课题组负责人


钟羽武 研究员
email:zhongyuwu@iccas.ac.cn
电话：
办公室：2#415
实验室：2#413，416







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化学试剂 2013-06-04
有用链接 2013-06-04
研究小组 2013-06-04


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祝贺李志娟同学荣获2019年度“化学所青年科学奖（研究生）特别优秀奖”
祝贺钟羽武研究员获“第五届中国化学会-赢创化学创新奖”
祝贺李蕊同学获得化学所2019年羽毛球赛女单冠军！
祝贺钟羽武研究员获2019年度“卢嘉锡优秀导师奖”
祝贺钟羽武研究员获第二届“中国化学会-泊菲莱优秀青年科学家奖”


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简介
我们课题组主要是面向分子电子学和智能响应功能材料，我们从分子水平设计合成新型金属有机配合物，研究化合物的电化学，光吸收与发射，光谱电化学，DFT和TDDFT理论预测，EPR性质以及自组装行为等，探索材料在混合价化学，分子导线，近红外电致变色薄膜，离子探针和敏化电池等方面的应用。以材料所含氧化还原中心的个数分类，包括单核金属配合物，对称与不对称双中心体系，三中心，四中心以及多中心体系，配位聚合物。
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课题组负责人


钟羽武 研究员
email:zhongyuwu@iccas.ac.cn
电话：
办公室：2#415
实验室：2#413，416







链接
名称 日期

化学试剂 2013-06-04
有用链接 2013-06-04
研究小组 2013-06-04


更多





课题组动态
名称

祝贺李志娟同学荣获2019年度“化学所青年科学奖（研究生）特别优秀奖”
祝贺钟羽武研究员获“第五届中国化学会-赢创化学创新奖”
祝贺李蕊同学获得化学所2019年羽毛球赛女单冠军！
祝贺钟羽武研究员获2019年度“卢嘉锡优秀导师奖”
祝贺钟羽武研究员获第二届“中国化学会-泊菲莱优秀青年科学家奖”


更多





搜索
所有社区 本社区






欢迎访问与交流








简介
我们课题组主要是面向分子电子学和智能响应功能材料，我们从分子水平设计合成新型金属有机配合物，研究化合物的电化学，光吸收与发射，光谱电化学，DFT和TDDFT理论预测，EPR性质以及自组装行为等，探索材料在混合价化学，分子导线，近红外电致变色薄膜，离子探针和敏化电池等方面的应用。以材料所含氧化还原中心的个数分类，包括单核金属配合物，对称与不对称双中心体系，三中心，四中心以及多中心体系，配位聚合物。
点击全文






欢迎加入我们

---

课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







课题组成员

?
?
?
在职员工
在读学生
联合培养
以往小组成员

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课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







课题组组长

钟羽武 研究员
email:zhongyuwu@iccas.ac.cn
电话：
办公室：2#415
实验室：2#-413，416

中国科学院化学研究所光化学实验室，研究员、课题组长、博士生导师。
1977年6月生于浙江省松阳县。1999年7月南开大学化学系本科毕业。2004年7月中国科学院上海有机化学研究所博士毕业，导师林国强研究员。2004年9月到2006年9月在日本东京大学Eiichi Nakamura小组做博士后工作。2006年10月到2009年9月在美国康奈尔大学化学与生物学系Héctor D. Abru?a小组做博士后工作。2009年10月回国加入中科院化学研究所光化学实验室。

研究兴趣包括有机及金属有机光电功能材料的合成与性能研究、基于环金属钌的新型混合价体系、配位聚合物薄膜的制备与近红外电致变色研究等。迄今为止在JACS，Coord.Chem.Rev.等期刊上发表SCI收录论文50余篇，近5年他人引用次数600余次。目前承担国家自然科学基金青年基金一项，面上基金一项，重点研究计划培养项目一项，作为项目骨干参与科技部国家重大科学研究计划项目一项。获2012年中科院研究生院-BHPB导师科研奖。

代表性论文: 1. Yu-Wu Zhong*，Chang-Jiang Yao，Hai-Jing Nie，Electropolymerized Films of Vinyl-substituted Polypyridine Complexes: Synthesis，Characterization，and Applications，Coord. Chem. Rev.2013，257(7-8)，1357-1372.

2.Hai-Jing Nie，Xialing Chen，Chang-Jiang Yao，Yu-Wu Zhong*，Geoffrey R. Hutchison*，Jiannian Yao*，Electronic Coupling between Two Amine Redox Sites through the 5.5'-positions of Metal-Chelating 2.2'-Bipyridines，Chem. Eur. J.2012，18(45)，14497-14509.

3. Chang-Jiang Yao，Ren-Hui Zheng，Qiang Shi，Yu-Wu Zhong*，Jiannian Yao，1.4-Benzene-Bridged Covalent Hybrid of Triarylamine and Cyclometalated Ruthenium: A New Type of Organic-Inorganic Mixed-Valent System，Chem. Commun.2012，48(45)，5680-5682.

4. Chang-Jiang Yao，Yu-Wu Zhong*，Hai-Jing Nie，Hector D. Abruna，Jiannian Yao*，Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc.2011，133(51)，20720-20723.

5. Chang-Jiang Yao，Yu-Wu Zhong*，Jiannian Yao*，Charge Delocalization in a Cyclometalated Bisruthenium Complex Bridged by a Noninnocent 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc.2011，133(39)，15697-15706.

6. Yu-Wu Zhong，Yutaka Matsuo*，Eiichi Nakamura.* Lamellar assembly of conical molecules possessing a fullerene apex in crystals and liquid crystals，J. Am. Chem. Soc.2007，129，3052-3053.

7. Yu-Wu Zhong，Yi-Zhou Dong，Kai Fang，Kenji Izumi，Ming-Hua Xu*，Guo-Qiang Lin*， A highly efficient and direct approach for synthesis of enantiopure beta-amino alcohols by reductive cross-coupling of chiralN-tert-butanesulfinyl imines with aldehydes.J. Am. Chem. Soc.2005，127，11956-11957.

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课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







在职员工

邵将洋
shaojiangyang@iccas.ac.cn

龚忠亮
gongzhongliang@iccas.ac.cn

唐健洪
tangjianhong@iccas.ac.cn

---

课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







在读学生

李蕊 lirui316@iccas.ac.cn
孙天歌 suntiange@iccas.ac.cn
李志娟 lizhijuan@iccas.ac.cn
唐坤 tangkun@iccas.ac.cn
李仲秋 lizhongqiu17@mails.ucas.edu.cn
曾伟 plzengwei@163.com
王宇端 wangyuduan18@mails.ucas.ac.cn
丁春云 cyding@iccas.ac.cn
马点雪 madianxue19@mails.ucas.ac.cn

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课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







联合培养

王浩
7@mail.bnu.edu.cn

张丽然
**@163.com

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课题组成员
课题组组长
在职员工
在读学生 博士三年级
博士二年级
博士一年级
硕士三年级
硕士二年级
硕士一年级
联合培养
以往小组成员







以往小组成员
朱建强 (zhujianqiang001984@163.com)
隋龙臻(suilongzhen@gmail.com)
康红卫 (kanghw@iccas.ac.cn)
吴静 (wujing051021@126.com)
汪雷 (wanglei90@iccas.ac.cn)
张友明 (zhangyouming1218@iccas.ac.cn)
姚长江 (yaochemistry@iccas.ac.cn)
聂海晶 (niehaijing@iccas.ac.cn)
邵将洋 (shaojiangyang@iccas.ac.cn)
吴四海 (wusihai@iccas.ac.cn)
龚忠亮 (gongzhongliang@iccas.ac.cn)
沈军舰 (shenjj@iccas.ac.cn)
杨文文 (yangwenwen@iccas.ac.cn)
崔彬彬 (binbincui@iccas.ac.cn)
何艳芹 (dheshan@126.com)
张春雨 (zhangchunyu1032@163.com)
余宙 (phapku@163.com)
冯骏 (fengljun@gmail.com)
郑嘉楠 (zhengjn@iccas.ac.cn)
邓利叶 (dengliye12345@163.com)
孙孟佳(sunmengjia13@mails.ucas.ac.cn)

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研究领域
金属有机光电功能材料

关键词：金属有机材料；光电功能配合物；光电有机材料；多中心氧化还原体系；混合价化合物；多吡啶配合物；三唑；咪唑；环金属配合物；钌；锇；铂；三芳胺；二茂铁；芘；近红外；电致变色；电化学聚合。

面向分子电子学和智能响应功能材料，我们从分子水平设计合成新型金属有机配合物，研究化合物的电化学，光吸收与发射，光谱电化学，DFT和TDDFT理论预测，EPR性质以及自组装行为等，探索材料在混合价化学，分子导线，近红外电致变色薄膜，离子探针和敏化电池等方面的应用。以材料所含氧化还原中心的个数分类，包括单核金属配合物，对称与不对称双中心体系，三中心，四中心以及多中心体系，配位聚合物。

1. 单核环金属配合物
环金属配合物含有CN型二齿螯合配体或CNN或NCN型三齿螯合配体，其中带负电荷的“C”原子与金属形成碳-金属键，常见金属包括钌，铂，铱，锇等。环金属钌和锇配合物具有化学可逆的氧化还原过程。碳-金属键的引入成为调节金属氧化还原电位的重要和有效方法。我们设计合成了多种单核金属配合物，通过改变辅基配体的种类（吡啶，苯并咪唑，三唑，氮杂卡宾等）和引入碳-金属键，实现Ru(II/III)和Os(II/III)电位的宽范围调节与控制。（Organometallics2011，30，2236-2240；2012，31，4302-4308；Inorg. Chem.2012，51，890-899；Dalton Trans.2012，41，9280-9282）


2.基于环金属双钌配合物的混合价体系
设计合成了一系列桥联双核环状金属钌配合物。这些配合物中，金属和桥联配体之间以碳-金属键结合，有利于增强金属-金属电子相互作用。配合物显示两个分步的金属氧化峰。当处于混合价态（II-III）时，配合物在近红外区域显示混合价电荷转移（IVCT）吸收。根据金属之间的距离，桥联配体的共轭程度，端基配体的电子性质以及辅基配体的不同，这些体系的电子相互作用程度和IVCT峰的能量可以得到调控。这些工作进展为设计合成性能优异的金属有机导线分子以及开展更为复杂的混合价体系的研究奠定基础。（J. Am. Chem. Soc.2011，133，15697-15706；Inorg. Chem.2010，49，8347-8350；2011，50，517-524；2011，50，7074-7079；2012，51，1590-1598；2012，51，4343-4351；Organometallics2012，31，1035-1041）



3.氧化还原不对称混合价体系
设计合成了以环状金属钌和三芳胺为氧化还原中心的无机-有机杂化混合价体系，通过成键方式的改变，实现电荷转移方向的反转。当两者以1.4-苯基相连时，三芳胺先被氧化，充当受体，环状金属钌作为给体，体系在1050纳米呈现较强混合价电荷转移吸收。当两者以4-吡啶基为桥基时，环状金属钌先氧化，充当受体，而三芳胺作为给体，实现电荷转移方向的反转。经过相似的方法，合成了环状金属钌-二茂铁杂化的不对称混合价体系，通过成键方式的改变，电荷转移的方向发生类似的反转。（Chem. Commun.2012，48，5680-5682；Organometallics2012，31，8577-8583；Chem. Asian J.2013，8，138-147）



