朱钢国博士校“双龙****”****
ORCID ID: 0000-0003-4384-824X
Tel：；E-mail: gangguo@zjnu.cn。
主要经历如下：
1996年9月－2000年7月：浙江师范大学化学系，理学学士。
2000年9月－2005年7月：中科院上海有机化学研究所，理学博士，导师张兆国教授。
2005年9月－2007年10月：师从美国普渡大学诺贝尔化学奖得主Negishi教授博士后研究。
2007年11月－2008年10月：美国印第安纳大学博士后研究。
2008年12月－至今：浙江师范大学化学系任教。现为教授、博士生导师、化学与生命科学学院副院长（主持工作）、浙江省化学会常务理事，2013年入选浙江省高校中青年学科带头人，2016年入选浙江省“151”人才工程第二层次培养对象、浙江师范大学首批“双龙****”****。发表Angew. Chem. Int. Ed.、Chem. Sci.、Org. Lett.、Chem. Commun.、Adv. Synth. Catal.、J. Org. Chem.等SCI论文78篇，授权发明专利10多件，先后主持国家自然科学基金3项、浙江省自然科学基金重点项目、****基金等省部级项目4项，完成企业横向项目3项，主要从事过渡金属催化的氟化反应、自由基反应和生理活性的天然产物全合成研究。
获奖：
1、2019 Thieme Chemistry Journal Award。
2、2015年浙江省自然科学奖三等奖：杂原子取代炔烃的亲核金属化反应方法学研究（第一完成人）；
3、2012年度浙江省高校优秀科研成果奖一等奖：杂原子取代炔烃的亲核钯化反应方法学研究（第一完成人）。
主持项目：
1、国家自然科学基金面上项目：过渡金属催化的醛直接转化为酮的自由基反应研究(**)；
2、浙江省公益性技术应用研究计划项目：2-氨基呋喃化学品的催化合成技术研究(2015C31030)；
3、国家自然科学基金面上项目：基于1,2-双官能团化烯烃的偶联反应选择性合成多取代烯烃(**)，已结题；
4、浙江省****基金：1-卤-1-硫代烯烃的立体选择性合成及其三取代烯烃的构建(LR12B02001)，已结题；
5、国家自然科学基金青年基金：偶极烯丙基钯的环加成反应研究(**)，已结题；
6、浙江省钱江人才计划项目：抗禽流感药物达菲的合成工艺研究(2010R10016)，已结题。
发表文章：
2020年
1. AIBN-Induced Remote Trifluoromethyl-Alkynylation of Thioalkynes,Xiong, Z.; Zhang, F.; Yu, Y.; Tan, Z.; Zhu, G.*Org. Lett.2020,22, accepted.
2. Photocatalytic Remote Oxyfluoroalkylation of Heteroalkynes: Regio-, Stereo-, and Site-Selective Access to Complex Fluoroalkylated (Z)-Alkenes, Shang, T.; Zhang, J.; Zhang, Y.; Zhang, F.; Li, X.-S.*;Zhu, G.*Org. Lett.2020,22, 3667-3672.
2019年
3. Visible-Light Photocatalytic Remote Thiolation of Aldehydes Triggered by Sulfonylation of Alkenes With Thiosulfonates, Yang, J.; Fu, X.; Lu, Z.; Zhu, G.* Acta Chim. Sinica2019, 77, 901-905 (invited paper).
4. Photocatalytic 1,1-Hydrofluoroalkylation of Alkynes with A Concurrent Vicinal Acylation: An Access to Fluoroalkylated Cyclic Ketones, Wan, Y.; Shang, T.; Lu, Z. Zhu, G.*Org. Lett.2019,21, 4187-4191.
5. Visible light photocatalytic acyldifluoroalkylation of unactivated alkenes for the direct synthesis of gem-difluorinated ketones, Zhou,Y.; Xiong, Z.; Qiu, J.; Kong, L.*; Zhu, G.* Org. Chem. Front.2019, 6, 1022-1026.
6. Modular Synthesis of Alkylarylazo Compounds via Iron(III)-Catalyzed Olefin Hydroamination,Zhang, Y.*; Huang, C.; Lin, X.; Hu, Q.; Hu, B.; Zhou, Y.;Zhu, G.*Org. Lett.2019,21, 2261-2264.
7. Multicomponent Synthesis of Isoindolinones by RhIIIRelay Catalysis: Synthesis of Pagoclone and Pazinaclone from Benzaldehyde, Zhang, Y.*; Zhu, H.; Huang, Y.; Hu, Q.; He, Y.; Wen, Y.;Zhu, G.*Org. Lett.2019,21, 1273-1277.
2018年
8. Recent Advances on Oxidative Radical Addition to Aldehydes, Kong, L.; Zhou, Y.; Luo, F.; Zhu, G.*Chin. J. Org. Chem.2018, 38, 2858-2865.
9. Palladium-Catalyzed anti-Selective Fluoroalkylboration of Internal and Terminal Alkynes, Wang, S.; Zhang,J.;Kong, L.; Tan, Z.; Bai,Y.*;Zhu, G.* Org. Lett.2018, 20, 5631-5635.
