课题组长
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何圣贵 研究员
联系我们
地址：北京市海淀区中关村北一街 2号
中国科学院化学研究所
邮编：100190
电话：+86-
邮箱 : shengguihe@iccas.ac.cn
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招生：课题组每年有2个招生名额，欢迎报考！
课题组研究方向简介
1. 惰性小分子活化转化研究
分子的活化转化是化学研究的核心内容，其中，惰性小分子的活化转化十分困难，但意义特别重大，例如，合成氨（N2+ 3H2 ->2NH3）对人类现代化有不可估量的贡献。目前，CH4、CO2、N2等惰性分子的活化转化（CH4->C2Hx, CH4+ H2O -> CH2O + 2H2, CO2+ H2->CxHyOz…）常常需要高温、高压、强酸、强碱等苛刻条件，寻找温和条件下惰性小分子活化转化新途径，是本课题组研究的重要方向。我们使用自主研制的实验仪器，制备几个至上百个原子组成的原子团簇，在完全可控、可重复的条件下，测定团簇与CH4、CO2、N2等分子在温和条件下的反应，筛选出性能优良的团簇，结合先进谱学实验和量子化学计算认识其反应机理，进一步探索分子宏量催化转化的方法。我们在甲烷、氮气、二氧化碳等分子活化转化方面取得了系列研究进展。
2. 挥发性有机物检测研究
挥发性有机物（volatile organic compounds, VOCs）是一类大气污染物，具有致癌、致畸、致突变性，严重危害人体健康，同时，VOCs 也是光化学烟雾和PM2.5的重要前体物。VOCs也是人体呼出物和食品挥发物的重要成分，相关检测有助于疾病早期诊断和食品质量鉴定。化学电离质谱检测具有选择性高和软电离等特点，在VOCs检测中具有重要的优势。基于我们自主开发的团簇质谱实验仪器，寻找新型离子源，高灵敏、特异性检测VOCs是本课题组的重要研究方向，最近，我们在长链烷烃、乙二醛、甲基乙二醛无碎裂高灵敏质谱检测方面取得了研究进展。
3. 科学仪器设计与研制
科学仪器是推动科学研究的主要动力，针对上述惰性小分子活化转化研究、挥发性有机物检测研究中不断出现的科学问题，我们自主设计研制包括机械、真空、光学、电学、自动控制等技术在内的实验仪器。课题组利用电子和离子轨迹模拟、工程设计等软件，从头设计并建立了四套大型实验仪器，实现了高分辨率质谱、碰撞和光诱导解离质谱、真空-紫外光电离质谱、红外光解离光谱、光电子速度成像、四极质量过滤器、低温与高温离子阱等实验技术的集成与发展，建立了团簇综合研究实验平台。
课题组长
?
何圣贵 研究员
联系我们
地址：北京市海淀区中关村北一街 2号
中国科学院化学研究所
邮编：100190
电话：+86-
邮箱 : shengguihe@iccas.ac.cn
?
招生：课题组每年有2个招生名额，欢迎报考！
课题组研究方向简介
1. 惰性小分子活化转化研究
分子的活化转化是化学研究的核心内容，其中，惰性小分子的活化转化十分困难，但意义特别重大，例如，合成氨（N2+ 3H2 ->2NH3）对人类现代化有不可估量的贡献。目前，CH4、CO2、N2等惰性分子的活化转化（CH4->C2Hx, CH4+ H2O -> CH2O + 2H2, CO2+ H2->CxHyOz…）常常需要高温、高压、强酸、强碱等苛刻条件，寻找温和条件下惰性小分子活化转化新途径，是本课题组研究的重要方向。我们使用自主研制的实验仪器，制备几个至上百个原子组成的原子团簇，在完全可控、可重复的条件下，测定团簇与CH4、CO2、N2等分子在温和条件下的反应，筛选出性能优良的团簇，结合先进谱学实验和量子化学计算认识其反应机理，进一步探索分子宏量催化转化的方法。我们在甲烷、氮气、二氧化碳等分子活化转化方面取得了系列研究进展。
2. 挥发性有机物检测研究
挥发性有机物（volatile organic compounds, VOCs）是一类大气污染物，具有致癌、致畸、致突变性，严重危害人体健康，同时，VOCs 也是光化学烟雾和PM2.5的重要前体物。VOCs也是人体呼出物和食品挥发物的重要成分，相关检测有助于疾病早期诊断和食品质量鉴定。化学电离质谱检测具有选择性高和软电离等特点，在VOCs检测中具有重要的优势。基于我们自主开发的团簇质谱实验仪器，寻找新型离子源，高灵敏、特异性检测VOCs是本课题组的重要研究方向，最近，我们在长链烷烃、乙二醛、甲基乙二醛无碎裂高灵敏质谱检测方面取得了研究进展。
3. 科学仪器设计与研制
科学仪器是推动科学研究的主要动力，针对上述惰性小分子活化转化研究、挥发性有机物检测研究中不断出现的科学问题，我们自主设计研制包括机械、真空、光学、电学、自动控制等技术在内的实验仪器。课题组利用电子和离子轨迹模拟、工程设计等软件，从头设计并建立了四套大型实验仪器，实现了高分辨率质谱、碰撞和光诱导解离质谱、真空-紫外光电离质谱、红外光解离光谱、光电子速度成像、四极质量过滤器、低温与高温离子阱等实验技术的集成与发展，建立了团簇综合研究实验平台。
单篇全文显示
课题组组长：何圣贵
在职职工： 李晓娜
赵艳霞
李子玉
刘清宇
离职职工：丁迅雷
在职学生：任熠
陈娇娇
卢雪伟
杨圆
吕士英
牟丽慧
魏龚平
姜桂朵
刘云竹
阮曼
赵西官
杨祁
在站博士后：韩路平
毕业学生
联合培养
单篇全文显示
课题组长
何圣贵研究员
中国科学院化学研究所
电话：+86-010-6256 8330
地址：北京市海淀区中关村北一街2号
邮编：100190
邮箱：shengguihe@iccas.ac.cn
学习经历
1993.9-1997.7：中国科学技术大学近代物理系，学士
1997.9-2002.7：中国科学技术大学化学物理系，物理化学专业，博士
工作经历
2002.9-2005.2：美国肯塔基大学化学系，博士后
2005.2-2007.1：美国科罗拉多州立大学化学系，博士后
2007.1-至今：中国科学院化学研究所，分子动态与稳态结构实验室，研究员，博士生导师
2015.9-至今：中国科学院大学，岗位教授
荣誉
2009 中国化学会青年化学奖
2012 中国分析测试学会科学技术奖二等奖
任职
2012-2016 International Journal of Mass Spectrometry 期刊编委
2013-至今 中国化学会化学动力学专业委员会委员
2015-至今化学所分析测试中心主任
2017-至今化学所所长助理
2018-至今 Journal of Physical Chemistry A/B/C/Letters 顾问编委
2019-至今 ChemPhysChem顾问编委
2019-至今化学所分子反应动力学实验室主任
研究方向：惰性化学键活化，团簇催化，质谱和光谱技术。
学术成果：发现了甲烷在温和条件下活化转化的协同策略，提出了异核金属氧化物团簇催化中的"电负性阶梯"效应，建立了氧自由和金属单原子催化研究的新方法。发表SCI论文200余篇，其中在Acc. Chem. Res.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed. 期刊上发表论文30余篇；授权专利4项。主持承担基金委****基金、重点项目、仪器研制项目等。
在职员工
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研 究 员 ：何圣贵
项目研究员：李晓娜
副 研 究 员： 赵艳霞
李子玉
助理研究员：刘清宇
单篇全文显示
硕博在读
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卢雪伟2017博士生
籍贯：山东滨州
2010-2014：山东理工大学学士
2014-2017：山东理工大学硕士
2017-09-至今中国科学院化学研究所
Email: luxuewei@iccas.ac.cn
陈娇娇 2015硕士生
籍贯: 安徽省潜山县
出生年月：1993年01月27号
2011年9月-2015年6月 安徽师范大学 化学与材料科学学院 应用化学专业
2015年9月-至今：中国科学院化学研究所
E-mail: chenjiaojiao115@mails.ucas.ac.cn
任熠 2015硕士生
籍贯：山东省聊城市
出生年月：1993.07
2011.09-2015.06 兰州大学 化学化工学院 化学专业
2015.09至今 中国科学院化学研究所
Email：renyi15@iccas.ac.cn
吕士英 2016级硕士生
籍贯：黑龙江省双鸭山市
出生年月：1993年8月14日
2012年9月-2016年6月：中国人民大学理学院化学专业
2016年9月-至今：中国科学院化学研究所
E-mail: lvshiying16@mails.ucas.ac.cn
杨圆 2016级硕士生
籍贯：河南省郑州市
2011.9-2015.6 郑州大学 化学与分子工程学院
2016.9-至今 化学研究所
E-mail：yangyuan161@mails.ucas.ac.cn
牟丽慧，2017级硕士生
籍贯：山东省菏泽市
出生年月：1995.4
2013-2017:北京工商大学化学系
2017-至今：中国科学院化学研究所
Email：moulhui@iccas.ac.cn
刘云竹2018级 直博生
籍贯：山东省青岛市
出生年月：1996年4月9日
2014年9月-2018年6月：北京工商大学理学院化学专业
2018年9月-至今中国科学院化学研究所
Email:liuyz_1218@163.com
姜桂朵 2018 直博生
籍贯：内蒙古乌兰察布市
出生年月：1996.10
2014.09-2018.06 中国矿业大学（北京）化学与环境工程学院
Email: jiangguiduo@iccas.ac.cn
阮曼 2018级硕博生
籍贯：河南省周口市
出生年月：1996.03.17
2014.10-2018.6:东北大学理学院
2018.9-至今：中国科学院化学研究所
Email：ruanman@iccas.ac.cn
魏龚平 2018级硕博生
籍贯：浙江省嘉兴市
出生年月：1994.11.15
2013.9-2017.6:北京师范大学化学学院
2018.9-至今：中国科学院化学研究所
Email：weigongping@iccas.ac.cn
杨祁 2019直博生
籍贯: 湖南永州
出生年月:1995.08
2015-2019: 湘潭大学化学学院
Email:**@163.com
赵西官 2019直博生
籍贯: 山东省菏泽市
出生年月:1997.06
2015-2019: 湘潭大学化学学院
Email：**@163.com
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毕业学生
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已毕业学生
1. 薛伟 2007.1 - 2009.12
毕业后：北京大学 博士后
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2. 王哲琛 2007.1 - 2010.1
毕业后：德国柏林工业大学 洪堡****
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3. 赵艳霞 2008.9 - 2011.7
毕业后： 留所工作
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4. 吴晓楠 2007.9 - 2012.7