4.三中心体系



5.四中心体系


6.电化学配位聚合物薄膜与近红外电致变色
在双核环状金属钌配合物工作的基础上，合成了端基配体上含有乙烯基结构的双核钌配合物。通过电化学原位还原聚合，在ITO导电玻璃表面形成金属配合物聚合物薄膜。这些配位聚合物保留了双核钌配合物单体的电化学和光谱性质。通过施加不同电压，配合物可以进行单电子和双电子氧化，薄膜颜色发生相应多步变化。当处于单电子氧化态时，ITO薄膜在近红外区域显示IVCT峰，当处于原始状态或双电子氧化时，IVCT峰消失，实现近红外区域的薄膜电致变色，并具有薄膜稳定性好，表面覆盖率容易控制，响应时间快和对比率好等电致变色优点。（J. Am. Chem. Soc.2011，133，20720-20723；J. Org. Chem.2011，76，4771-4775；Organometallics2012，31，6952-6959；Inorg. Chem.2012，51，6259-6263）

7.近红外发光材料


8. 基于金属配合物的离子探针


9.敏化太阳能电池

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博士三年级 课题组成员 19-11-21 下午7:17 已批准 光化学-杨文文
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课题组成员 课题组成员 19-11-21 下午6:58 已批准 光化学-杨文文
祝贺李蕊同学获得化学所2019年羽毛球赛女单冠军！ 课题组动态 19-11-15 下午7:37 已批准 光化学-杨文文
祝贺钟羽武研究员获2019年度“卢嘉锡优秀导师奖” 课题组动态 19-11-12 下午10:13 已批准 光化学-杨文文
祝贺钟羽武研究员获第二届“中国化学会-泊菲莱优秀青年科学家奖” 课题组动态 19-11-12 下午9:53 已批准 光化学-杨文文
招生与招聘 招生与招聘信息 19-10-23 下午10:52 已批准 光化学-杨文文
2010-2014年论文 发表论文 19-10-23 下午10:42 已批准 光化学-杨文文
2019年10月9日 朱晨教授 组内活动 19-10-23 下午10:09 已批准 光化学-杨文文

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招生与招聘
招生信息
招聘信息

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招生信息
本课题组每年招收硕博连读研究生一名(可接收推荐免试生)和博士生一名，欢迎报考。

有意者欢迎提前到课题组进行研究实习工作。

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招聘信息
因科研工作需要，课题组拟招聘包括副研，助研，博士后和本科以上学历各类科研工作人员，主要从事功能配合物与光电材料研究。

一、应聘条件
具相关工作经验和科研兴趣，品学兼优，身体健康，具有或者即将取得相关学位。
受聘期间需在本课题组全职从事科研工作，不得兼职。吃苦耐劳、工作认真负责。

二、研究方向
有机合成，金属有机反应
多吡啶类功能配合物的合成与光电性能研究
混合价体系与分子导线的合成及单分子导电行为测试
有机光电功能纳米材料，敏化太阳能电池
功能配合物和有机光电材料的结构模拟与理论计算

具备以上相关方面研究经验和扎实科学论文撰写能力的优秀人才优先考虑


二、聘用待遇
工资待遇按照中科院及化学所相关规定执行

三、应聘材料
个人陈述与简历，具体科研经历，发表文章目录
身份证、学历和学位证书复印件
合作导师等联系人联系信息或其他相关证明材料

四、联系方式
联系人：钟羽武
联系电话：（010）**
E-mail:zhongyuwu@iccas.ac.cn
http://zhongyuwu.iccas.ac.cn/ 地址：北京市海淀区中关村北一街2号
邮编：100190


本招聘长期有效，热忱期待你的加盟！

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发表论文
2020年论文
2019年论文
2018年论文
2017年论文
2016年论文
2015年论文
2010-2014年论文 2014年论文
2013年论文
2012年论文
2011年论文
2010年论文
2002-2009年论文

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单篇全文显示
154. Yan-Qin He, Werner Fudickar, Jian-Hong Tang*, Heng Wang, Xiaopeng Li, Jun Han, Zhengping Wang, Min Liu, Yu-Wu Zhong, Torsten Linker* and Peter J. Stang*, Capture and Release of Singlet Oxygen in Coordination-Driven Self-Assembled Organoplatinum(II) Metallacycles. J. Am. Chem. Soc. 2020, 142, 5, 2601-2608
153. Jiang-Yang Shao, Si-Hai Wu*, Junjie Ma, Zhong-Liang Gong, Tian-Ge Sun, Yulong Jin, Rong Yang, Bin Sun and Yu-Wu Zhong*, Ratiometric detection of amyloid-β aggregation by a dual-emissive tris-heteroleptic ruthenium complex.Chem. Commun., 2020, 56, 2087 - 2090
152. Si-Hai Wu*, Zhong-Liang Gong, Jiang-Yang Shao, Rong Yang, Yu-Wu Zhong*, Dual-emissive transition-metal complexes and their applications as ratiometric photoluminescent probes. Sci. Sin. Chim., 2020, DOI: 10.1360/SSC-2019-0151

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单篇全文显示
2019
151. Qing Hao, Zhi-Juan Li, Cheng Lu, Bing Sun, Yu-Wu Zhong*, Li-Jun Wan and Dong Wang*, Oriented Two-Dimensional Covalent Organic Framework Films for Near-Infrared Electrochromic Application, J. Am. Chem. Soc. 2019, DOI: 10.1021/jacs.9b09956.

150. Zhi-Juan Li, Chang-Jiang Yao and Yu-Wu Zhong*, Near-infrared electrochromism of multilayer films of a cyclomet-alated diruthenium complex prepared by layer-by-layer deposi-tion on metal oxide substrates, Sci. China Chem. 2019, DOI:10.1007/s11426-019-9640-1.

149.Jiang-Yang Shao^?, Ning Yang^?, Wang Guo, Bin-Bin Cui*, Qi Chen and Yu-Wu Zhong*,Introducing fluorene into organic hole transport materials to improve mobility and photovoltage for perovskite solar cells,Chem. Commun. 2019, 55, 13406-13409.

148. Jian-Hong Tang^?, Yueqi Li^?, Qingqing Wu^?, Zixiao Wang^?, Songjun Hou, Kun Tang, Yue Sun, Hui Wang, Heng Wang, Cheng Lu, Xiang Wang, Xiaopeng Li, Dong Wang, Jiannian Yao, Colin J. Lambert*, Nongjian Tao*, Yu-Wu Zhong* andPeter J. Stang*, Single-molecule level control of host-guest interactions in metallocycle-C60 complexes, Nat. Commun. 2019, 10, 4599.

147.Jian-Hong Tang^?,Ruidong Ni^?,Yan-Qin He^?,Ryan T. Vanderlinden, Yanrong Li, Bingbing Shi, Zhong-Yu Li, Heng Wang*, Xiaopeng Li, Yue Sun*, Yu-Wu Zhong*and Peter J. Stang*,Metal?Organic Pt(II) Hexagonal-Prism Macrocycles and TheirPhotophysical Properties,Inorg. Chem. 2019,58(19), 13376-13381.

146.Zhong-Qiu Li, Jian-Hong Tang and Yu-Wu Zhong*,Multidentate Anchors for Surface Functionalization,Chem. Asian J. 2019, 14, 3119-3126.

145. Jiang-Yang Shao, Bin-Bin Cui, Jian-Hong Tang and Yu-Wu Zhong*, Resistive memory switching of transition-metal complexes controlled by ligand design. Coord. Chem. Rev. 2019, 393, 21-36.
?

144.Zhong-Liang Gong and Yu-Wu Zhong*,New insight into hydrogen bond-mediated electron transfer.Sci China Chem, 2019,62, 927-928.

143.Si-Qi Zhang, Lin-Xiu Cheng, Zhong-Liang Gong, Wu-Biao Duan*, Bin Tu*, Yu-Wu Zhong* and Qing-Dao Zeng*,Temperature-Triggered Self-Assembled Structural Transformation: From Pure Hydrogen-Bonding Quadrilateral Nanonetwork to Trihexagonal Structures.Langmuir 2019,35, 6571-6577.

142.Meng-Jia Sun^?, Yingying Liu^?, zeng wei, Yong Sheng Zhao*, Yu-Wu Zhong*and Jiannian Yao*,Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer.J. Am. Chem. Soc. 2019,141(15), 6157-6161.(front cover, 01-May-2019)

141.Jiang-Yang Shao and Yu-Wu Zhong*,Stabilization of a Cyclometalated Ruthenium Sensitizer on Nanocrystalline TiO₂ by an Electrodeposited Covalent Layer.Inorg. Chem. 2019,58(5), 3509-3517.

140.Yutaka Matsuo*, Chu-Guo Yu, Takafumi Nakagawa, Hiroshi Okada, Hiroshi Ueno, Tian-Ge Sun, and Yu-Wu Zhong,Reduced Knoevenagel Reaction of Acetetracenylene-1,2-dione with Acceptor Units for Luminescent Tetracene Derivatives.J. Org. Chem. 2019,84(4), 2339-2345.

139.Zhi-Juan Li, Jiang-Yang Shao, Si-Hai Wu* and Yu-Wu Zhong*,Nanocrystalline Sb-Doped SnO₂ Films Modified with CyclometalatedRuthenium Complexes for Two-Step Electrochromism.Dalton Trans. 2019, 48, 2197-2205.

138.Tian-Ge Sun, Zhi-Juan Li, Jiang-Yang Shao and Yu-Wu Zhong*, Electrochromism in Electropolymerized Films of Pyrene-Triphenylamine Derivatives.Polymers 2019, 11, 73.(Special Issue on Electrochromic Polymers)

137. Zhong-Liang Gong, Rui Li and Yu-Wu Zhong, Electroluminochromism: Classical Materials and New Developments, Chapter 7 of Electrochromic Smart Materials: Fabrication and Applications, edited by Jian Wei Xu, Ming Hui Chua, Kwok Wei Shah,RSC 2019.

136.Chang-Jiang Yao, Kexiang Zhao, Guankui Long, Xinxiong Li, Zhong-Liang Gong, Yu-Wu Zhong, Weibo Gao, Yongxin Li, Rakesh Ganguly, Gang Lie, and Qichun Zhang *,Synthesis, characterization and photophysical studies of a novel polycyclic diborane.New J. Chem. 2019,43, 564-568.

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单篇全文显示
2018
135. Bin-Bin Cui*, Ying Han, Ning Yang, Shuangshuang Yang, Liuzhu Zhang, Yue Wang, Yifei Jia, Lin Zhao, Yu-Wu Zhong, and Qi Chen,Propeller-Shaped, Triarylamine-Rich, and Dopant-Free Hole-Transporting Materials for Efficient n–i–p Perovskite Solar Cells.ACS Appl. Mater. Interfaces2018, 10(48), 41592-41598.