10. Visible-light inducedthree-component alkynyl-difluoroalkylation of unactivated alkenes,Jin, W.; Wu, M.; Xiong, Z. Zhu, G.* Chem. Commun.2018, 54, 7924-7927.
11. Synthesis of Difluoromethylated and Phosphorated Spiro[5.5]trienones via Dearomative Spirocyclization of Biaryl Ynones, Zhang, Y.*; Zhang, J.; Hu, B.; Ji, M.; Ye, S.; Zhu, G.*Org. Lett.2018, 20, 2988-2992.
12. Photocatalytic acylarylation of unactivated alkenes with diaryliodonium salts toward indanones and related compounds, Chen, Y.; Shu, C.; Luo, F.; Xiao, X.;*Zhu, G.* Chem. Commun.2018, 54, 5373-5376.
13. Intermolecular Oxidative Radical Addition to Aromatic Aldehydes: Direct Access to 1,4- and 1,5-Diketones via Silver-Catalyzed Ring-Opening Acylation of Cyclopropanols and Cyclobutanols, Che, C.; Qian,Z.; Wu, M.; Zhao, Y.; Zhu, G.*J. Org. Chem.2018, 83, 5665-5673.
14. Nickel-Catalyzed Remote Arylation of Alkenyl Aldehydes Initiated by Radical Alkylation with Tertiary α-Carbonyl Alkyl Bromides, Jin, W.; Zhou, Y.; Zhao, Y.; Ma, Q.; Kong, L.; Zhu, G.* Org. Lett.2018, 20, 1435-1438.
15. Palladium-Catalyzed Site-Selective sp3C-H Bond Thiocyanation of 2-Aminofurans, Chen, Y.; Wang, S.; Jiang, Q.; Cheng, C.; Xiao,X.;*Zhu, G.* J. Org. Chem.2018, 83, 716-722.
2017年
16. Preparation of 2-Amino-5-homoallylfurans via Palladium-Catalyzed Tandem Cycloisomerization/Heck-Type Coupling of Homoallenyl Amides with Allyltrialkylsilanes, Zhang, J.; Wu, M.; Lu, W.; Wang, S.; Zhang, Y.; Cheng, C.;* Zhu, G.* J. Org. Chem.2017, 82, 11134-11140.
17. Palladium-catalyzed tandem cyclization/sulfonylation of homoallenyl amides with sodium sulfinates, Wan, Y.; Zhang, J.; Chen, Y.; Kong, L.; Luo, F.;* Zhu, G.*Org. Biomol. Chem. 2017,15, 7204-7211.
18. Copper-Catalyzed Radical Cascade Difluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes: A Route to Difluoromethylated Naphthoquinones, Zhang, Y.*; Ye, S.; Ji, M.; Li, L.; Guo, D.; Zhu, G.J. Org. Chem.2017, 82, 6811-6818. 12
19. Visible Light-Induced Tandem Radical Addition-Cyclization of Alkenyl Aldehydes Leading to Indanonesand Related Compounds, Lu, D.; Wan, Y.; Kong, L.;Zhu, G.*Org. Lett.2017, 19, 2929-2932. 23
20. Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds,Liu, Z.; Bai, Y.; Zhang, J.; Yu, Y.; Tan, Z.;Zhu, G.*Chem. Commun.2017, 53,6440-6443. 20
21. Palladium-Catalyzed Remote Aryldifluoroalkylation of Alkenyl Aldehydes, Nie, X.; Cheng, C.; Zhu, G.* Angew. Chem. Int. Ed.2017,56, 1898-1902.33
22. Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes, Zhang, Y.;*Guo, D.(本科生); Ye, S.; Liu, Z.;Zhu, G.*Org. Lett.2017, 19, 1302-1305. 29
23. Copper-catalyzed borylative cyclization of 1,n-enynyl phosphates leading to five- to eight-membered cyclic 1,4-dienyl boronates, Zhang, F.; Wang, S.; Liu, Z.; Bai, Y.;*Zhu, G.* Tetrahedron Lett.2017, 58, 1448-1452.
2016年
24. Synthesis of (E)-α,β-Unsaturated Carbonylsvia Silver-Catalyzed Tandem Epoxide Rearrangement/Intermolecular Carbonyl-Heteroalkyne Metathesis,Zhu, H.; Jin, W.; He, J.; Zhang, Y.*; Zhu, G.* Adv. Synth. Catal. 2016, 358, 3730-3735.
25. Copper-catalyzed cascade annulation between α-bromocarbonyls andbiaryl or (Z)-arylvinylacetylenes enabling a direct synthesis of dibenzocycloheptanes and related compounds, Lu, D.; Wan, Y.; Kong, L.;Zhu, G.*Chem. Commun.2016, 52, 13971-13974.