毕业后：德国柏林工业大学 博士后
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5. 马嘉璧 2008.9 - 2013.7
毕业后：北京理工大学
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6. 徐波 2009.9 - 2014.7
毕业后：劳伦斯伯克利国家实验室 （美国 ）博士后
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7. 贾美叶 2011.9 - 2014.7
毕业后：留所工作
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8. 孟敬恒 2010.9 - 2015.7
毕业后：大连化物所 博士后
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9. 李子玉 2010.9 - 2015.7
毕业后：留所工作
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10. 袁震2011.9 - 2016.7
毕业后：留所工作（分析测试中心）
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11. 李海方 2014.9 - 2017.7
毕业后：清华大学 博士后
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12. 刘清宇 2012.9 - 2017.7
毕业后：留所工作
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13. 张婷 2015.9 - 2018.7
毕业后：美国 博士后
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14. 李亚柯 2013.9 - 2018.7
毕业后：德国 博士后
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15. 姜利学 2014.9 - 2019.7
毕业后：美国 博士后
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16. 张梅琦 2014.9 - 2019.7
毕业后：北京大学 博士后
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17. 王丽娜 2016.9 - 2019.7
毕业后：复旦大学 博士后
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博士后
在站博士后
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韩路平
2006.9-2010.7：北京工业大学
2010.9-2013.12 研究生：美国俄勒冈州立大学 (OSU) 材料科学专业
2013.12-2018.3 博士：美国加州大学河滨分校 (UCR)
2019.9至今：中科院化学研究所博士后
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已出站博士后
1. 马艳平 2007.3-2009.8
出站去向：中科院化学所，高分子物理与化学实验室，副研究员。
2. 李晓娜 2010.12-2012.12
出站去向：中科院化学所，分子动态与稳态结构实验室，副研究员。
3. 陈强 2016.10-2019.4
出站去向：山西大学，分子科学研究所，教授
曾经工作过职工
丁迅雷：2007.12-2013.06 副研究员
2013.07-~ 华北电力大学 教授
联合培养
联合培养学生
王斯顿 联合培养
籍贯：山西晋中
出生年月：1994.11
2014年9月-2018年6月:福建农林大学
2018年9月至今：华南理工大学
E-mail：wang_sidun@163.com
成鑫 联合培养
籍贯：山东东营
出生年月：1994.05
2013年9月-2017年6月:山东理工大学
2017年9月至今：华北电力大学
E-mail：chengxin_1028@163.com
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1. 田利华2012.9-2013.9
华南理工大学
2. 王丽娜 2013.9-2014.9
华南理工大学
3. 周小红 2015.9-2016.9
华南理工大学
4. 邹秀萍 2017.9-2018.10
华南理工大学
5. 张岩 2016.9-2017.8
华北电力大学
6. 陈一鸣 2017.9-2018.9
华北电力大学
7. 欧淑华 2018.9-2019.8
华南理工大学
8. 王萌萌 2018.9-2019.8
华北电力大学
单篇全文显示
1. 团簇离子源-四极质量过滤器-离子阱-高分辨率质谱耦合装置（团簇活性研究系统） 2. 团簇结构研究系统
3.纳米尺寸团簇结构系统
4.真空紫外光电离质谱（中性团簇研究系统）
发表论文
[2020] [2019] [2018] [2017] [2016] [2015] [2014]
[2013] [2012] [2011] [2010] [2009] [2008]
2020年论文
(1)Wang L-N, Li X-N, He S-G*, "Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters" Sci.China. Mater. 2020, DOI: 10.1007/s40843-019-1206-2.
(2)Ren Y, Liu Q-Y*, Zhao Y-X, Yang Q, He S-G*, "C-C Coupling of Methane Mediated by Atomic Gold Cations under Multiple-Collision Conditions", Acta. Phys.-Chim. Sin. 2020, 36, **.
2019年发表文章
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(1)ChenJ-J,LiX-N*,Chen Q,Liu Q-Y,Jiang L-X, He S-G, "Neutral Au1-Doped Cluster Catalysts AuTi2O3-6 for CO Oxidation by O2",J. Am.Chem. Soc.2019, 141, 2027-2034 (Front Cover). [PDF]
(2)ZhangM-Q,Lv S-Y,LiX-N*,He S-G*, "Cooperative Desorption of H2O and CO from Photo-Excited Cobalt Oxide Clusters: The Evidence of Photo-Catalytic Coupling",Chem. Phys. Lett. 2019, 219, 72-77. [PDF]
(3)OuS-H,Chen J-J,LiX-N*,Wang L-N, Ma T-M*, He S-G*, "CO Oxidation by Neutral Gold-Vanadium Oxide Clusters",Chin. J. Chem. Phys. 2019, 32, 207-212. [PDF]
(4) Lv S-Y, Liu Q-Y*, Zhao Y-X, Zhang M-Q, Jiang L-X, He S-G*, "Formaldehyde Generation in Photooxidation of Isoprene on Iron Oxide Nanoclusters", J. Phys. Chem. C 2019, 123, 5120-5127. [PDF] [SI]
(5) Chen Q, Jiang L-X, Li H-F, Chen, J-J, Zhao Y-X*, He S-G*, "Thermal Activation of Methane by Diatomic Vanadium Boride Cations", Acta Phys.-Chim. Sin. 2019, 35, 1014-1020. [PDF]
(6) Wang L-N, Li X-N*, He S-G, "Catalytic CO Oxidation by Noble-Metal-Free Ni2VO4,5?Clusters, A CO Self-Promoted Mechanism", J. Phys. Chem. Lett. 2019, 10, 1133-1138. [PDF] [SI]
(7) Li Z-Y, Mou L-H, Wei G-P, Ren Y, Zhang M-Q, Liu Q-Y, He S-G*, "C-N Coupling in N2 Fixation by the Ditantalum Carbide Cluster Anions Ta2C4?", Inorg. Chem. 2019, 58, 4701-4705. [PDF] [SI]
(8) Zhao Y-X*, Wang M-M, Zhang Y, Ding X-L*, He S-G, "Activity of Atomically Precise Titania Nanoparticles in CO Oxidation", Angew. Chem. Int. Ed. 2019, 58, 8002-8006.(Inside back cover) [PDF]
(9) Wang L-N, Chen J-J, Li X-N*, Liu Y-Z, He S-G, "Doping Effects on the Reactivity of the MVO5?(M = V-Zn) Clusters in CO Oxidaton Reaction", J. Phys. Chem. C 2019, 123, 14180-14186.[PDF]
(10) Ren Y, Yang Y, Zhao Y-X*, He S-G*, "Size-Dependent Reactivity of Rhodium Cluster Anions toward Methane", J. Phys. Chem. C 2019, 123, 17035?17042. [PDF][SI]
(11)Mou L-H,Li Z-Y*,LiuQ-Y, He S-G*, "Size-Dependent Association of Cobalt Deuteride Cluster Anions Co3Dn?(n = 0-4) with Dinitrogen", J.Am. Soc. Mass Spectrom.2019, 30(10), 1956-1963. [PDF][SI]
(12) Lu X-W, Jiang L-X, Liu J, Yang Y, Liu Q-Y*, Ren Y, Li X, He S-G*, "Sensitive Detection of Gas-Phase Glyoxal by Electron Attachment Reaction Ionization Mass Spectrometry",Anal. Chem. 2019, 91, 12688-12695. [PDF]