134.Zhi-Juan Li^§, Jun-Jian Shen^§, Jiang-Yang Shao, and Yu-Wu Zhong*,Substituent Effects on the Electrochemistry and Electronic Coupling of Terphenyl-Bridged Cyclometalated Ruthenium-Amine Conjugated Complexes.ACS Omega2018, 3 (12), 16744-16752.

133.Jian-Hong Tang, Zhenfeng Cai, Dong Yan, Kun Tang, Jiang-Yang Shao,Chuanlang Zhan, Dong Wang, Yu-Wu Zhong,* Li-Jun Wan, and Jiannian Yao, A Molecular Quadripod as a Noncovalent Interfacial Coupling Reagent for Forming Immobilized Coordination Assemblies.J. Am. Chem. Soc. 2018,140, 12337-12340.

132.Liu Tiecheng, Zhang Li, Sun Jing, Zhong Yuwu, Wang Zhongyang, Guo Xinjun, Ruan Hao*. Optical Properties of Dithienylethene and Its Applications in Super-Resolution Optical Storage. Chinese Journal of Lasers, 2018, 45(9), **.(in Chinese)
131.Qian-Qing Ge^?,Jiang-Yang Shao^?,*,Jie Ding, Li-Ye Deng, Wen-Ke Zhou, Yao-Xuan Chen, Jing-Yuan Ma, Li-Jun Wan, Jiannian Yao, Jin-Song Hu*, and Yu-Wu Zhong*,A Two‐Dimensional Hole‐Transporting Material for High‐Performance Perovskite Solar Cells with 20% Average Efficiency.Angew. Chem. Int. Ed. 2018,57, 10959-10965.

130.Bin-Bin Cui*, Ning Yang, Congbo Shi, Shuangshuang Yang,Jiang-Yang Shao, Ying Han, Liuzhu Zhang, Qingshan Zhang, Yu-Wu Zhongand Qi Chen*,Naphtho[1,2-b:4,3-b']dithiophene-based hole transporting materials for high-performanceperovskite solar cells: molecular engineering and opto-electronic properties.J. Mater. Chem. A2018, 6, 10057-10063.

129.Jian-Hong Tang^?, Yue Sun^?, Zhong-Liang Gong, Zhong-Yu Li, Zhixuan Zhou,Heng Wang, Xiaopeng Li, Manik Lal Saha*, Yu-Wu Zhong* and Peter J. Stang*,Temperature-Responsive Fluorescent Organoplatinum(II) Metallacycles.J. Am. Chem. Soc. 2018,140, 7723-7729.

128.Meng-Jia Sun, Yu-Wu Zhong* and Jiannian Yao*,Thermal-Responsive Phosphorescent Nanoamplifiers Assembled from Two Metallophosphors.Angew. Chem. Int. Ed. 2018,57, 7820-7825.

127.Meng-Jia Sun, Yingying Liu, Yaming Yan, Rui Li, Qiang Shi*, Yong Sheng Zhao*, Yu-Wu Zhong*and Jiannian Yao*,In Situ Visualization of Assembly and Photonic Signal Processing in a Triplet Light-Harvesting Nanosystem.J. Am. Chem. Soc. 2018,140, 4269?4278.

126.Ce Zhou^?, Xingxing Li^?, Zhongliang Gong^?, Chuancheng Jia, Yuanwei Lin, Chunhui Gu, Gen He, Yuwu Zhong*, Jinlong Yang* andXuefeng Guo*,Direct observation of single-molecule hydrogen-bond dynamics with single-bond resolution.Nat. Commun. 2018, 9, 807.

125.Dongmei Li^?, Jiang-Yang Shao^?, Yiming Li, Yusheng Li, Li-Ye Deng, Yu-Wu Zhong* and Qingbo Meng*,New hole transporting materials for planar perovskite solar cells.Chem. Commun. 2018,54, 1651-1654.

124.Rui Li, Zhong-Liang Gong, Jian-Hong Tang, Meng-Jia Sun, Jiang-Yang Shao, Yu-Wu Zhong* and Jiannian Yao,Triarylamines with branched multi-pyridine groups: modulation ofemission properties by structural variation, solvents,and tris(pentafluorophenyl)borane.Sci. China Chem. 2018,61(5), 545-556.

123. Jiang-Yang Shao, Zhong-Liang Gong and Yu-Wu Zhong*, Bridged cyclometalated diruthenium complexes for fundamental electron transfer studies and multi-stage redox switching. Dalton Trans. 2018,47, 23-29.(invited Frontier article)

122. Si-Hai Wu,* Jiang-Yang Shao, Zhong-Liang Gong, Na Chen and Yu-Wu Zhong*, Tuning the dual emissions of a monoruthenium complex with a dangling coordination site by solvents, O2, and metal ions. Dalton Trans. 2018,47, 292-297.

121. Jun Feng, Jiang-Yang Shao, Hai-Jing Nie, Zhong-Liang Gong, Yu-Wu Zhong*, Synthesis and electrochemical and spectroscopic studies of a N,N,N',N'-tetraphenylbenzidine-bridged bis(2,2'-bipyridine) ligand and diruthenium complex. Chin. Chem. Lett. 2018,29, 385-389.

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单篇全文显示
2017
120.Jian-Hong Tang, Tian-Ge Sun, Jiang-Yang Shao, Zhong-Liang Gong and Yu-Wu Zhong*,Resistive memory devices based on a triphenylamine-decorated non-precious cobalt(II) bis-terpyridine complex,Chem. Commun. 2017,53, 11925-11928.

119.Zhong-Liang Gong, Yu-Wu Zhong*and Jiannian Yao,Regulation of Intra- and Intermolecular Pt-Pt and π-π Interactions of a U-Shaped Diplatinum Complex to Achieve Pseudo-Polymorphic Emissions in Solution and Crystalline States,J. Mater. Chem. C2017, 5, 7222-7229.

118.Zhi-Juan Li, Jiang-Yang Shao, Yu-Wu Zhong*,Near-Infrared and Two-Wavelength Electrochromism Based on Nanocrystalline TiO₂ Films Functionalized with Ruthenium-Amine Conjugated Complexes,Inorg. Chem. 2017, 56, 8538-8546.

117.Si-Hai Wu*, Jiang-Yang Shao, Xiaojuan Dai, Xiuling Cui, Hongmei Su, Yu-Wu Zhong*,Synthesis and Characterization of Trisbidentate Ruthenium Complexes of Di(pyrid-2-yl)-methylamine,Eur. J. Inorg. Chem. 2017,24, 3064-3071.

116. Jiang-Yang Shao, Yu-Wu Zhong*, pH value-dependent electronic absorption and Ru(III/II) potential of bis-tridentate pincer ruthenium complexes, J. Organometall. Chem. 2017, 845, 144-150.(special issue of Organometallic Chemistry of Pincer Complexes)

115.Zhong-Liang Gong, Li-Ye Deng, Yu-Wu Zhong*, and Jiannian Yao, Anion-Regulated Electronic Communication in a Cyclometalated Diruthenium Complex with a Urea Bridge, Phys. Chem. Chem. Phys.2017,19, 8902-8907.

114.Hongwei Song, Xian Wang, WenWen Yang, Guiying He, Zhuoran Kuang, Yang Li, Andong Xia, Yu-Wu Zhong,* Fan'ao Kong*, Ultrafast Relaxation Dynamics of Amine-Substituted Bipyridyl Ruthenium(II) Complexes, Chem. Phys. Lett. 2017,683,322-328.(Ahmed Zewail Commemoration Issue)

113.Zhong-LiangGong,Chang-JiangYao,Jiang-YangShao,Hai-JingNie,Jian-HongTang, Yu-WuZhong*,Redox-responsive carbometalated ruthenium and osmium complexes,Sci. China Chem.2017,60(5), 583-590.

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单篇全文显示
2016
112. Meng-Jia Sun, Xinliang Zhang, Yu-Wu Zhong*, Chuanlang Zhan*, and Jiannian Yao*, Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor–Acceptor-Structured Diruthenium Complex, Inorg. Chem. 2016, 55(24), 13007-13013.

111.Linxiu Cheng, Yibao Li, Chun-Yu Zhang, Zhong-Liang Gong, Qiaojun Fang, Yu-Wu Zhong*, Bin Tu*, Qingdao Zeng*, and Chen Wang,Temperature-Triggered Chiral Self-Assembly of Achiral Molecules at the Liquid–Solid Interface,ACS Appl. Mater. Interfaces 2016,8(46),32004-32010.

110. Jian-Hong Tang, Yan-Qin He, Jiang-Yang Shao, Zhong-Liang Gong, Yu-Wu Zhong*, Multistate Redox Switching and Near-Infrared Electrochromism Based on a Star-Shaped Triruthenium Complex with a Triarylamine Core, Sci. Rep. 2016, 6, 35253.

109.Zhong-Liang Gong,Yu-Wu Zhong*,H₂PO₄^-- and Solvent-Induced Polymorphism of an Amide-Functionalized [Pt(N^C^N)Cl] Complex,Inorg. Chem. 2016, 55(20), 10143-10151.

108.Jiang-Yang Shao,? Dongmei Li,? Kun Tang, Yu-Wu Zhong* and Qingbo Meng*,Simple biphenyl or carbazole derivatives with four di(anisyl)amino substituents as efficient hole-transporting materials for perovskite solar cells,RSC Adv. 2016, 6, 92213-92217.

107. Bin-Bin Cui, Jian-Hong Tang, Yu-Wu Zhong*, Resistive Memory Materials Based on Transition-Metal Complexes, Acta Chim. Sinica2016, 74(9), 726-733.(in Chinese)

106. Lin Wang⁺, Zhong-Liang Gong⁺, Shu-Ying Li, Wenjing Hong*, Yu-Wu Zhong*, Dong Wang*, Li-Jun Wan, Molecular Conductance through a Quadruple-Hydrogen-Bond-Bridged Supramolecular Junction, Angew. Chem. Int. Ed. 2016,55(40), 12393-12397.

105.ZhongliangGong ,ChangjiangYao ,JiangyangShao ,HaijingNie ,JianhongTang, Zhong Yuwu*, Redox-responsive cyclometalated ruthenium and osmium complexes, Sci. Sin. Chim. 2016, 46(10), 1093-1100.(in Chinese)

104. Jun Feng, Jiang-Yang Shao, Zhong-Liang Gong, Yu-Wu Zhong*, Amine-Amine Electronic Coupling through an Anthracene Bridge, Chin. J. Org. Chem. 2016, 36(10), 2407-2412.

103.Jian-Hong Tang, Jiang-Yang Shao, Yan-Qin He, Si-Hai Wu, Jiannian Yao, Yu-Wu Zhong*,Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System, Chem. Eur. J. 2016,22(30), 10341-10345.

