008), 1699-1704.
Zhao, D.; Chen, C.*; Wang, Y.; Ma, W. H.; Zhao, J. C.*; Rajh, T.; Zang, L. Enhanced photocatalytic degradation of dye pollutants under visible irradiation on Al(III)-modified TiO₂: Structure, interaction, and interfacial electron transfer. Environ. Sci. Technol., 42(1)(2008), 308-314.
Zhao, D.; Chen, C. C.*; Wang, Y. F.; Ji, H. W.; Ma, W. H.; Zang, L.; Zhao, J. C.* Surface modification of TiO₂ by phosphate: Effect on photocatalytic activity and mechanism implication. J. Phys. Chem. C,112(15)(2008), 5993-6001.
Wang, Q.; Chen, C.*; Zhao, D.; Ma, W. H.; Zhao, J. C.* Change of adsorption modes of dyes on fluorinated TiO₂ and its effect on photocatalytic degradation of dyes under visible irradiation. Langmuir,24(14) (2008), 7338-7345.
Liu, L. L.; Chen, C. C.; Hu, X. F.; Mohamood, T.; Ma, W. H.; Lin, J.; Zhao, J. C.* A role of ionic liquid as an activator for efficient olefin epoxidation catalyzed by polyoxometalate. New J. Chem., 32(2)(2008), 283-289.
Ding, X. J.; An, T. C.; Li, G. Y.; Chen, J. X.; Sheng, G. Y.; Fu, J. M.; Zhao, J. C. Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO₂ pillared montmorillonite photocatalyst.Res.Chem. Intermediat., 34(1)(2008), 67-83.

Group Activites
名称日期

Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of 1O2 2019-09-30
Nitrate Enhanced Oxidation of SO2 on Mineral Dust: A Vital Role of Proton 2019-08-25
Proton-free electron-trapping feature of titanium dioxide nanoparticles without the characteristic blue color 2019-07-30
Elemental Carbon in the Photochemical Aging of Soot 2018-07-24
Photochemical Aging of Beijing Urban PM2.5: HONO Production 2018-05-25

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