(13) Lv S-Y, Liu Q-Y*, Chen J-J, He S-G*, "Oxidation of Isoprene by Neutral Iron Oxide Nanoclusters in the Gas Phase" J. Phys. Chem. C 2019, 123,25949-25956. [PDF][SI]
(14) Wang Z-C, Li Y-K, He S-G, Bierbaum M. V. "The HNO- radical anion: A proposed intermediate in diazeniumdiolate synthesis using nitric oxide and alkoxides", Eur. J. Mass. Spectrom. 2019, 25, 82-85. [PDF]
(15) Yang Y, Yang B, Zhao Y-X*, Jiang L-X, Li Z-Y, Ren Y, Xu H-G, Zheng W-J*, He S-G*, "Direct Conversion of Methane with Carbond Dioxide Mediated by RhVO3?Cluster Anions",Angew. Chem. Int. Ed. 2019, 58, 17287-17292. [PDF]
(16) Cheng X, Li Z-Y*, Mou L-H, Ren Y, Liu Q-Y, Ding X-L*, He S-G*, "Side-on-End-on Coordination of Dinitrogen on a Poly-Nuclear Vanadium Cluster Anion V5N5?", Chem. Eur. J 2019, 25, 16523-6527. [PDF][SI]
(17) Zhao Y, Cui J-T, Wang M, Valdivielso D Y, Fielicke A,* Hu L-R,* Cheng X, Liu Q-Y, Li Z-Y, He S-G, Ma J-B*, "Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity", J. Am. Chem. Soc. 2019, 141, 12592-12600. [PDF]
(18) Li X-N, Wang L-N, Mou L-H, He S-G*, "Catalytic CO Oxidation by Gas-Phase Metal Oxide Clusters" J. Phys. Chem. A 2019, 123, 9257-9267. [PDF]
(19) Chen Q, Zhao Y-X*, Chen J-J, Jiang L-X, He S-G*, "Selective Generation of Free Hydrogen Atoms in the Reaction of Methane with Diatomic Gold Boride Cations" Z. Phys. Chem. 2019, 233, 785-797. [PDF]
(20) Li X-N, Jiang L-X, Wang L?N, Ou S-H, Zhang M-Q, Yang Y, Ma T-M, He S-G* "An Eight-Atom Iridium?Aluminum Oxide Cluster IrAlO6+ Catalytically Oxidizes Six CO Molecules" J. Phys. Chem. Lett. 2019, 10, 7850-7855. [PDF]
2018年论文
2018年发表论文
(1)JiangL-X,Liu Q-Y,LiX-N*,He S-G*, "Design and Application of A High-Temperature Linear Ion Trap Reactor",J. Am. Soc.Mass Spectrom.2018, 29, 78-84. [PDF][SI]
(2)ZouX-P,Li Z-Y,LiX-N*,Wang L-N,Li H-F, Ma T-M*, He S-G*, "Consecutive Oxidation of Three H2 Molecules by A Gold-Vanadium Oxide Cluster Cation AuVO4+",Top. Catal. 2018, 61, 28-34. [PDF][SI]
(3)Wang L-N,LiX-N*,Jiang L-X, Yang B, Liu Q-Y, Xu H-G, Zheng W-J*, He S-G*, "Catalytic CO Oxidation by O2 Mediated by Noble-Metal-Free Cluster Anions Cu2VO3-5?",Angew. Chem. Int. Ed.2018, 57, 3349-3353. [PDF][SI]
(4)Li H-F,Jiang L-X, Zhao Y-X*, Liu Q-Y, Zhang T, He S-G*, "Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3?under High-Temperature Conditions",Angew. Chem. Int. Ed.2018, 57, 2662-2666. [PDF][SI]
(5)Zou X-P,Wang L-N,Li X-N*, Liu Q-Y, Zhao Y-X, Ma T-M*, He S-G*, "Noble-Metal Free Single Atom Catalysts CuAl4O7-9?for CO Oxidation by O2",Angew. Chem. Int. Ed.2018, 57,10989-10993. [PDF][SI]
(6)Mou L-H,Liu Q-Y,Zhang T, Li Z-Y*, He S-G*, "Reactivity of Tantlum Carbide Cluster Anions TaCn?(n = 1-4) with Dinitrogen",J. Phys. Chem. A 2018, 122, 3489-3495. [PDF][SI]
(7)Chen J-J,Yang Y,Zhao Y-X*, He S-G*, "VUV Ionization Induced Reaction of Neutral Au2Al2O3 Clusters with Methane",J. Phys. Chem.C 2018, 122, 6159-6165. [PDF][SI]
(8)Li Y-K,Zhao Y-X*, He S-G*, "Selective Conversion of Methane by Rh1-Doped Aluminum Oxide Cluster Anions RhAl2O4?: A Comparision with the Reactivity of PtAl2O4?",J. Phys. Chem.A 2018, 122, 3950-3955. [PDF]
(9)Chen Q,Zhao Y-X*, Jiang L-X, Li H-F, Chen J-J, Zhang T, Liu Q-Y,He S-G*, "Thermal Activation of Methane by Vanadium Boride Cluster Cations VBn+ (n = 3-6)",Phys. Chem. Chem. Phys.2018, 20, 4641-4645. [PDF][SI]
(10)Zhao Y-X,He S-G*, "A Breakthrough inDirect Conversion of Methane to Oxygenates under Mild Conditions",Science China Materials2018, 61, 1012-1014. [PDF]
(11) Lu X-W, Ren Y, Liu Q-Y*, Zhang T, Jiang L-X, Wei G-P, He S-G*, "Electron Attachment Reaction Ionization of Gas-Phase Methylglyoxal", Anal. Chem. 2018, 90, 13467-13474. [PDF]
(12) Chen Q, Zhao Y-X*, Jiang L-X, Chen J-J, He S-G*, "Coupling of Methane and Carbon Dioxide Mediated by Diatomic Copper Boride Cations", Angew. Chem. Int. Ed. 2018, 57, 14134-14138. [PDF][SI]
(13) Liu Y-Z, Jiang L-X, Li X-N*, Wang L-N, Chen J-J, He S-G*, "Gas-Phase Reactions of Carbon Dioxide with Copper Hydride Anions Cu2H2?: Temperature-Dependent Transformation", J. Phys. Chem. C 2018, 122, 19379-19384. [PDF][SI]
(14) Chen Y-M, Wang L-N, Chen J-J, Chen Q, Jiang L-X, Zhao Y-X*, Ding X-L*, He S-G*, "Mechanistic Variants in Methane Activation Mediated by Gold(I) Supported on Silicon Oxide Clusters", Chem. Eur. J. 2018, 24, 17506-17512. [PDF][SI]
(15) Zhao Y-X, Li Z-Y, Yang Y, He S-G*, "Methane Activation by Gas Phase Atomic Clusters", Acc. Chem. Res. 2018, 51, 2603-2610. [PDF]
(16) Jiang L-X, Li X-N*, Li Z-Y, Li H-F, He S-G*, "H2 Dissociation by Au1-Doped Closed-Shell Titanium Oxide Cluster Anions", Chin. J. Chem. Phys. 2018, 31, 457-462. [PDF][SI]
2017年论文
2017年发表论文
(1)Jiang L-X,Zhao C, Li X-N*, Chen H*, He S-G*. "Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions", Angew. Chem. Int. Ed, 2017, 56, 4187-4191 (Cover, VIP). [PDF][SI]
(2)Zhang M-Q, Zhao Y-X*, Liu Q-Y, Li X-N, He S-G*. "Does Each Atom Count in the Reactivity of VanadiaNanoclusters?",J.Am.Chem. Soc. 2017, 139, 342-347.