102.Jiang-Yang Shao, Chang-Jiang Yao, Bin-Bin Cui, Zhong-Liang Gong, Yu-Wu Zhong*,Electropolymerized films of redox-active rutheniumcomplexes for multistate near-infrared electrochromism, ionsensing, and information storage,Chin. Chem. Lett. 2016, 27(8), 1105-1114.(special issue of pai-Functional Molecules & Polymers)

101.Hai-Jing Nie, Wen-Wen Yang, Jiang-Yang Shao and Yu-Wu Zhong,*Ruthenium-Tris(bipyridine) Complexes with Multiple Redox-Active Amine Substituents: Tuning of Spin Density Distribution and Deep-Red to NIR Electrochromism and Electrofluorochromism,Dalton Trans. 2016,45, 10136-10140.

100. Xing-Dong Xu, Chang-Jiang Yao, Li-Jun Chen, Guang-Qiang Yin, Yu-Wu Zhong*, and Hai-Bo Yang*, Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization, Chem. Eur. J. 2016, 22(15), 5211-5218.

99. You-Ming Zhang, Fanyuan Meng, Jian-Hong Tang, Yafei Wang, Caifa You, Hua Tan, Yu Liu, Yu-Wu Zhong*, Shijian Su* and Weiguo Zhu*, Achieving near-infrared emission in platinum(II) complexes by using an extended donor–acceptor-type ligand, Dalton Trans. 2016,45, 5071-5080.

98. Jian-Hong Tang, Chang-Jiang Yao, Bin-Bin Cui and Yu-Wu Zhong*, Ruthenium-Amine Conjugated Organometallic Materials for Multistate Near-IR Electrochromism and Information Storage,Chem. Rec.2016, 16(2), 754-767.

97. Zhong-Liang Gong, Jiang-Yang Shao, Yu-Wu Zhong*, Synthesis, Structural Diversity, and Redox Control of Cyclometalated Monoruthenium Complexes, J. Electrochem. 2016, 22(3), 244-259.

96. Yu-Wu Zhong*, Zhong-Liang Gong, Jiang-Yang Shao, Jiannian Yao, Electronic coupling in cyclometalated ruthenium complexes, Coord. Chem. Rev. 2016, 312, 22-40.

95. Jun-Jian Shen, Jiang-Yang Shao, Xiaozhang Zhu*, and Yu-Wu Zhong*,Amine－Amine Electronic Coupling through a Dibenzo[a,e]pentalene Bridge,Org. Lett. 2016,18(3), 256-259.

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单篇全文显示
2015
94. Jun-Jian Shen, Jiang-Yang Shao, Zhong-Liang Gong, and Yu-Wu Zhong*, Cyclometalated Osmium-Amine Electronic Communication through the p-Oligophenylene Wire, Inorg. Chem. 2015, 54(22), 10776-10784.

93. Jiang-Yang Shao, Nianqing Fu, Wen-Wen Yang, Chun-Yu Zhang, Yu-Wu Zhong,* Yuan Lin,* and Jiannian Yao, Cyclometalated ruthenium(II) complexes with bis(benzimidazolyl)benzene for dye-sensitized solar cells, RSC Adv. 2015, 5, 90001-90009.

92. Jun-Jian Shen, Yu-Wu Zhong,* Long-Range Ruthenium-Amine Electronic Communication through the para-Oligophenylene Wire, Sci. Rep. 2015, 5,13835.

91. Zhong-Liang Gong, Yu-Wu Zhong,* Urea-bridged diferrocene: structural, electrochemical, and spectroelectrochemical studies, Sci. China Chem. 2015, 58(9), 1444-1450.

90. Yu-Wu Zhong, Electrochromism within Transition-Metal Coordination Complexes and Polymers, Chapter 6 of Electrochromic Materials and Devices, edited by Roger J. Mortimer, David R. Rosseinsky and Paul M. S. Monk, 2015 Wiley-VCH.

89. Meng-Jia Sun, Jiang-Yang Shao*, Chang-Jiang Yao, Yu-Wu Zhong*, and Jiannian Yao*, Osmium Bisterpyridine Complexes with Redox-Active Amine Substituents: A Comparison Study with Ruthenium Analogues, Inorg. Chem. 2015,54(16), 8136-8147.

88. Bin-Bin Cui, Jian-Hong Tang, Jiannian Yao, and Yu-Wu Zhong*, A Molecular Platform for Multistate Near-Infrared Electrochromism and Flip-Flop, Flip-Flap-Flop, and Ternary Memory, Angew. Chem. Int. Ed. 2015, 54(32), 9192-9197.

87. Azusa Kajikawa, Takanari Togashi, Yuka Orikasa, Bin-Bin Cui, Yu-Wu Zhong, Masatomi Sakamoto, Masato Kurihara*, and Katsuhiko Kanaizuka*, Construction of hybrid films of silver nanoparticles and polypyridine ruthenium complexes on substrates,Dalton Trans.2015,44, 15244-15249.

86. Wen-Wen Yang, Jiang-Yang Shao, and Yu-Wu Zhong*, Cyclometalated Diruthenium Complexes Bridged by 3,3′,5,5′-Tetra(pyrid-2-yl)biphenyl: Tuning of Electronic Properties and Intervalence Charge Transfer by Terminal Ligand Effects, Eur. J. Inorg. Chem.2015,(19), 3195-3204.

85. Chang-Jiang Yao, Hai-Jing Nie, Wen-Wen Yang, Jiannian Yao, and Yu-Wu Zhong*, Combined Experimental and Computational Study of Pyren-2,7-diyl-Bridged Diruthenium Complexes with Various Terminal Ligands, Inorg. Chem.2015, 54(10), 4688-4698.

84. Meng-Jia Sun,Hai-Jing Nie,Jian-Nian Yao,Yu-Wu Zhong*, Bis-triarylamine with a cyclometalated diosmium bridge: a multi-stage redox-active system, Chin. Chem. Lett. 2015, 26(6), 649-652.

83. Bin-Bin Cui, Yu-Wu Zhong*, Jiannian Yao, Three-State Near-Infrared Electrochromism at the Molecular Scale,J. Am. Chem. Soc.2015,137(12),4058-4061.

82. Hai-Jing Nie, Wen-Wen Yang, Ren-Hui Zheng, Qiang Shi, Hui Chen, Jiannian Yao, and Yu-Wu Zhong,* Metal Chelation-Assisted Amine?Amine Electronic Coupling through the 4,4′-Positions of 2,2′-Bipyridine,Inorg. Chem.2015, 54(4),1272-1282.

81. Yan-Qin He and Yu-Wu Zhong,* The synthesis of 2- and 2,7-functionalized pyrene derivatives through Ru(II)-catalyzed C–H activation, Chem. Commun. 2015, 51, 3411-3414.

80. Bin-Bin Cui, Zupan Mao, Yuxia Chen, Yu-Wu Zhong*, Gui Yu,* Chuanlang Zhan,* Jiannian Yao*, Tuning of Resistive Memory Switching in Electropolymerized Metallopolymeric films,Chem. Sci.2015, 6, 1308-1315.

79. Zhong-Liang Gong, Yu-Wu Zhong,* and Jiannian Yao, Conformation-Determined Through-Bond versus Through-Space Electronic Communication in Mixed-Valence Systems with a Cross-Conjugated Urea Bridge,Chem. Eur. J. 2015, 21(4), 1554-1566.

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2010-2014年论文
2014年论文
2013年论文
2012年论文
2011年论文
2010年论文

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2002-2009年发表论文
2002-2009
20.Yu-Wu Zhong, Neus Vila, Jay C. Henderson, Hector D. Abruna.*Transition-metal tris-bipyridines containing three dithienylcyclopentenes: synthesis, photochromic, and electrochromic properties.Inorg. Chem.2009,48, 7080-7085.
19. Liangfeng Sun,* Lei Bao, Byung-Ryool Hyun, Adam Bartnik,Yu-Wu Zhong, Hector D. Abruna, George G. Malliaras, Frank W. Wise.*Electrogenerated chemiluminescence from PbS quantum dots.Nano Lett.2009,9, 789-793.
18.Yu-Wu Zhong, Neus Vila, Jay C. Henderson, Hector D. Abruna.*Dithienylcyclo- pentenes-containing transitional metal bis-terpyridine complexes directed toward molecular electronic applications.Inorg. Chem.2009,48, 991-999.
17. Byung-Ryool Hyun,*Yu-Wu Zhong, Adam Bartnik, Liangfeng Sun, Hector D. Abruna, Frank W. Wise, James Matthews, Jason Goodreau, Thomas Leslie, Nick Borrelli.Electron injection from colloidal PbS quantum dots into titanium dioxide nanoparticles. ACS Nano 2008,2, 2206-1121.
16. Guo-Qiang Lin,* Ming-Hua Xu,Yu-Wu Zhong, Xing-Wen Sun.An advance on exploringN-tert-butanesulfinyl imines in asymmetric synthesis of chiral amines.Acc. Chem. Res.2008,41, 831-840.
15. Yutaka Matsuo,* Katsuhiko Kanaizuka, Keiko Matsuo,Yu-Wu Zhong, Takahiro Nakae, Eiichi Nakamura.*Photocurrent-generating properties of organometallic fullerene molecules on an electrode.J. Am. Chem. Soc.2008,130,5016-5017.
14. Jason D. Slinker, John A. DeFranco, Michael J. Jaquith, William R. Silveira,Yu-Wu Zhong, Jose M. Moran-Mirabal, Harold G. Craighead, Hector D. Abruna, John A. Marohn, George G. Malliaras.*Direct measurement of the electric-field distribution in a light-emitting electrochemical cell.Nature Mater.2007,6,894-899.
13.Yu-Wu Zhong, Neus Vila, Jay C. Henderson, Samuel Florres-Torres, Hector D. Abruna.*Dinuclear transition-metal terpyridine complexes with a dithienylcyclopentene bridge directed toward molecular electronic applications.Inorg. Chem.2007,46,10470-10472.
12.Yu-Wu Zhong, Yutaka Matsuo,* Eiichi Nakamura.*Lamellar assembly of conical molecules possessing a fullerene apex in crystals and liquid crystals.J. Am. Chem. Soc.2007,129,3052-3053.
11.Yu-Wu Zhong, Yutaka Matsuo,* Eiichi Nakamura.*Chiral ruthenium- allenylidene complexes that Bear a fullerene cyclopentadienyl ligand: synthesis, characterization, and remote chirality transfer.Chem. Asian. J.2007,2,358-366.
10.Yu-Wu Zhong, Yutaka Matsuo, Eiichi Nakamura.*Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C₆₀.Org.Lett.2006,8,1463-1467.
9. Yutaka Matsuo, Yuichi Mitani,Yu-Wu Zhong, Eiichi Nakamura.*Remote chirality transfer within coordination sphere by the use of a ligand possessing a concave cavity.Organometallics.2006,25,2826-2832.
8.Yu-Wu Zhong, Yi-Zhou Dong, Kai Fang,KenjiIzumi,Ming-HuaXu,*andGuo-QiangLin.*A highly efficient and direct approach for synthesis of enantiopure beta-amino alcohols by reductive cross-coupling of chiralN-tert-butanesulfinyl imines with aldehydes. J. Am. Chem. Soc.2005,127,11956-11957.
7.Yu-Wu Zhong,KenjiIzumi,Ming-HuaXu,*andGuo-QiangLin.Highly diastereoselective and enantioselective synthesis of enantiopureC₂-symmetrical vicinal diamines by reductive homocoupling of chiralN-tert-butanesulfinyl imines.Org.Lett.2004,6, 4747-4750.
6.Yu-Wu Zhong,Ming-HuaXu,*andGuo-QiangLin.Samariumdiiodide-inducedasymmetricsynthesis ofopticallypureunsymmetricalvicinaldiamines byreductivecross-coupling ofnitrones withN-tert-butanesulfinylimines.Org.Lett.2004,6, 3953-3956.
5. Chong-Tian Yu, Yin-Long Guo,*Guo-Qiang Chen,Yu-Wu Zhong.Chiralrecognition ofZinc(II)ioncomplexescomposed ofbicyclo[3.3.0]octane-2,6-diol ands-naproxenprobed bycollisional-induceddissociation.J.Am.Soc.Mass Spectrom.2004,15, 795-802.
4.Yu-Wu Zhong, Chang-Sheng Jiang,Ming-HuaXu,*andGuo-QiangLin.*Bifunctional pyridyl alcohols with the bicyclo[3.3.0]octane scaffold in the asymmetric addition of diethylzinc to aldehydes.Tetrahedron. 2004,60, 8861-8868.
3.Yu-Wu Zhong, Ping Tian, andGuo-QiangLin.*New beta-Amino alcohols with a bicyclo[3.3.0]octane scaffold in an asymmetric Henry reaction.Tetrahedron: Asymmetry2004,15, 771-776.
2. Wei Wang,Yu-Wu Zhong, andGuo-QiangLin.*Carbohydrates as chiral auxiliaries in enantioselective synthesis of four stereoisomers of optically active alpha,gama-substituted gama-butyrolactones.Tetrahedron Lett.2003,44, 4613-4616.
1.Yu-Wu Zhong, Xin-Sheng Lei, andGuo-QiangLin.*Amino alcohols with the bicyclo[3.3.0]octane scaffold as ligands for the catalytic enantioselective addition of diethylzinc to aldehydes.Tetrahedron: Asymmetry2002,13, 2251-2255.

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2019年10月9日 朱晨教授
2019年10月9日 朱晨教授
苏州大学 材料与化学化工学部
16：00 化学所5号楼100会议室作邀请报告，交流讨论
学术报告题目：自由基参与的开环和迁移反应







2019年9月23日 郑佑轩教授
2019年9月23日 郑佑轩教授
南京大学化学化工学院 配位化学国家重点实验室
10:00 化学所3号楼101会议室做邀请报告，交流讨论
学术报告题目：几类发光材料OLED性能研究







2019年8月23日 赵建章教授
2019年8月23日 赵建章教授
大连理工大学化工学院 精细化工国家重点实验室
16:00 化学所3号楼1001会议室做邀请报告，交流讨论
学术报告题目：Intersystem Crossing of Visible Light-Harvesting Electron Donor/Acceptor Dyads







2019年8月22日 潘梅教授
2019年8月22日 潘梅教授
中山大学化学学院
15:30 化学所3号楼501会议室做邀请报告，交流讨论
学术报告题目：发光功能配位超分子：结构与机制



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2018年12月14日 Xiaopeng Li
2018年12月14日 Xiaopeng Li
Department of Chemistry, University of South Florida
15:30在化学所3号楼101会议室做讲座报告，交流讨论
学术报告题目：Self-Assembly of Giant 2D and 3D Metallo-Supramolecules with Increasing Complexity


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2018年12月4日 Prof. Héctor D. Abru?a
2018年12月4日 Prof. Héctor D. Abru?a
Cornell Cornell University, Ithaca, New York, USA
16:00在化学所3号楼101会议室做讲座报告，交流讨论
学术报告题目：Energy Conversion and Storage: Novel Materials and Operando Methods







2018年1月8日 Prof. Hiroyuki Isobe
2018年1月8日 Prof. Hiroyuki Isobe
Department of Chemistry, The University of Tokyo
15:30 所3号楼101会议室做分子科学前沿讲座报告，交流讨论
学术报告题目：Viewing Science through Macrocycles: An Approach of A Synthetic Organic Chemist

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Welcome








The Group
?









Prof. Zhong

?
Yu-Wu Zhong

Email:zhongyuwu@iccas.ac.cn
Phone: +86-(0)
Office: 2#415
Lab: 2#413，416

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Research Interests
Optoelectronic Organometallic Materials
Keywords: organometallic materials; optoelectronic complexes; optoelectronic organic materials; multi redox-center systems; mixed-valence compounds; polypyridyl complexes; triazole; imidazole; cyclometalated complexes; ruthenium; osmium; platinum; triarylamines; ferrocene; pyrene; near-infrared; electrochromism; electropolymerization.
1. mononuclear cyclometalated Ru/Os complexes

2. mixed-valence systems with cyclometalated bisruthenium complexes


3. redox-asymmetric mixed-valence systems


4. three redox-center systems


5. four and multi redox-center systems

6. near-infrared electromism in electropolymerized metallopolymeric films


7. near-infrared emitting materials

8. ion recognitions using organometallic compounds

9 dye-sensitized solar cells

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Professor
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Group Members
Professor
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网站地图
Professor
Current Members
Former Members







Prof. YuWu Zhong

Yu-Wu Zhong
Email:zhongyuwu@iccas.ac.cn
Phone: +86-(0)
Office:2#415
Lab: 2#-413，416

Professor of the Key Laboratory of Photochemistry，Institute of Chemistry，Chinese Academy of Sciences.

Yu-Wu Zhong was born in June 1977 at Song Yang，Zhejiang，China. He obtained his bachelor degree in July 1999 from Nankai University. He obtained the Ph.D. in July 2004 from the Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences under the supervision of Prof. Guo-Qiang Lin. From September 2004 to September 2006，he has been a postdoctoral researcher at the University of Tokyo with Prof. Eiichi Nakamura. From October 2006 to September 2009，He worked with Prof Hector D. Abruna at Cornell University as a postdoctoral researcher. In October 2009，Yu-Wu Zhong joined the Institute of Chemistry，Chemistry Academy of Sciences，to start his independent career.

His research interests include organic and organometallic materials with optoelectronic functions，mixed-valence systems involving cyclometalated complexes as the charge-bearing sites，metallopolymeric films via electropolymerization，and near-infrared electrochromism. He has published over 50 research articles in journals such as JACS and Coord. Chem. Rev. His work is currently supported by several funding awards from the national natural science foundation of China and the Ministry of Science and Technology.


Selected publications:

1. Yu-Wu Zhong*，Chang-Jiang Yao，Hai-Jing Nie，Electropolymerized Films of Vinyl-substituted Polypyridine Complexes: Synthesis，Characterization，and Applications，Coord. Chem. Rev.2013，257(7-8)，1357-1372.


2.Hai-Jing Nie，Xialing Chen，Chang-Jiang Yao，Yu-Wu Zhong*，Geoffrey R. Hutchison*，Jiannian Yao*，Electronic Coupling between Two Amine Redox Sites through the 5.5'-positions of Metal-Chelating 2.2'-Bipyridines，Chem. Eur. J.2012，18(45)，14497-14509.

3. Chang-Jiang Yao，Ren-Hui Zheng，Qiang Shi，Yu-Wu Zhong*，Jiannian Yao，1.4-Benzene-Bridged Covalent Hybrid of Triarylamine and Cyclometalated Ruthenium: A New Type of Organic-Inorganic Mixed-Valent System，Chem. Commun.2012，48(45)，5680-5682.

4. Chang-Jiang Yao，Yu-Wu Zhong*，Hai-Jing Nie，Hector D. Abruna，Jiannian Yao*，Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc.2011，133(51)，20720-20723.

5. Chang-Jiang Yao，Yu-Wu Zhong*，Jiannian Yao*，Charge Delocalization in a Cyclometalated Bisruthenium Complex Bridged by a Noninnocent 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc.2011，133(39)，15697-15706.

6. Yu-Wu Zhong，Yutaka Matsuo*，Eiichi Nakamura.* Lamellar assembly of conical molecules possessing a fullerene apex in crystals and liquid crystals，J. Am. Chem. Soc.2007，129，3052-3053.

7. Yu-Wu Zhong，Yi-Zhou Dong，Kai Fang，Kenji Izumi，Ming-Hua Xu*，Guo-Qiang Lin*， A highly efficient and direct approach for synthesis of enantiopure beta-amino alcohols by reductive cross-coupling of chiralN-tert-butanesulfinyl imines with aldehydes.J. Am. Chem. Soc.2005，127，11956-11957.

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Professor
Current Members
Former Members





Current Members
Staffs:

Jiang-Yang Shao Zhong-Liang Gong
shaojiangyang@iccas.ac.cn gongzhongliang@iccas.ac.cn


Jian-Hong Tang
tangjianhong@iccas.ac.cn
?
Students:



Meng-JiaSun Tian-GeSun
sunmengjia13@mails.ucas.ac.cn suntiange@iccas.ac.cn

Zhi-JuanLi Rui Li
lizhijuan@iccas.ac.cn lirui316@iccas.ac.cn

Kun Tang Zhong-Qiu Li
tangkun@iccas.ac.cn lizhongqiu17@mails.ucas.ac.cn

Wei Zeng Yu-Duan Wang
plzengwei@163.com wangyuduan18@mails.ucas.ac.cn

Hao Wang Li-Ran Zhang
@qq.com **@163.com

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Professor
Current Members
Former Members







Former Members

朱建强 (zhujianqiang001984@163.com)
隋龙臻 (suilongzhen@gmail.com)
康红卫 (kanghw@iccas.ac.cn)
吴静 (wujing051021@126.com)
汪雷 (wanglei90@iccas.ac.cn)
张友明 (zhangyouming1218@iccas.ac.cn)
姚长江 (yaochemistry@iccas.ac.cn)
聂海晶 (niehaijing@iccas.ac.cn)
邵将洋 (shaojiangyang@iccas.ac.cn)
吴四海 (wusihai@iccas.ac.cn)
龚忠亮 (gongzhongliang@iccas.ac.cn)
沈军舰 (shenjj@iccas.ac.cn)
杨文文 (yangwenwen@iccas.ac.cn)
崔彬彬 (binbincui@iccas.ac.cn)
何艳芹 (dheshan@126.com)
张春雨 (zhangchunyu1032@163.com)
余宙 (phapku@163.com)
冯骏 (fengljun@gmail.com)
郑嘉楠 (zhengjn@iccas.ac.cn)
邓利叶 (dengliye12345@163.com)

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2019 papers
2018 papers
2017 papers
2016 papers
2015 papers
2014 papers
2013 papers
2012 papers
2011 papers
2010 papers
2002-2009 papers