(3)Li H-F, Zhao Y. X*, Yuan Z, Liu Q-U, Li Z-Y, Li X-N, Ning C-G, He S-G*. "Mathane Activtion by Tantalum Carbide Cluster Anions Ta2C4?",J. Phys. Chem. Lett. 2017, 8, 605-610. [PDF][SI]
(4) Li X-N, Zou X-P, He S-G*, "Metal-Mediated Catalysis in the Gas Phase, A Review", Chinese J. Catal. 2017, 38, 1515. [PDF]
(5) Zhou X-H, Li Z-Y*, Jiang L-X, He S-G*, Ma T-M*, "Methane Activation Mediated by Dual Gold Atoms Doped in Aluminium Oxide Cluster Cations Au2Al2O3+", Chemistry Select. 2017, 2, 991-996. [PDF][SI]
(6)Chen J-J, Zhang T, Zhang M-Q, Liu Q-Y, Li X-N*, He S-G*, "Size-Dependent Reactivity of Nano-Sized Neutral Manganese Oxide Clusters toward Ethylene", Chem. Eur. J. 2017, 23, 15820-15826. [PDF][SI]
(7)Chen J-J, Yuan Z, Li X-N, He S-G*, "A VUV Photoionization Time-of-Flight Mass Spectrometer for the Formation, Distribution, and Reaction of Nano-Sized Neutral Metal Oxide Clusters",Int. J. Mass Spectrom.2017, 422, 98-104. [PDF]
(8)ZhangY, LiZ-Y*, Zhao Y-X, Li H-F, Ding X-L*, Zhang H-Y, He S-G*, "H2 Oxidation Mediated by Au1-Doped Vanadium Oxide Cluster Cation AuV2O5+: A Compartive Study with AuCe2O4+",J. Phys. Chem.A2017, 121, 4069-4075. [PDF][SI]
(9)ZhangT, LiZ-Y, Liu Q-Y, He S-G*, "Chemical Ionization of Large Linear Alkanes and Small Oxidized Volatile Organic Compounds by the Reactions with Atomic Gold Cations",Anal. Chem.2017, 89, 9083-9090. [PDF][SI]
(10)Zhang L,Zhang X-B*,Zhang D-D, He S-G*, "Theoretical Prediction of the Synthesis of 2,3-Dihydropyridines through Ir(III) Catalysed Reaction of Unsaturated Oximes with Alkenes",RSC Adv.2017, 7, 5679-5659. [PDF][SI]
(11)Hu J-C,Xu L-L,Li H-F, Valdivielso D-Y, Fielicke A, He S-G, MaJ-B*,"Liberation of Three Dihydrogens from Two Ethene Molecules as Mediated by the Tantalum Nitride Anion Cluster Ta3N2?at Room Temperature",Phys. Chem. Chem. Phys.2017, 19, 3136-3142. [PDF][SI]
(12)Yan Y,Shi W-D,Yuan Z, He S-G, Li D-M, Meng, Q-B, Ji H-W, Chen C-C, Ma W-H*, Zhao J-C*,"The Formation of Ti-H Species at Interface Is Lethal to the Efficiency of TiO2-Based Dye-Sensitized Devices",J. Am. Chem. Soc.2017,139, 2083-2089.[PDF][SI]
(13)Yan X-J*,Ma K-L,Zou W-X, He S-G, An J-B, Yang F-M, Dong L*,"Influence of Preparation Methods on the Physicochemical Properties and Catalytic Performation of MnOx-CeO2 Catalysts for NH3-SCR at Low Temperature",Chinese J. Catal.2017,38, 146-159. [PDF]
(14)Li Y-K,Wang Z-C, He S-G, Bierbaum V-M*,"Reactions of Sulfur- and Oxygen-Containing Anions with Hydrogen Atoms: A Comparative Study",J. Phys. Chem. Lett.2017,8, 5725-5729. [PDF][SI]
2016年论文
2016年发表论文
(1) Li X-N, Zhang H-M, Yuan Z, He S-G*, "A Nine-Atom Rhodium-Aluminum Oxide Cluster Oxidizes Five CarbonMonoxide Molecules", Nat. Commun, 2016, 7, 11404. [PDF]
(2)Zhao Y-X, Li X-N, Yuan Z, Liu Q-Y, Shi Q*, He S-G*, "Methane Activation by Gold-Doped Titanium Oxide Cluster Anions with Closed-Shell Electronic Structures", Chem. Sci.2016, 7, 4730-4735. [PDF][SI]
(3) Li X-N, Li Z-Y, Li H-F, He S-G*, "Muliple CO Oxidation Promoted by Au2-dimer in Au2TiO4?Cluster Anions", Chem. Eur. J. 2016, 22, 9024-9029. [PDF]
(4)Ma J-B*, Xu L-L, Liu Q-Y, He S-G*, "Activation of Methane and Ethane as Mediated by the Tiatomic Anion HNbN?: Electronic Structure Similarity with a Pt Atom ",Angew. Chem. Int. Ed.2016, 55, 4947. [PDF]
(5)Liu Q-Y, Ma J-B*,Li Z-Y, Zhao C,Ning C-G, Chen H*,He S-G*, "Activation of Methane Promoted by Adsorption of CO on Mo2C2?Cluster Anions",Angew. Chem. Int. Ed.2016, 55, 5760. [PDF][SI]
(6) Li Z-Y, Li H-F, Zhao Y-X*, He S-G*, "Gold (III) Mediated Activation and Transformation of Methane on Au1-doped Vanadium Oxide Cluster Cations AuV2O6+", J. Am. Chem. Soc.2016, 138, 9437-9443. [PDF][SI]
(7) Liu Q-Y, Yuan Z, Zhao Y-X, He S-G*, "Photo-Induced Reaction of Ethene Bound to Vanadia Nanoparticles [(V2O5)nC2H4(n=2-20)]?in the Gas Phase", J. Phys. Chem. C2016, 120, 17081-17086. [PDF]
(8) Zhou X-H, Li Z-Y*, Ma T-M*, He S-G, "Consecutive H2Oxidation Mediated by Au2VO4+Clusters", J. Phys. Chem. C2016, 120, 10452-10459. [PDF][SI]
(9) Jiang L-X, Li X-N*, Li H-F, Zhou Z-X, He S-G*, "Generation of Hydroxyl Radicals in the Reaction of Dihydrogen with AuNbO4+Cluster Cations",Chem. Asian J.2016, 11, 2730-2734. [PDF][SI]
(10) Zhang T, Li Z-Y, Zhang M-Q, He S-G*, "Gas-Phase Reactions of Atomic Gold Cations with Linear Alkanes (C2-C9)", J. Phys. Chem. A2016, 120, 4285-4293. [PDF][SI]
(11) Zhao Y-X, Liu Q-Y, Zhang M-Q, He S-G*, "Reactions of Metal Cluster Anions with Inorganic and Organic Molecules in the Gas Phase",Dalton Trans. 2016, 45, 11471-11495. [PDF]
(12)Ma J-B, Meng J-H, He S-G*, "Methane Activation Mediated by a Series of Cerium-Vanadium Bimetallic Oxide Cluster Cations: Tuning Reactivity by Doping", ChemPhysChem2016, 17, 1112-1118. [PDF]
(13) 赵艳霞，何圣贵*, "异核氧化物团簇与小分子的反应研究", Progress in Chemistry 2016, 28, 401-414. [PDF]
(14) Ma J-B*, Xu L-L, Meng J-H, He S-G*, "Dehydrogenation of Propylene Mediated by CeVO4+: An Interesting Example for the Chemistry of Binary Ce-V Transition-Metal Oxide Cluster Cations",Int. J. Mass Spectrom.2016, 401, 39-45. [PDF][SI]
(15) Li Y-K, Li Z-Y, Zhao Y-X*, Liu Q-Y, Meng J-H, He S-G*, "Activation and Transformation of Ethane by Au2VO3+ Clusters with Closed-Shell Electronic Structures", Chem. Eur. J. 2016, 22, 1825-1830. [PDF]
(16) Zhou, Z-X, Wang L-N, Li Z-Y*, He S-G, Ma T-M*, "Oxidation of SO2to SO3by Cerium Oxide Cluster Cations Ce2O4+and Ce3O6+". J. Phys. Chem. A 2016, 120, 3843-3848. [PDF][SI]
(17) Yuan Z, Liu Q-Y, Li X-N*, He S-G*, "Formation, Distribution, and Photoreaction of Nano-sized Vanadium Oxide Cluster Anions", Int. J. Mass Spectrom. 2016, 407, 62-68. [PDF]
(18) Li Y-K, Yuan Z, Zhao Y-X*, Zhao C, Liu Q-Y, Chen H*, He S-G*, "Thermal Methane Conversion to Syngas Mediated by Rh1?Doped Aluminum Oxide Cluster Cations RhAl3O4+", J. Am. Chem. Soc.2016, 138, 12854-12860. [PDF][SI]
(19)Hu J-C, Xu L-L, Hou X-Y, Li H-F, Ma J-B*, He S-G, "Origin of the Different Reactivity of the Triatomic Anions HMoN?and ZrNH?toward Alkane: Compositions of the Active Orbitals", J. Phys. Chem. A 2016, 120, 7786-7791. [PDF][SI]
(20) 张梅琦，赵艳霞，何圣贵*, "贵金属及其掺杂团簇与甲烷反应研究进展",化学通报，2016, 7, 395-402. [PDF]