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单篇全文显示
2019
149. Jiang-Yang Shao^?, Ning Yang^?, Wang Guo, Bin-Bin Cui*, Qi Chen and Yu-Wu Zhong*, Introducing fluorene into organic hole transport materials to improve mobility and photovoltage for perovskite solar cells, Chem. Commun. 2019, DOI:10.1039/C9CC06155J.
148. Jian-Hong Tang^?, Yueqi Li^?, Qingqing Wu^?, Zixiao Wang^?, Songjun Hou, Kun Tang, Yue Sun, Hui Wang, Heng Wang, Cheng Lu, Xiang Wang, Xiaopeng Li, Dong Wang, Jiannian Yao, Colin J. Lambert*, Nongjian Tao*, Yu-Wu Zhong* and Peter J. Stang*, Single-molecule level control of host-guest interactions in metallocycle-C60 complexes, Nat. Commun. 2019, 10, 4599.
147. Jian-Hong Tang^?, Ruidong Ni^?, Yan-Qin He^?, Ryan T. Vanderlinden, Yanrong Li, Bingbing Shi, Zhong-Yu Li, Heng Wang*, Xiaopeng Li, Yue Sun*, Yu-Wu Zhong* and Peter J. Stang*, Metal?Organic Pt(II) Hexagonal-Prism Macrocycles and Their Photophysical Properties, Inorg. Chem. 2019, 58(19), 13376-13381.
146. Zhong-Qiu Li, Jian-Hong Tang and Yu-Wu Zhong*, Multidentate Anchors for Surface Functionalization, Chem. Asian J. 2019,14, 3119-3126.
145. Jiang-Yang Shao, Bin-Bin Cui, Jian-Hong Tang and Yu-Wu Zhong*, Resistive memory switching of transition-metal complexes controlled by ligand design. Coord. Chem. Rev. 2019, 393, 21-36.

144. Zhong-Liang Gong and Yu-Wu Zhong*, New insight into hydrogen bond-mediated electron transfer.Sci China Chem, 2019, 62, 927-928.
143. Si-Qi Zhang, Lin-Xiu Cheng, Zhong-Liang Gong, Wu-Biao Duan*, Bin Tu*, Yu-Wu Zhong* and Qing-Dao Zeng*, Temperature-Triggered Self-Assembled Structural Transformation: From Pure Hydrogen-Bonding Quadrilateral Nanonetwork to Trihexagonal Structures. Langmuir 2019,35, 6571-6577.
142. Meng-Jia Sun^?, Yingying Liu^?, zeng wei, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer. J. Am. Chem. Soc. 2019,141(15), 6157-6161.(front cover, 01-May-2019)

141. Jiang-Yang Shao and Yu-Wu Zhong*, Stabilization of a Cyclometalated Ruthenium Sensitizer on Nanocrystalline TiO2 by an Electrodeposited Covalent Layer. Inorg. Chem. 2019,58(5), 3509-3517.

140. Yutaka Matsuo*, Chu-Guo Yu, Takafumi Nakagawa, Hiroshi Okada, Hiroshi Ueno, Tian-Ge Sun, and Yu-Wu Zhong, Reduced Knoevenagel Reaction of Acetetracenylene-1,2-dione with Acceptor Units for Luminescent Tetracene Derivatives. J. Org. Chem. 2019,84(4), 2339-2345.
139. Zhi-Juan Li, Jiang-Yang Shao, Si-Hai Wu* and Yu-Wu Zhong*, Nanocrystalline Sb-Doped SnO₂ Films Modified with Cyclometalated Ruthenium Complexes for Two-Step Electrochromism. Dalton Trans. 2019, 48, 2197-2205.

138. Tian-Ge Sun, Zhi-Juan Li, Jiang-Yang Shao and Yu-Wu Zhong*, Electrochromism in Electropolymerized Films of Pyrene-Triphenylamine Derivatives. Polymers 2019, 11, 73.(Special Issue on Electrochromic Polymers)

137. Zhong-Liang Gong, Rui Li and Yu-Wu Zhong, Electroluminochromism: Classical Materials and New Developments, Chapter 7 of Electrochromic Smart Materials: Fabrication and Applications, edited by Jian Wei Xu, Ming Hui Chua, Kwok Wei Shah, RSC 2019.

136. Chang-Jiang Yao, Kexiang Zhao, Guankui Long, Xinxiong Li, Zhong-Liang Gong, Yu-Wu Zhong, Weibo Gao, Yongxin Li, Rakesh Ganguly, Gang Lie, and Qichun Zhang *, Synthesis, characterization and photophysical studies of a novel polycyclic diborane. New J. Chem. 2019,43, 564-568.

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单篇全文显示
2018
135. Bin-Bin Cui*, Ying Han, Ning Yang, Shuangshuang Yang, Liuzhu Zhang, Yue Wang, Yifei Jia, Lin Zhao, Yu-Wu Zhong, and Qi Chen, Propeller-Shaped, Triarylamine-Rich, and Dopant-Free Hole-Transporting Materials for Efficient n–i–p Perovskite Solar Cells. ACS Appl. Mater. Interfaces2018, 10(48), 41592-41598.
134. Zhi-Juan Li^§, Jun-Jian Shen^§, Jiang-Yang Shao, and Yu-Wu Zhong*, Substituent Effects on the Electrochemistry and Electronic Coupling of Terphenyl-Bridged Cyclometalated Ruthenium-Amine Conjugated Complexes. ACS Omega2018, 3(12), 16744-16752.

133. Jian-Hong Tang, Zhenfeng Cai, Dong Yan, Kun Tang, Jiang-Yang Shao, Chuanlang Zhan, Dong Wang, Yu-Wu Zhong,* Li-Jun Wan, and Jiannian Yao, A Molecular Quadripod as a Noncovalent Interfacial Coupling Reagent for Forming Immobilized Coordination Assemblies. J. Am. Chem. Soc. 2018,140, 12337-12340.

132. Liu Tiecheng, Zhang Li, Sun Jing, Zhong Yuwu, Wang Zhongyang, Guo Xinjun, Ruan Hao*. Optical Properties of Dithienylethene and Its Applications in Super-Resolution Optical Storage. Chinese Journal of Lasers, 2018, 45(9), **.(in Chinese)
131. Qian-Qing Ge^‡, Jiang-Yang Shao^‡,*, Jie Ding, Li-Ye Deng, Wen-Ke Zhou, Yao-Xuan Chen, Jing-Yuan Ma, Li-Jun Wan, Jiannian Yao, Jin-Song Hu*, and Yu-Wu Zhong*, A Two‐Dimensional Hole‐Transporting Material for High‐Performance Perovskite Solar Cells with 20% Average Efficiency. Angew. Chem. Int. Ed. 2018,57, 10959-10965.

130. Bin-Bin Cui*, Ning Yang, Congbo Shi, Shuangshuang Yang, Jiang-Yang Shao, Ying Han, Liuzhu Zhang, Qingshan Zhang, Yu-Wu Zhong and Qi Chen*, Naphtho[1,2-b:4,3-b']dithiophene-based hole transporting materials for high-performance perovskite solar cells: molecular engineering and opto-electronic properties. J. Mater. Chem. A2018, 6, 10057-10063.
129. Jian-Hong Tang^‡, Yue Sun^‡, Zhong-Liang Gong, Zhong-Yu Li, Zhixuan Zhou, Heng Wang, Xiaopeng Li, Manik Lal Saha*, Yu-Wu Zhong* and Peter J. Stang*, Temperature-Responsive Fluorescent Organoplatinum(II) Metallacycles. J. Am. Chem. Soc. 2018,140, 7723-7729.

128. Meng-Jia Sun, Yu-Wu Zhong* and Jiannian Yao*, Thermal-Responsive Phosphorescent Nanoamplifiers Assembled from Two Metallophosphors. Angew. Chem. Int. Ed. 2018,57, 7820-7825.

127. Meng-Jia Sun, Yingying Liu, Yaming Yan, Rui Li, Qiang Shi*, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, In Situ Visualization of Assembly and Photonic Signal Processing in a Triplet Light-Harvesting Nanosystem. J. Am. Chem. Soc. 2018,140, 4269−4278.

126. Ce Zhou^‡, Xingxing Li^‡, Zhongliang Gong^‡, Chuancheng Jia, Yuanwei Lin, Chunhui Gu, Gen He, Yuwu Zhong*, Jinlong Yang* and Xuefeng Guo*, Direct observation of single-molecule hydrogen-bond dynamics with single-bond resolution. Nat. Commun. 2018, 9, 807.

125. Dongmei Li^‡, Jiang-Yang Shao^‡, Yiming Li, Yusheng Li, Li-Ye Deng, Yu-Wu Zhong* and Qingbo Meng*, New hole transporting materials for planar perovskite solar cells. Chem. Commun. 2018, 54, 1651-1654.

124. Rui Li, Zhong-Liang Gong, Jian-Hong Tang, Meng-Jia Sun, Jiang-Yang Shao, Yu-Wu Zhong* and Jiannian Yao, Triarylamines with branched multi-pyridine groups: modulation of emission properties by structural variation, solvents, and tris(pentafluorophenyl)borane. Sci. China Chem. 2018,61(5), 545-556.

123. Jiang-Yang Shao, Zhong-Liang Gong and Yu-Wu Zhong*, Bridged cyclometalated diruthenium complexes for fundamental electron transfer studies and multi-stage redox switching. Dalton Trans. 2018, 47, 23-29.(invited Frontier article).

122. Si-Hai Wu,* Jiang-Yang Shao, Zhong-Liang Gong, Na Chen and Yu-Wu Zhong*, Tuning the dual emissions of a monoruthenium complex with a dangling coordination site by solvents, O2, and metal ions. Dalton Trans. 2018, 47, 292-297.

121. Jun Feng, Jiang-Yang Shao, Hai-Jing Nie, Zhong-Liang Gong, Yu-Wu Zhong*, Synthesis and electrochemical and spectroscopic studies of a N,N,N',N'-tetraphenylbenzidine-bridged bis(2,2'-bipyridine) ligand and diruthenium complex. Chin. Chem. Lett. 2018,29, 385-389.

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单篇全文显示
2017
120. Jian-Hong Tang, Tian-Ge Sun, Jiang-Yang Shao, Zhong-Liang Gong and Yu-Wu Zhong*, Resistive memory devices based on a triphenylamine-decorated non-precious cobalt(II) bis-terpyridine complex, Chem. Commun. 2017, 53, 11925-11928.

119. Zhong-Liang Gong, Yu-Wu Zhong* and Jiannian Yao, Regulation of Intra- and Intermolecular Pt-Pt and π-π Interactions of a U-Shaped Diplatinum Complex to Achieve Pseudo-Polymorphic Emissions in Solution and Crystalline States, J. Mater. Chem. C 2017, 5, 7222-7229.

118. Zhi-Juan Li, Jiang-Yang Shao, Yu-Wu Zhong*, Near-Infrared and Two-Wavelength Electrochromism Based on Nanocrystalline TiO₂ Films Functionalized with Ruthenium-Amine Conjugated Complexes, Inorg. Chem. 2017,56, 8538?8546.

117. Si-Hai Wu*, Jiang-Yang Shao, Xiaojuan Dai, Xiuling Cui, Hongmei Su, Yu-Wu Zhong*, Synthesis and Characterization of Trisbidentate Ruthenium Complexes of Di(pyrid-2-yl)-methylamine, Eur. J. Inorg. Chem. 2017,24, 3064-3071.

116. Jiang-Yang Shao, Yu-Wu Zhong*, pH value-dependent electronic absorption and Ru(III/II) potential of bis-tridentate pincer ruthenium complexes, J. Organometall. Chem. 2017, 845, 144-150.(special issue of Organometallic Chemistry of Pincer Complexes)

115.Zhong-Liang Gong, Li-Ye Deng, Yu-Wu Zhong*, and Jiannian Yao, Anion-Regulated Electronic Communication in a Cyclometalated Diruthenium Complex with a Urea Bridge,Phys. Chem. Chem. Phys.2017,19, 8902-8907.

114.Hongwei Song, Xian Wang, WenWen Yang, Guiying He, Zhuoran Kuang, Yang Li, Andong Xia, Yu-Wu Zhong,* Fan'ao Kong*, Ultrafast Relaxation Dynamics of Amine-Substituted Bipyridyl Ruthenium(II) Complexes,Chem. Phys. Lett.2017, 683, 322-328.(Ahmed Zewail Commemoration Issue)

113.Zhong-LiangGong,Chang-JiangYao,Jiang-YangShao,Hai-JingNie,Jian-HongTang, Yu-WuZhong*,Redox-responsive carbometalated ruthenium and osmium complexes,Sci. China Chem.2017,60(5), 583-590.

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单篇全文显示
2016
112. Meng-Jia Sun, Xinliang Zhang, Yu-Wu Zhong*, Chuanlang Zhan*, and Jiannian Yao*, Tunable Self-Assembly and Morphology-Dependent Photoconductivity of a Donor–Acceptor-Structured Diruthenium Complex, Inorg. Chem. 2016,55(24), 13007-13013.

111. Linxiu Cheng, Yibao Li, Chun-Yu Zhang, Zhong-Liang Gong, Qiaojun Fang, Yu-Wu Zhong*, Bin Tu*, Qingdao Zeng*, and Chen Wang, Temperature-Triggered Chiral Self-Assembly of Achiral Molecules at the Liquid–Solid Interface, ACS Appl. Mater. Interfaces 2016,8(46),32004-32010.

110. Jian-Hong Tang, Yan-Qin He, Jiang-Yang Shao, Zhong-Liang Gong, Yu-Wu Zhong*, Multistate Redox Switching and Near-Infrared Electrochromism Based on a Star-Shaped Triruthenium Complex with a Triarylamine Core, Sci. Rep. 2016, 6, 35253.

109. Zhong-Liang Gong, Yu-Wu Zhong*, H₂PO₄^-- and Solvent-Induced Polymorphism of an Amide-Functionalized [Pt(N^C^N)Cl] Complex, Inorg. Chem. 2016, 55(20), 10143-10151.

108.Jiang-Yang Shao,? Dongmei Li,? Kun Tang, Yu-Wu Zhong* and Qingbo Meng*,Simple biphenyl or carbazole derivatives with four di(anisyl)amino substituents as efficient hole-transporting materials for perovskite solar cells,RSCAdv.2016, 6, 92213-92217.

107. Bin-Bin Cui, Jian-Hong Tang, Yu-Wu Zhong*, Resistive Memory Materials Based on Transition-Metal Complexes, Acta Chim. Sinica 2016, 74(9), 726-733.(in Chinese)

106. Lin Wang⁺, Zhong-Liang Gong⁺, Shu-Ying Li, Wenjing Hong*, Yu-Wu Zhong*, Dong Wang*, Li-Jun Wan, Molecular Conductance through a Quadruple-Hydrogen-Bond-Bridged Supramolecular Junction,Angew. Chem. Int. Ed.2016,55(40), 12393-12397.

105. Zhongliang Gong, Changjiang Yao, Jiangyang Shao, Haijing Nie, Jianhong Tang, and Yuwu Zhong*, Redox-responsive cyclometalated ruthenium and osmium complexes, Sci. Sin. Chim.2016, 46(10), 1093-1100.(in Chinese)

104. Jun Feng, Jiang-Yang Shao, Zhong-Liang Gong, Yu-Wu Zhong*, Amine-Amine Electronic Coupling through an Anthracene Bridge,Chin. J. Org. Chem.2016, 36(10), 2407-2412.

103.Jian-Hong Tang, Jiang-Yang Shao, Yan-Qin He, Si-Hai Wu, Jiannian Yao, Yu-Wu Zhong*, Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System, Chem. Eur. J. 2016,22(30), 10341-10345.

102. Jiang-Yang Shao, Chang-Jiang Yao, Bin-Bin Cui, Zhong-Liang Gong, Yu-Wu Zhong,* Electropolymerized films of redox-active ruthenium complexes for multistate near-infrared electrochromism, ion sensing, and information storage, Chin. Chem. Lett. 2016, 27(8), 1105-1114.(special issue of pai-Functional Molecules & Polymers)

101. Hai-Jing Nie, Wen-Wen Yang, Jiang-Yang Shao and Yu-Wu Zhong,* Ruthenium-Tris(bipyridine) Complexes with Multiple Redox-Active Amine Substituents: Tuning of Spin Density Distribution and Deep-Red to NIR Electrochromism and Electrofluorochromism, Dalton Trans. 2016, 45, 10136-10140.

100. Xing-Dong Xu, Chang-Jiang Yao, Li-Jun Chen, Guang-Qiang Yin, Yu-Wu Zhong,* and Hai-Bo Yang*, Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization, Chem. Eur. J. 2016, 22(15), 5211-5218.

99. You-Ming Zhang, Fanyuan Meng, Jian-Hong Tang, Yafei Wang, Caifa You, Hua Tan, Yu Liu, Yu-Wu Zhong,* Shijian Su* and Weiguo Zhu*, Achieving near-infrared emission in platinum(II) complexes by using an extended donor–acceptor-type ligand, Dalton Trans. 2016, 45, 5071-5080.

98. Jian-Hong Tang, Chang-Jiang Yao, Bin-Bin Cui andYu-Wu Zhong*, Ruthenium-Amine Conjugated Organometallic Materials for Multistate Near-IR Electrochromism and Information Storage,Chem. Rec. 2016, 16(2), 754-767.

97. Zhong-Liang Gong, Jiang-Yang Shao,Yu-Wu Zhong*, Synthesis, Structural Diversity, and Redox Control of Cyclometalated Monoruthenium Complexes, J. Electrochem. 2016, 22(3), 244-259.

96. Yu-Wu Zhong*, Zhong-Liang Gong, Jiang-Yang Shao, Jiannian Yao, Electronic coupling in cyclometalated ruthenium complexes, Coord. Chem. Rev. 2016, 312, 22-40.

95. Jun-Jian Shen, Jiang-Yang Shao, Xiaozhang Zhu*, and Yu-Wu Zhong*,Amine－Amine Electronic Coupling through a Dibenzo[a,e]pentalene Bridge,Org. Lett.2016,18(2), 256-259.

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单篇全文显示
2015
94. Jun-Jian Shen, Jiang-Yang Shao, Zhong-Liang Gong, and Yu-Wu Zhong*, Cyclometalated Osmium-Amine Electronic Communication through the p-Oligophenylene Wire, Inorg. Chem. 2015, 54(22), 10776-10784.

93. Jiang-Yang Shao, Nianqing Fu, Wen-Wen Yang, Chun-Yu Zhang, Yu-Wu Zhong,* Yuan Lin,* and Jiannian Yao, Cyclometalated ruthenium(II) complexes with bis(benzimidazolyl)benzene for dye-sensitized solar cells, RSC Adv. 2015, 5, 90001-90009.

92. Jun-Jian Shen, Yu-Wu Zhong,* Long-Range Ruthenium-Amine Electronic Communication through the para-Oligophenylene Wire, Sci. Rep. 2015, 5, 13835.

91. Zhong-Liang Gong, Yu-Wu Zhong,* Urea-bridged diferrocene: structural, electrochemical, and spectroelectrochemical studies, Sci. China Chem. 2015, 58(9), 1444-1450.

90. Yu-Wu Zhong, Electrochromism within Transition-Metal Coordination Complexes and Polymers, Chapter 6 of Electrochromic Materials and Devices, edited by Roger J. Mortimer, David R. Rosseinsky and Paul M. S. Monk, 2015 Wiley-VCH.

89. Meng-Jia Sun, Jiang-Yang Shao*, Chang-Jiang Yao, Yu-Wu Zhong*, and Jiannian Yao*, Osmium Bisterpyridine Complexes with Redox-Active Amine Substituents: A Comparison Study with Ruthenium Analogues, Inorg. Chem.2015, 54(16), 8136-8147.

88. Bin-Bin Cui, Jian-Hong Tang, Jiannian Yao, and Yu-Wu Zhong*, A Molecular Platform for Multistate Near-Infrared Electrochromism and Flip-Flop, Flip-Flap-Flop, and Ternary Memory,Angew. Chem. Int. Ed.2015,54(32), 9192-9197.

87. Azusa Kajikawa, Takanari Togashi, Yuka Orikasa, Bin-Bin Cui, Yu-Wu Zhong, Masatomi Sakamoto, Masato Kurihara*, and Katsuhiko Kanaizuka*, Construction of hybrid films of silver nanoparticles and polypyridine ruthenium complexes on substrates,Dalton Trans.2015,44, 15244-15249.

86. Wen-Wen Yang, Jiang-Yang Shao, and Yu-Wu Zhong*, Cyclometalated Diruthenium Complexes Bridged by 3,3′,5,5′-Tetra(pyrid-2-yl)biphenyl: Tuning of Electronic Properties and Intervalence Charge Transfer by Terminal Ligand Effects, Eur. J. Inorg. Chem.2015, (19), 3195-3204.

85. Chang-Jiang Yao, Hai-Jing Nie, Wen-Wen Yang, Jiannian Yao, and Yu-Wu Zhong*, Combined Experimental and Computational Study of Pyren-2,7-diyl-Bridged Diruthenium Complexes with Various Terminal Ligands，Inorg. Chem.2015, 54(10), 4688-4698.

84. Meng-Jia Sun,Hai-Jing Nie,Jian-Nian Yao,Yu-Wu Zhong*, Bis-triarylamine with a cyclometalated diosmium bridge: a multi-stage redox-active system, Chin. Chem. Lett. 2015,26(6), 649-652.

83. Bin-Bin Cui, Yu-Wu Zhong*, Jiannian Yao, Three-State Near-Infrared Electrochromism at the Molecular Scale,J. Am. Chem. Soc. 2015,137(12),4058-4061.

82. Hai-Jing Nie, Wen-Wen Yang, Ren-Hui Zheng, Qiang Shi, Hui Chen, Jiannian Yao, and Yu-Wu Zhong,* Metal Chelation-Assisted Amine?Amine Electronic Coupling through the 4,4′-Positions of 2,2′-Bipyridine,Inorg. Chem.2015,54(4),1272-1282.