2015年发表论文
2015年发表论文
(1)Wang L-N, Zhou Z-X, Li X-N, Ma T-M, He S-G, "Thermal Conversion of Methane to Formaldehyde Promoted byGold in AuNbO3+ Cluster Cations", Chem. Eur. J. 2015,21, 6957-6961. [PDF][SI]
(2)Liu Q-Y, Hu L-R, Li Z-Y, Ning C-G, Ma J-B, Chen H, He S-G, "Photoelectron imaging spectroscopy of MoC?and NbN?diatomic anions:A comparative study", J. Chem. Phys.2015, 142, 164301. [PDF]
(3) Li H-F, Li Z-Y, Liu Q-Y, Li X-N, Zhao Y-X, He S-G, "Methane Activation by Iron-Carbide Cluster Anions FeC6?",J. Phys. Chem. Lett.2015,6, 2287-2291.[PDF][SI]
(4) Li Y-K, Meng J-H, He S-G, "Generation of free hydrogen atoms in thermal reaction of ethane with AuNbO3+ cluster cations",Int. J. Mass, Spectrom. 2015, 381-382, 10-16. [PDF]
(5) Liu Q-Y, Hu L-R, Chen H, He S-G, "Photoelectron imaging spectroscopy of ZrO?diatomic anion", Chin. J. Chem. Phys. 2015, 28, 452-458.[PDF]
(6) Li Z-Y, Hu L-R, Liu Q-Y, Ning C-G, Chen H, He S-G, Yao J-N, "C-H Bong Activation by Early Transition Metal Carbide Cluster Anion MoC3?", Chem. Eur. J. 2015, 21, 17748-17756.[PDF]
(7) Meng Z, Han Y, Wang L-N, Xing J-F, He S-G, Chen C-F, "Stepwise Motion in a Multivalent [2](3)Catenane", J. Am. Chem. Soc. 2015, 137, 9739-9745.[PDF]
(8) 何圣贵，"欧美科学家使用飞秒X 射线激光检测一氧化碳氧化过程的过渡态"，科学通报，2015, 60, 2149-2150.[PDF]
(9) Wang L-N, Li Z-Y, Liu Q-Y, Meng J-H, He S-G, Ma T.M, "CO oxidation promoted by gold dimer in Au2VO3?and Au2VO4?clusters",Angew. Chem. Int. Ed. 2015, 54, 11720-11724.[PDF][SI]
(10)Li X-N, Yuan Z, Meng J-H, Li Z-Y, He S-G, "Catalytic CO Oxidation on Single Pt-Atom Doped Aluminum Oxide Clusters: Electronegativity-Ladder E?ect ", J. Phys. Chem. C2015, 119, 15414-15420.[PDF][SI]
2014年论文
2014年发表文章
(1) Meng J-H, He S-G*, "Thermal Dihydrogen Activation by a Closed-Shell AuCeO2+Cluster" J. Phys. Chem. Lett. 2014, 5, 3890-3894.[PDF][SI]
(2) Li Z-Y, Yuan Z, Li X-N*, Zhao Y-X, He S-G*, "CO Oxidation Catalyzed by Single-Au Atoms Supported on Aluminum Oxide Clusters" J. Am. Chem. Soc. 2014,136, 14307-14313. [PDF][SI]
(3) Li X-N, Yuan Z, He S-G*, "CO Oxidation Promoted by Gold Atoms Supported on Titanium Oxide Cluster Anions"J. Am. Chem. Soc. 2014, 136, 3617-3623.[PDF][SI]
(4) Zhao Y-X, Li Z-Y, Yuan Z, Li X-N, He S-G*, " Thermal Methane Conversion to Formaldehyde Promoted by single Platinum Atoms in PtAl2O4?cluster Anions"Angew. Chem. Int. Ed.2014,53, 9482-9486. [PDF]
(5) Yuan Z, Li X-N*, He S-G*, "CO Oxidation Promoted by Gold Atoms Loosely Attached in AuFeO3? Cluster Anions" J. Phys. Chem. Lett. 2014, 5, 1585-1590. [PDF][SI]
(6) Tian L-H, Meng J-H, Wu X-N, Zhao Y-X*, Ding X-L, He S-G*, Ma T-M*, "Reactivity of Oxygen Radical Anions Bound to Scandia Nanoparticles in the Gas Phase: C-H Bond Activation" Chem. Eur. J. 2014, 20, 1167-1175. [PDF][SI]
(7) Meng J-H, Deng X-J, Li Z-Y, He S-G*, Zheng W-J*, "Thermal Methane Activation by La6O10?cluster anions" Chem. Eur. J. 2014, 20, 5580-5583. [PDF]
(8) Li Z-Y, Yuan Z, Zhao Y-X*, He S-G*, "Methane Activation by Diatomic Molybdenum Carbide Cations" Chem. Eur. J. 2014, 20, 4163-4169. [PDF][SI]
(9) Jia M-Y, Luo Z-X*, He S-G*, Ge M-F, "Oxygen-Sulfur Exchange and the Gas-Phase Reactivity of Cobalt Sulfide Cluster Anions with Molecular Oxygen"J. Phys. Chem. A 2014, 118, 8163-8169. [PDF]
(10) Jia M-Y, Bo X, Deng K, He S-G*, Ge M-F*, "Consecutive Oxygen-for-Sulfur Exchange Reactions between Vanadium Oxide Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. A 2014,118, 8106-8114. [PDF][SI]
(11) Yuan Z, Li Z-Y, Zhou Z-X, Liu Q-Y, Zhao Y-X, He S-G*, "Thermal Reactions of (V2O5)nO– (n = 1–3) Cluster Anions with Ethylene and Propylene: Oxygen Atom Transfer Versus Molecular Association" J. Phys. Chem. C 2014,118, 14967-14976. [PDF]
(12) Liu Q-Y, He S-G*, "Oxidation of Carbon Monoxide on Atomic Clusters." Chem. J. Chinese U. 2014, 35, 665-688.
(13) Xu B, Meng J-H, He S-G*, "Photoreaction Study of Methanol Adsorption Complexes on VO2(V2O5)n+ (n = 1–3) Clusters at 355 nm" J. Phys. Chem. C 2014, 118, 18488-18495. [PDF][SI]
2013年论文
2013年发表文章
(1) Xu B,Zhao Y-X,Ding X-L,Liu Q-Y, He S-G*,"Collision-Induced Dissociation and Infrared Photodissociation Studies of Methane Adsorption on V5O12+ and V5O13+ Clusters" J. Phys. Chem. A 2013, 117, 2961-2970.[PDF][SI]
(2) Ma J-B, Xu B, Meng J-H, Wu X-N, Ding X-L, Li X-N, He S-G*, "Reactivity of Atomic Oxygen Radical Anions Bound to Titania and Zirconia Nano-Particles in the Gas Phase: Low-Temperature Oxidation of Carbon Monoxide" J. Am. Chem. Soc. 2013, 135, 2991-2998. （cover article) [PDF]
(3) Wu X-N, Li X-N, Ding X-L, He S-G*,"Activation of Multiple C-H Bonds Promoted by Gold in AuNbO3+ Clusters" Angew. Chem. Int. Ed. 2013, 52, 2444-2448. [PDF][SI]
(4) Ma J-B, Wang Z-C, Schlangen M, He S-G*, Schwarz H*, "On the Origin of the Surprisingly Sluggish Redox Reaction of the N2O/CO Couple Mediated by [Y2O2]+o and [YAlO2]+ Cluster Ions in the Gas Phase" Angew. Chem. Int. Ed. 2013, 52, 1226-1230. [PDF]
(5) Xu B, Zhao Y-X*, Ding X-L, He S-G*, "Reactions of Sc2O4?and La2O4?Clusters with CO: A comparative study"Int. J. Mass Spectrom. 2013, 334, 1-7. [PDF]
(6) Tian L-H, Ma T-M*, Li X-N*, He S-G*, "C-H bond Activation by Aluminum Oxide Cluster Anions, An Experimental and Theoretical Study" Dalton Trans. 2013, 42, 11205-11211. [PDF][SI]
(7) Yuan Z, Zhao Y-X*, Li X-N, He S-G*, "Reactions of V4O10+ Cluster Ions with Simple Inorganic and Organic Molecules" Int. J. Mass Spectra. 2013, 354-355, 105-112. [PDF][SI]
(8) Jia M-Y, Ding X-L, He S-G*, Ge M-F*, "Experimental and Theoretical Study of the Reactions between MO2?(M = Fe, Co, Ni, Cu, and Zn) Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. A 2013, 117, 8377-8387.
(9) Meng J-H, Zhao Y-X*, He S-G*, "Reactivity of Stoichiometric Lanthanum Oxide Cluster Cations in C-H Bond Activation" J. Phys. Chem. C 2013, 117, 17548-17556. [PDF][SI]
(10) Jia M-Y, He S-G*, Ge M-F*, "Experimental and Theoretical Study of Reactions between Manganese Oxide Cluster Cations and Hydrogen Sulfide" Chin. J. Chem. Phys. 2013, 26, 679-686. [PDF]
(11) Zhao Y-X*, Xu B, Ding X-L, He S-G*, "Fabrication and Optical Properties of Pyrene-Eu Hybrid Materials" J. Nanosci. Nanotechnol. 2013, 13, 819-823.
(12) Xu H-G, Li X-N*, Kong X-Y, He S-G, Zheng W-J*, "Interaction of TiO+ with Water: Infrared Photodissociation Spectroscopy and Density Functional Calculations"Phys. Chem. Chem. Phys. 2013, 15, 17126-17133. [PDF]
2012年发表文章
2012年发表文章
(1) Ma J-B, Wang Z-C, Schlangen M*, He S-G*, Schwarz H*, "Thermal Reactions of YAlO3+ with Methane: Increasing the Reactivity of Y2O3+ and the Selectivity of Al2O3+ by Doping"Angew. Chem. Int. Ed. 2012, 51, 5991-5994. [PDF]
(2) Ding X-L, Li Z-Y, Meng J-H, Zhao Y-X, He S-G*, "Density-functional global optimization of (La2O3)n clusters" J. Chem. Phys. 2012,137,214311. [PDF]
(3) Huang J-H, Zhao Y, Ding X-L, Jia H, Jing B, Zhang Z-G, Zhan C-L*, He S-G, Pei Q-B*, Li Y-F, Liu Y-Q, Yao J-N*, "Synthesis and charge-transporting properties of electron-deficient CN2-fluorene based D-A copolymers " Polym. Chem. 2012, 3, 2170-2177. [PDF][SI]
(4) Jia M-Y, Xu B, Ding X-L, He S-G*, Ge M-F*, "Experimental and Theoretical Study of the Reactions between Manganese Oxide Cluster Anions and Hydrogen Sulfide" J. Phys. Chem. C 2012, 116,24184-24192. [PDF][SI]
(5) Jia M-Y, Xu B, Ding X-L, Zhao Y-X, He S-G*, Ge M-F*, "Experimental and Theoretical Study of the Reactions between Vanadium Oxide Cluster Cations and Hydrogen Sulfide" J. Phys. Chem. C 2012, 116, 9043-9048. [PDF]
(6) Li X-N, Xu B, Ding X-L, He S-G*, "Interaction of vanadium oxide cluster anions with water: an experimental and theoretical study on reactivity and mechanism" Dalton Trans. 2012, 41, 5562-5570. [PDF]
(7) Li X-N, Wu X-N, Ding X-L, He S-G*, "Reactivity control of C-H bond activation over vanadium-silver bimetallic oxide cluster cations" Chem. Eur. J. 2012,18, 10998-11006. [PDF][SI]
(8) Tian L-H, Zhao Y-X, Wu X-N, Ding X-L, He S-G*, Ma T-M*, "Structures and Reactivity of Oxygen-Rich Scandium Cluster Anions ScO3-5?" ChemPhysChem 2012,13, 1282-1288. [PDF][SI]
(9) Ding X-L, Wu X-N, Zhao Y-X, He S-G*, "C-H Bond Activation by Oxygen-Centered Radicals over Atomic Clusters" Acc. Chem. Res. 2012, 45,382-390. [PDF][SI]
(10) Ma J-B, Zhao Y-X, He S-G*, Ding X-L*, "Experimental and Theoretical Study of the Reactions between Vanadium Oxide Cluster Cations and Water" J. Phys. Chem. A 2012, 116, 2049-2054. [PDF]
(11) Wu X-N, Xu B, Meng J-H, He S-G*, "C-H Bond Activation by Nanosized Scandium Oxide Clusters in Gas-Phase" Int. J. Mass Spectrom. 2012,310, 57-64. [PDF][SI]
2011年发表文章
2011年发表文章
(1) Zhao Y-X, Wu X-N, Ma J-B, He S-G*, Ding X-L*, "Characterization and reactivity of oxygen-centred radicals over transition metal oxide clusters" Phys. Chem. Chem. Phys. 2011, 13,1925-1938. [PDF]
(2) Ding X-L, Wu X-N, Zhao Y-X, Ma J-B, He S-G*, "Double-oxygen-atom transfer reaction in the reaction of CemO2m+ (m = 2-6) with C2H2" ChemPhysChem 2011, 12, 2110-2117. [PDF][SI]
(3) Li Z-Y, Zhao Y-X, Wu X-N, Ding X-L*, He S-G*, "Methane Activation by Yttrium-Doped Vanadium Oxide Cluster Cations: Local Charge Effects" Chem. Eur. J. 2011,17, 11728-11733. [PDF]
(4) Zhao Y-X, Yuan J-Y, Ding X-L, He S-G*, Zheng W-J*, "Electronic Structure and Reactivity of a Biradical Cluster: Sc3O6?" Phys. Chem. Chem. Phys. 2011, 13, 10084-10090. [PDF]
(5) Wu X-N, Ding X-L, Bai S-M, Xu B, He S-G*, Shi Q*, "Experimental and Theoretical Study of the Reactions between Cerium Oxide Cluster Anions and Carbon Monoxide: Size-Dependent Reactivity of CenO2n+1?(n = 1-21)" J. Phys. Chem. C. 2011,115,13329-13337. [PDF][SI]
(6) Wang Z-C, Wu X-N, Zhao Y-X, Ma J-B, Ding X-L*, He S-G, "C-H Activation on Aluminum-Vanadium Bimetallic Oxide Cluster Anions" Chem. Eur. J. 2011,17,3449-3457. [PDF]
(7) Xu B, Zhao Y-X, Li X-N, Ding X-L, He S-G*, "Experimental and Theoretical Study of Hydrogen Atom Abstraction from n-Butane by Lanthanum Oxide Cluster Anions" J. Phys. Chem. A. 2011, 115, 10245-10250. [PDF][SI]
(8) Ma Y-P, Zhao Y-X, Li Z-Y, Ding X-L*, He S-G*, "Classification of VxOyq Clusters by ? = 2y+q-5x" Chinese J. Chem. Phys. 2011,24,596-596.
(9) Wu X-N, Xu B, Ma J-B, He S-G*, "Collision-Induced Characterization of adsorption of small molecules over atomic clusters through collisions with helium beam" SCIENTIA SINICA Chimica 2011, 41, 1379-1386 (In Chinese). [PDF]
(10) Xue L, Li G-P, Liu Q, Wang H-H, Liu C, Ding X-L, He S-G*, Jiang H*, "Ratiometric Fluorescent Sensor Based on Inhibition of Resonance for Detection of Cadmium in Aqueous Solution and Living Cells" Inorg. Chem. 2011,50, 3680-3690. [PDF]
(11) Wu X-N, Ma J-B, Xu B, Zhao Y-X, Ding X-L, He S-G*, "Collision-Induced Dissociation and Density Functional Theory Studies of CO Adsorption over Zirconium Oxide Cluster Ions: Oxidative and Nonoxidative Adsorption" J. Phys. Chem. A 2011, 115, 5238-5246.