81. Yan-Qin He and Yu-Wu Zhong,* The synthesis of 2- and 2,7-functionalized pyrene derivatives through Ru(II)-catalyzed C–H activation, Chem. Commun. 2015,51,3411-3414.

80. Bin-Bin Cui, Zupan Mao, Yuxia Chen, Yu-Wu Zhong*, Gui Yu,* Chuanlang Zhan,* Jiannian Yao*, Tuning of Resistive Memory Switching in Electropolymerized Metallopolymeric films,Chem. Sci.2015, 6, 1308-1315.

79. Zhong-Liang Gong, Yu-Wu Zhong,* and Jiannian Yao, Conformation-Determined Through-Bond versus Through-Space Electronic Communication in Mixed-Valence Systems with a Cross-Conjugated Urea Bridge,Chem. Eur. J. 2015, 21(4), 1554-1566.

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单篇全文显示
2014
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78.Qing-Na Zheng, Xuan-He Liu, Xing-Rui Liu, Ting Chen, Hui-Juan Yan, Yu-Wu Zhong, Dong Wang,* and Li-Jun Wan,* Bilayer Molecular Assembly at a Solid/Liquid Interface as Triggered by a Mild Electric Field,Angew. Chem. Int. Ed.2014,53, 13395-13399.

77. Chang-Jiang Yao, Hai-Jing Nie, Wen-Wen Yang, Jiang-Yang Shao, Jiannian Yao, and Yu-Wu Zhong,* Strongly Coupled Cyclometalated Ruthenium–Triarylamine Hybrids: Tuning Electrochemical Properties, Intervalence Charge Transfer, and Spin Distribution by Substituent Effects, Chem. Eur. J. 2014, 20(52), 17466-17477.

76. Hai-Jing Nie, Chang-Jiang Yao, Jiang-Yang Shao, Jiannian Yao, and Yu-Wu Zhong,* Oligotriarylamines with a Pyrene Core: A Multicenter Strategy for Enhancing Radical Cation and Dication Stability and Tuning Spin Distribution, Chem. Eur. J. 2014, 20(52), 17454-17465.

?
75. Junjian Shen, Dafei Yuan, Yan Qiao, Xingxing Shen, Zhongbo Zhang, Yuwu Zhong, Yuanping Yi, and Xiaozhang Zhu,* Diaceno[a,e]pentalenes from Homoannulations of o?Alkynylaryliodides Utilizing a Unique Pd(OAc)2/n?Bu4NOAc Catalytic Combination, Org. Lett. 2014, 16, 4924?4927.

74. Hai-Jing Nie,Chang-Jiang Yao,Meng-Jia Sun, Yu-Wu Zhong,* Jiannian Yao,* Ruthenium-bis-terpyridine Complex with Two Redox-Asymmetric Amine Substituents: Potential-Controlled Reversal of the Direction of Charge-Transfer, Organometallics 2014, 33(21), 6223-6231.

73. Hai-Jing Nie, Yu-Wu Zhong,* Near-Infrared Electrochromism in Electropolymerized Metallopolymeric Films of a Phen-1,4-diyl-Bridged Diruthenium Complex, Inorg. Chem. 2014, 53(20), 11316-11322.

72. Bin-Bin Cui, Jiang-Yang Shao,Yu-Wu Zhong,* Bis-Tridentate Ruthenium Complexes with a Redox-Active Amine Substituent: Electrochemical, Spectroscopic, and DFT/TDDFT Studies, Organometallics 2014, 33(16), 4220-4229.

71. Hai-Jing Nie, Jiang-Yang Shao, Chang-Jiang Yao, Yu-Wu Zhong,* Organic–inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium, Chem. Commun. 2014, 50(70), 10082-10085.

70. Takumi Nagashima, Takuya Nakabayashi, Takashi Suzuki, Katsuhiko Kanaizuka, Hiroaki Ozawa, Yu-Wu Zhong, Shigeyuki Masaoka, Ken Sakai, Masa-aki Haga,* Tuning of metal-metal interactions in mixed-valence states of cyclometalated dinuclear ruthenium and osmium complexes bearing tetrapyridylpyrazine or –benzene, Organometallics 2014, 33(18), 4893-4904.

69. Jiang-Yang Shao, Yu-Wu Zhong,* Tuning the electronic coupling in cyclometalated diruthenium complexes through substituent effects: a correlation between the experimental and calculated results, Chem. Eur. J. 2014, 20(28), 8702-8713.

68. Chang-Jiang Yao, Yu-Wu Zhong,* Near-infrared electrochromism in mixed-valent diruthenium complexes (in Chinese), Chin. Sci. Bull. 2014, 59(17), 1591-1602.
67. Zhong-Liang Gong, Bin-Bin Cui, Wen-Wen Yang, Jiannian Yao, Yu-Wu Zhong,* Reversible multichannel detection of Cu²⁺ using an electropolymerized film, Electrochim. Acta 2014, 130(1), 748-753.

66. Qing-Na Zheng, Lei Wang, Yu-Wu Zhong, Xuan-He Liu, Ting Chen, Hui-Juan Yan, Dong Wang,* Jian-Nian Yao, Li-Jun Wan,* Adaptive reorganization of 2D molecular nanoporous network induced by coadsorbed guest molecule, Langmuir. 2014, 30(11), 3034-3040.

65. Bin-Bin Cui, Chang-Jiang Yao, Jiannian Yao, Yu-Wu Zhong,* Electropolymerized films as a molecular platform for volatile memory devices with two near-infrared outputs and long retention time, Chem. Sci. 2014, 5(3), 932-941.

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2013 papers
2013
64. Zhong-Liang Gong, Yu-Wu Zhong,* Stepwise Coordination Followed by Oxidation Mechanism for the Multichannel Detection of Cu²⁺ in an Aqueous Environment, Organometallics 2013, 32(24), 7495-7502.

63. Feng Gao, Long Cui, Wei Liu, Liang Hu, Yu-Wu Zhong, Yi-Zhi Li, Jing-Lin Zuo,* Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Ligand, Inorg. Chem. 2013, 52(19), 11164-11172.


62. Si-Hai Wu, Jiang-Yang Shao, Hong-Wei Kang, Jiannian Yao, Yu-Wu Zhong,* Substituent and Solvent Effects on the Electrochemical Properties and Intervalence Transfer in Asymmetric Mixed-Valent Complexes Consisting of Cyclometalated Ruthenium and Ferrocene, Chem. Asian J. 2013, 8(11), 2843-2850.

61. Bin-Bin Cui, Hai-Jing Nie, Chang-Jiang Yao, Jiang-Yang Shao, Si-Hai Wu, Yu-Wu Zhong,* Reductive electropolymerization of bis-tridentate ruthenium complexes with 5,5''-divinyl-4'-tolyl-2,2':6',2''-terpyridine, Dalton Trans. 2013, 42(39), 14125-14133.

60. Chang-Jiang Yao, Ren-Hui Zheng, Hai-Jing Nie, Bin-Bin Cui, Qiang Shi, Jiannian Yao, Yu-Wu Zhong,* A Combined Experimental and Computational Study of Linear Ruthenium(II) Coordination Oligomers with End-Capping Organic Redox Sites: Insight into the Light Absorption and Charge Delocalization, Chem. Eur. J. 2013, 19(37), 12376-12387.

59. Mao Li,* Jian Zhang, Hai-Jing Nie, Meiyong Liao, Liwen Sang, Wenqiang Qiao, Zhi Yuan Wang, Yuguang Ma, Yu-Wu Zhong,* Katsuhiko Ariga,* In situ switching layer-by-layer assembly: one-pot rapid layer assembly via alternation of reductive and oxidative electropolymerization, Chem. Commun. 2013, 49(61), 6879-6881.

58. Chuancheng Jia, Jinying Wang, Changjiang Yao, Yang Cao, Yuwu Zhong, Zhirong Liu, Zhongfan Liu,* Xuefeng Guo,* Conductance Switching and Mechanisms in Single-Molecule Junctions, Angew. Chem. Int. Ed. 2013, 52(33), 8666-8670.

57. Jian-Hong Tang, Si-Hai Wu, Jiang-Yang Shao, Hai-Jing Nie, Yu-Wu Zhong,* Ruthenium-Amine Electronic Coupling Bridged through Phen-1,3-diyl Versus Phen-1,4-diyl: Reverse of the Charge Transfer Direction, Organometallics 2013, 32(16), 4564-4570.

56. Chang-Jiang Yao, Yu-Wu Zhong,* Jiannian Yao, Five-Stage Near-Infrared Electrochromism in Electropolymerized Films Composed of Alternating Cyclometalated Bisruthenium and Bis-triarylamine Segments, Inorg. Chem. 2013, 52(17), 10000-10008.

55. Jiang-Yang Shao, Yu-Wu Zhong,* Monometallic Osmium(II) Complexes with Bis(N-methylbenzimidazolyl)benzene or-pyridine: A Comparison Study with Ruthenium(II) Analogues, Inorg. Chem. 2013, 52(11), 6464-6472.

54. Si-Hai Wu, Yu-Wu Zhong,*Jiannian Yao,2.3-Di(2-pyridyl)-5-phenylpyrazine: A NN-CNN-type Bridging Ligand for Dinuclear Transition-Metal Complexes, Chem. Asian J. 2013, 8(7), 1504-1513.


53. Chang-Jiang Yao，Yu-Wu Zhong*，Jiannian Yao，Multi-Center Redox-Active System: Amine-Amine Electronic Coupling through a Cyclometalated Bisruthenium Segment，Inorg. Chem.2013，52(7)，4040-4045.


52. Lei Wang，Wen-Wen Yang，Yu-Wu Zhong*，Jiannian Yao*，Enhancing the Electronic Coupling in a Cyclometalated Bisruthenium Complex by Using the 1.3.6.8-Tetra(pyridine-2-yl)carbazole Bridge，Dalton Trans. 2013，42(16)，5611-5614.


51. Wen-Wen Yang，Yu-Wu Zhong*，Cyclometalated Ruthenium Complexes of 1,2,3-Triazole-containing Ligands: Synthesis，Structural Studies，and Electronic Properties，Chin. J. Chem.2013，31(3)，329-338. (Dedicated to Prof. Guo-Qiang Lin on the occasion of his 70^thbirthday).

50. Yu-Wu Zhong*，Chang-Jiang Yao，Hai-Jing Nie，Electropolymerized Films of Vinyl-substituted Polypyridine Complexes: Synthesis，Characterization，and Applications，Coord. Chem. Rev.2013，257(7-8)，1357-1372.


49. Si-Hai Wu，Jun-Jian Shen，Jiannian Yao，Yu-Wu Zhong*，Asymmetric Mixed-Valence Complexes that Consist of Cyclometalated Ruthenium and Ferrocene: Synthesis，Characterization，and Electronic Coupling Studies，Chem. Asian J.2013，8(1)，138-147.