(12) Ke D-M, Zhan C-L*, Xu S-P, Ding X-L, Peng A-D, Sun J, He S-G, Li A. D. Q*, Yao J-N*, "Self-Assembled Hollow Nanospheres Strongly Enhance Photoluminescence" J. Am. Chem. Soc. 2011, 133, 11022-11025. [PDF][SI]
单篇全文显示
2010年发表论文
(1) Ding X-L, Zhao Y-X, Wu X-N, Wang Z-C, Ma J-B, He S-G*, "Hydrogen-Atom Abstraction from Methane by Stoichiometric Vanadium-Silicon Heteronuclear Oxide Cluster Cations" Chem. Eur. J. 2010, 16, 11463-11470. [PDF]
(2) Wu X-N, Zhao Y-X, Xue W, Wang Z-C, He S-G*, Ding X-L*, "Active sites of stoichiometric cerium oxide cations (CemO2m+) probed by reactions with carbon monoxide and small hydrocarbon molecules" Phys. Chem. Chem. Phys. 2010, 12,3984-3997. [PDF][SI]
(3) Zhao Y-X, Wu X-N, Wang Z-C, He S-G*, Ding X-L*, "Hydrogen-atom abstraction from methane by stoichiometric early transition metal oxide cluster cations" Chem. Commun. 2010, 46, 1736-1738. [PDF][SI]
(4) Ma J-B, Wu X-N, Zhao Y-X, Ding X-L, He S-G*, "Characterization of Mononuclear Oxygen-Centered Radical (O-o) in Zr2O8?Cluster" J. Phys. Chem. A 2010, 114, 10024-10027. [PDF]
(5) Ma J-B, Wu X-N, Zhao X-X, Ding X-L, He S-G*, "Methane activation by V3PO10o+ and V4O10o+ clusters: A comparative study" Phys. Chem. Chem. Phys. 2010, 12, 12223-12228. [PDF]
(6) Zhao Y-X, Ding X-L, Ma Y-P, Wang Z-C, He S-G*, "Transition metal oxide clusters with character of oxygen-centered radical: a DFT study" Theor. Chem. Acc. 2010, 127, 449-465. [PDF][SI]
(7) Wang Z-C, Wu X-N, Zhao Y-X, Ma J-B, Ding X-L, He S-G*, "Room-temperature methane activation by a bimetallic oxide cluster AlVO4+" Chem. Phys. Lett. 2010, 489, 25-29. [PDF]
(8) Ma Y-P, Ding X-L, Zhao Y-X, He S-G*, "A Theoretical Study on the Mechanism of C2H4 Oxidation over a Neutral V3O8 Cluster" ChemPhysChem 2010, 11, 1718-1725. [PDF]
(9) Ding X-L, Xue W, Ma Y-P, Zhao Y-X, Wu X-N, He S-G*, "Theoretical Investigation of the Selective Oxidation of Methanol to Formaldehyde on Vanadium Oxide Species Supported on Silica: Umbrella Model" J. Phys. Chem. C 2010, 114, 3161-3169. [PDF]
(10) Zhao Y-X, Wu X-N, Ma J-B, He S-G*, Ding X-L*, "Experimental and Theoretical Study of the Reactions between Vanadium-Silicon Heteronuclear Oxide Cluster Anions with n-Butane" J. Phys. Chem. C 2010, 114, 12271-12279. [PDF]
(11) Ma J-B, Wu X-N, Zhao Y-X, He S-G*, Ding X-L*, "Experimental and Theoretical Studies of the Reactions between Vanadium Oxide Cluster Anions and Small Hydrocarbon Molecules" Acta Physico-Chimica Sinica 2010, 26, 1761-1767 (Invited). [PDF]
(12) Ma J-B, Wu X-N, Zhao Y-X, Ding X-L, He S-G*, "Experimental and Theoretical Study of Hydrogen Atom Abstraction from C2H6 and C4H10 by Zirconium Oxide Clusters Anions" Chinese J. Chem. Phys. 2010, 23, 133-137. [PDF]
(13) Wang Z-C, Ma Y-P, Zhao Y-X, Ding X-L, He S-G, "Nearly Monodispersed Perylene Nanotablets: Easy Fabrication and Unique Optical Properties" Inec: 2010 3rd International Nanoelectronics Conference 2010, 1-2, 425-426. [PDF]
单篇全文显示
2009年发表论文
(1) Zhang Y-Q, Chen P-L*, Ma Y-P, He S-G, Liu M-H*, "Acidification and Assembly of Porphyrin at an Interface: Counterion Matching Selectivity and Supramolecular Chirality" Acs Applied Materials & Interfaces 2009, 1, 2036-2043. [PDF]
(2) Yin S, Xue W, Ding X-L, Wang W-G, He S-G*, Ge M-F*, "Formation distribution and structures of oxygen-rich iron and cobalt oxide clusters" Int. J. Mass Spectrom. 2009, 281, 72-78. [PDF]
(3) Yin S, He S-G*, Ge M-F*, "Reaction between sulfur dioxide and iron oxide cationic clusters" Chinese Sci. Bull. 2009, 54, 4017-4020. [PDF]
(4) Xue W, Yin S, Ding X-L, He S-G*, Ge M-F*, "Ground State Structures of Fe2O4-6+ Clusters Probed by Reactions with N2" J. Phys. Chem. A 2009, 113, 5302-5309. [PDF][SI]
(5) Wu X-N, Zhao Y-X, He S-G*, Ding X-L*, "Experimental and Theoretical Study of Hydrogen Atom Abstraction from Ethylene by Stoichiometric Zirconium Oxide Clusters" Chinese J. Chem. Phys. 2009, 22, 635-641. [PDF]
(6) Wang Z-C, Ding X-L, Ma Y-P, Cao H, Wu X-N, Zhao Y-X, He S-G*, "Theoretical study of partial oxidation of ethylene by vanadium trioxide cluster cation" Chinese Sci. Bull. 2009, 54, 2814-2821. [PDF]
(7) Ma Y-P, He S-G*, Ding X-L, Wang Z-C, Xue W, Shi Q*, "Theoretical study of intermolecular interactions in meso-tetraphenylporphyrin diacid dimer (H4TPPCl2)2" Phys. Chem. Chem. Phys. 2009, 11, 2543-2552. [PDF][SI]
(8) Hu H-Y, Xue W, Hu Z-Q, Xiang J-F, Chen C-F*, He S-G*, "Probing the Dynamic Environment-Associated Conformational Conversion from Secondary to Supersecondary Structures in Oligo(phenanthroline dicarboxamide)s" J. Org. Chem. 2009, 74, 4949-4957.
(9) He S-G, Sunahori F-X, Yang J, Clouthier D-J*, "Heavy atom nitroxyl radicals. II: Spectroscopic detection of H2As=O the prototypical arsenyl free radical" J. Chem. Phys. 2009, 131, 114311. [PDF]
(10) Dong F, Heinbuch S, Xie Y, Bernstein E-R*, Rocca J-J, Wang Z-C, Ding X-L, He S-G*, "C=C Bond Cleavage on Neutral VO3(V2O5)n Clusters" J. Am. Chem. Soc. 2009, 131, 1057-1066. [PDF]
(11) Ding X-L, Xue W, Ma Y-P, Wang Z-C, He S-G*, "Density functional study on cage and noncage (Fe2O3)n clusters" J. Chem. Phys. 2009, 130,014303. [PDF]
2008年发表论文
2008年发表成果
(1) Xue W, Wang Z-C, He S-G*, Xie Y, Bernstein E. R*, "Experimental and Theoretical Study of the Reactions between Small Neutral Iron Oxide Clusters and Carbon Monoxide" J. Am. Chem. Soc. 2008, 130, 15879-15888. [PDF][SI]
(2) Dong F, Heinbuch S, Xie Y, Rocca J. J, Bernstein E. R*, Wang Z-C, Deng K, He S-G*, "Experimental and theoretical study of the reactions between neutral vanadium oxide clusters and ethane ethylene and acetylene" J. Am. Chem. Soc. 2008, 130, 1932-1943. [PDF][SI]
(3) Yin S, Ma Y-P, Du L, He S-G*, Ge M-F*, "Experimental and theoretical studies of the reaction between cationic vanadium oxide clusters and acetylene" Chinese Sci. Bull. 2008, 53, 3829-3838. [PDF]
(4) Xie Y, He S-G, Dong F, Bernstein E. R*, "Reaction of carbon monoxide and hydrogen on neutral Nb8 clusters in the gas phase" J. Chem. Phys. 2008, 128, 044306. [PDF]
(5) Wang Z-C, Xue W, Ma Y-P, Ding X-L, He S-G*, Dong F, Heinbuch S, Rocca J. J, Bernstein E. R, "Partial oxidation of propylene catalyzed by VO3 clusters: A density functional theory study" J. Phys. Chem. A 2008, 112, 5984-5993. [PDF][SI]
(6) Wang Z-C, Xiao W-C, Ding X-L, Ma Y-P, Xue W, He S-G*, "Multicolor emission from large-area porous thin films constructed of nanowires of small organic molecules" Nanotechnology 2008,19. [PDF]
(7) Ma Y-P, Xue W, Wang Z-C, Ge M-F, He S-G*, "Acetylene cyclotrimerization catalyzed by TiO2 and VO2 in the gas phase: A DFT study" J. Phys. Chem. A 2008, 112,3731-3741. [PDF][SI]
(8) He S-G, Xie Y, Dong F, Heinbuch S, Jakubikova E, Rocca J. J, Bernstein E. R*, "Reactions of Sulfur Dioxide with Neutral Vanadium Oxide Clusters in the Gas Phase. II. Experimental Study Employing Single-Photon Ionization" J. Phys. Chem. A 2008, 112, 11067-11077. [PDF]
(9) He S-G*, Clouthier D. J, "RT3: A Windows program for the Renner-Teller analysis of 2Π states of triatomic molecules" Comp. Phys. Commun. 2008, 178, 676-684. [PDF]
(10) Ge M-F*, Du L, Ma Y-P, He S-G, "Ab initio and DFT study of the structural properties and thermochemistry of CH3SO2OONO2 atmospheric molecule and CH3SO2OO radical" Chinese J. Chem. 2008, 26, 998-1004. [PDF]
仪器设备
1. 团簇离子源-四极质量过滤器-离子阱-高分辨率质谱耦合装置（团簇活性研究系统） 2. 团簇结构研究系统
3.纳米尺寸团簇结构系统
4.真空紫外光电离质谱（中性团簇研究系统）
5. 计算服务器
成果简介
1、CO2活化
Jiang L-X,Zhao C,Li X-N*, Chen H*,He S-G*. "Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions", Angew. Chem. Int. Ed, 2017, 56, 4187-4191.
2、纳米尺寸团簇活性
Zhang M-Q, Zhao Y-X*, Liu Q-Y, Li X-N, He S-G*. "Does Each Atom Count in the Reactivity of VanadiaNanoclusters?",J.Am.Chem. Soc. 2017, 139, 342-347.
3、CH4活化
Li Z-Y, Li H-F, Zhao Y-X*, He S-G*. "Gold (III) Mediated Activation and Transformation of Methane on Au1-doped Vanadium Oxide Cluster Cations AuV2O6+", J. Am. Chem. Soc.2016, 138, 9437-9443.
Li Y-K, Yuan Z, Zhao Y-X*, Zhao C, Liu Q-Y, Chen H*, He S-G*. "Thermal Methane Conversion to Syngas Mediated by Rh1?Doped Aluminum Oxide Cluster Cations RhAl3O4+", J. Am. Chem. Soc.2016, 138, 12854-12860.
Liu Q-Y, Ma J-B*,Li Z-Y, Zhao C,Ning C-G, Chen H*,He S-G*. "Activation of Methane Promoted by Adsorption of CO on Mo2C2- Cluster Anions",Angew. Chem. Int. Ed.2016, 55, 5760.
4、CO氧化
Li X-N, Zhang H-M,Yuan Z, He S-G*. "A Nine-Atom Rhodium-Aluminum Oxide Cluster Oxidizes Five CarbonMonoxide Molecules", Nat. Commun, 2016, 7, 11404.
授权专利
1. 发明专利："一种乙二醛和/或甲基乙二醛的无碎裂质谱检测方法"，发明人：何圣贵、刘清宇、张婷、卢雪伟。授权日期：2020-02-03 2. 发明专利："一种分辨丙醛和丙酮的方法"，发明人：何圣贵、张婷、李海方。授权日期：2020-01-20 3. 发明专利："栅网电极及其制备方法"，发明人：何圣贵、袁震。授权日期：2019-10-15 4. 发明专利："一种高分辨率飞行时间质谱探测器俯仰角真空外调节装置"，发明人：何圣贵、袁震。授权日期：2017-04-12
荣誉获奖
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课题组
2012年荣获中国分析测试协会科学技术奖二等奖（CAIA)
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陈娇娇
2017 化学所长兴化工奖学金三等奖
2017 化学所青年科学奖优秀奖
2017-2018 学年三好学生
2019博士研究生国家奖学金
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姜利学
2016-2017 化学所冠名奖学金三等奖
2016-2017 三好学生标兵荣誉称号
2017 博士研究生国家奖学金
2017 化学所青年科学家特别优秀奖
2018 化学所所长优秀奖
2019 化学所优秀毕业生
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张梅琦
2017 中国科学院大学"三好学生"荣誉称号
2017 博士研究生国家奖学金
2017 化学所"所长优秀奖"奖学金
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王丽娜
2018 研究生国家奖学金
2018 中国科学院大学三好学生标兵
2018 化学所青年科学奖特别优秀奖
2018 "第二届化学发展前沿研究生论坛"
最佳墙报奖、最佳口头报告奖
2019 中国科学院化学研究所先锋岗党员
2019 中国科学院化学研究所所长奖学金
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刘清宇
2016 中国科学院化学研究所所长优秀奖
2016 化学所青年科学奖特别优秀奖
2015 化学所冠名奖学金三等奖（杰事杰）
2015 化学所青年科学奖优秀奖
?
袁震
2014 化学所冠名奖学金一等奖（国佳新材）
?
孟敬恒
2014 化学所冠名奖学金一等奖（成都拓力）
2013化学所联冠科技奖学金三等奖
2012中国科学院大学"优秀学生干部"
2011中国科学院研究生院"优秀学生"
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李子玉
2015 中国科学院大学"朱李月华"优秀博士生奖
2014 研究生国家奖学金 化学所所长奖学金优秀奖
2013 中国科学院大学三好学生
2012 化学所所长奖学金三等奖
2011 化学所冠名奖学金三等奖
2011 化学所所长奖学金二等奖
徐波
2011 化学所所长奖学金三等奖
马嘉璧
2010 化学所所长奖学金一等奖
2010 刘洪林奖学金三等奖
2012 中科院保洁优秀研究生奖
吴晓楠
2009 化学所青年科学奖优秀奖
2010 化学所所长奖学金三等奖
2010 刘洪林奖学金三等奖
2011 化学所青年科学奖优秀奖
2011 化学所所长奖学金一等奖
赵艳霞
2010 化学所青年科学奖特别奖
2010 化学所所长奖学金一等奖
2010 宁波大成奖学金二等奖
2011 三好学生标兵
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李晓娜
2014 中科院化学所青年科学奖特别优秀奖
2012 中科院化学所青年科学奖优秀奖
?
王哲琛
2009 化学所所长奖学金二等奖
2009 宁波大成奖学金三等奖
薛伟
2008年 化学所青年科学奖
2009年 化学所所长奖学金一等奖
2009年 江阴科技创新奖学金二等奖
单篇全文显示
毕业风采 组内活动
毕业风采
2019年毕业照
2018年毕业照
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2017年毕业照
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2016年毕业照
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2015年毕业照
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2014年毕业照
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2013年毕业照
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2012年毕业照
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2011年毕业照
2010年毕业照
单篇全文显示
2019年秋季登山活动——北京西山国家森林公园
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2019年全国动力学会议——苏州
团簇领域
Professor
Prof. Sheng-Gui He
Contact us
Institute of Chemistry, Chinese Academy of Sciences
Address: No.2 1st North Street Zhongguancun Beijing P.R.China
ZIP Code: 100190
TEL:+86-010-6256 8330
E-mail:shengguihe@iccas.ac.cn
Cluster chemistry
The research program of Dr. He's group focuses on generating and charactering very small chemical entities composed of limited numbers of atoms. These chemical entities are termed as atomic clusters or molecular clusters depending on the nature of chemical bonding in the systems. The properties of clusters are strongly dependent on the numbers of atoms in the systems, which are well recognized as "each atom counts" in the community of cluster sciences. By studying how and why each atom counts, one can provide reliable and fundamental basis with a bottom up strategy to solve complex scientific problems in practical applications.
Transformation of very stable molecules including methane, dinitrogen, carbon monoxide, and so on at low temperature or even room temperature is of great importance in terms of energy conservation and environmental protection. The research target of Dr. He's group is to find the mechanisms of low temperature activation and conversion of very stable molecules by a systematic study of the elementary reactions between molecules and cluster species under isolated, controlled, and well reproducible conditions with home-made instruments. These mechanisms can be fundamental basis with which to develop new catalytic materials or strategies in practice.
Research findings
1、CO2 Activation
Jiang L-X,Zhao C,Li X-N*, Chen H*,He S-G*. "Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions", Angew. Chem. Int. Ed, 2017, 56, 4187-4191.
2、The reactivity of nano-sized clusters
Zhang M-Q, Zhao Y-X*, Liu Q-Y, Li X-N, He S-G*. "Does Each Atom Count in the Reactivity of VanadiaNanoclusters?",J.Am.Chem. Soc. 2017, 139, 342-347.
3、CH4 Activation
Li Z-Y, Li H-F, Zhao Y-X*, He S-G*. "Gold (III) Mediated Activation and Transformation of Methane on Au1-doped Vanadium Oxide Cluster Cations AuV2O6+", J. Am. Chem. Soc.2016, 138, 9437-9443.
Li Y-K, Yuan Z, Zhao Y-X*, Zhao C, Liu Q-Y, Chen H*, He S-G*. "Thermal Methane Conversion to Syngas Mediated by Rh1?Doped Aluminum Oxide Cluster Cations RhAl3O4+", J. Am. Chem. Soc.2016, 138, 12854-12860.
Liu Q-Y, Ma J-B*,Li Z-Y, Zhao C,Ning C-G, Chen H*,He S-G*. "Activation of Methane Promoted by Adsorption of CO on Mo2C2- Cluster Anions",Angew. Chem. Int. Ed.2016, 55, 5760.
4、CO Oxidation
Li X-N, Zhang H-M,Yuan Z, He S-G*. "A Nine-Atom Rhodium-Aluminum Oxide Cluster Oxidizes Five CarbonMonoxide Molecules", Nat. Commun, 2016, 7, 11404.
Home-made instruments
A picture of the home-made Q-LIT-ReTOF mass spectrometer for reactions of mass-selected clusters.
A picture of the home-made ReTOF/ReTOF tandem mass spectrometer for characterizations of mass-selected clusters employing photoelectron imaging spectroscopy, collision induced dissociation, and vibrational spectroscopy.
A picture of the home-made oa-TOF/oa-TOF tandem mass spectrometer for studying nano-sized atomic clusters.