26. Copper-Catalyzed Trifluoromethylation of Alkenes with Redox-Neutral Remote Amidation of Aldehydes, Cheng, C.; Liu, S.; Lu, D.; Zhu, G.* Org. Lett.2016, 18, 2852-2855. 26
27. Copper-catalyzed cascade annulation of unsaturated α-bromocarbonyls with enynals: a facile access to ketones from aldehydes,Che, C.; Huang, Q.; Zheng, H.; Zhu, G.*Chem. Sci. 2016, 7, 4134-4139. 39
28. Direct access to 2-amino-5-azidomethylfurans through palladium-catalyzed azidativecycloisomerization of homoallenyl amides, Huang, Q.(本科生); Zheng, H.; Liu, S.; Kong, L.; Luo, F.*; Zhu, G.* Org. Biomol. Chem. 2016,14, 8557-8563.
29. HOTf-Catalyzed, Solvent-free Oxyarylation of Ynol Ethers and Thioethers, Hu, L.; Cui, Q.; Chen, X.; Tan, Z.*; Zhu, G.* J. Org. Chem.2016, 81, 4861-4868.
30. Copper-catalyzed coupling of 2-vinyl benzaldehydes with 3-alkenyl 2-bromocarbonyls for the rapid construction of 3,4-cyclopenta-1-tetralones, Zhu, H.; Nie, X.; Huang, Q.; Zhu G.*Tetrahedron Lett.2016, 57, 2331-2335. 16
31. Highly mono-selective ortho-trifluoromethylation of benzamides via 8-aminoquinoline assisted Cu-promoted C-H activations, Hu, L.; Chen, X.; Gui, Q.; Tan, Z.*, Zhu, G.Chem. Commun. 2016,52, 6845-6848.
2015年
32. A rapid and selective synthesis of α,α-fluorohalo esters via fluorohalogenative or difluorinative hydration of ynol ethers, Hu, L.; Che, C.; Tan, Z.;* Zhu, G.* Chem. Commun. 2015, 51, 16641-16644.
33. Construction of 1-Naphthols via Benzannulation Based on the Reaction of Aryl tert-Butyl Ynol Ethers with Ynamides or Ynol Ethers, Bai, Y.; Yin, J.; Liu, Z.; Zhu, G.* J. Org. Chem.2015, 80, 10226-10233.
34. Copper-Catalyzed trans-Carbohalogenation of Terminal Alkynes with Functionalized Tertiary Alkyl Halides, Che, C.; Zheng, H.; Zhu, G.* Org. Lett.2015, 17, 1617-1620.
35. Palladium-Catalyzed Cycloisomerization and Aerobic Oxidative Cycloisomerization of Homoallenyl Amides: A Facile and Divergent Approach to 2-Aminofurans, Cheng, C.; Liu, S.; Zhu, G.* Org. Lett.2015, 17, 1581-1584.
36. Copper-catalyzed regio- and stereoselective hydroallylation of thioalkynes with allylboronates: a facile and convenient synthesis of 1,4-dienes, Kong, W.; Che, C.; Kong, L.*; Zhu, G.* Tetrahedron Lett.2015, 56, 2780-2782.
37. Copper-Catalyzed β-Selective Borylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates, Bai, Y.*; Zhang, F.; Shen, J.; Luo, F.; Zhu, G.*Asian J. Org. Chem.2015, 4, 626-629 (Dedicated to Prof. Ei-ichi Negishi on the occasion of his 80th birthday)
38. Divergent Synthesis of 2-Aminofurans via Palladium-Catalyzed Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of Homoallenyl Amides, Cheng, C.; Liu, S.; Zhu, G.* J. Org. Chem.2015, 80, 7604-7612.
2014年
39. Palladium-Catalyzed Cross Addition of Terminal Alkynes to Aryl Ynamides: An Unusual trans-Hydroalkynylation Reaction, Liu, G.; Kong, W.; Che, J.; Zhu, G.*Adv. Synth. Catal. 2014, 356, 3314-3318.
40. Preparation of (Z)-α,β-Disubstituted Enamides via Palladium-Catalyzed Addition of Boronic Acids to Ynamides, Yang, Y.; Wang, L.; Zhang, F.; Zhu. G.*J. Org. Chem.2014, 79, 9319-9324.
41. Silver-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Ynol Ethers, Yin, J.; Bai, Y.; Mao, M.; Zhu. G.*J. Org. Chem.2014, 79, 9179-9185.
42. Silver-promoted trans-hydrofluorination of ynamides: a regio- and stereoselective approach to (Z)-α-fluoroenamides, Che, J.(本科生); Li, Y.; Zhang, F.; Zheng, R.*; Bai, Y.;Zhu. G.*Tetrahedron Lett. 2014,55, 6240-6242.
43. Pd-Catalyzed Regio- and Stereoselective Addition of Boronic Acids to Silylacetylenes: A Stereodivergent Assembly of β,β-Disubstituted Alkenyl Silanes and Alkenyl Halides, Kong, W.; Che, C.; Wu, J.; Ma, L.; Zhu, G.*J. Org. Chem. 2014, 79, 5799-5805.
44. Palladium-Catalyzed Hydroarylation, Hydroalkenylation, and Hydrobenzylation of Ynol Ethers with Organohalides: A Regio- and Stereoselective Entry to α,β- and β,β-Disubstituted Alkenyl Ethers, Cui, W.; Ying, J.;Zheng, R.; Cheng, C.; Bai, Y. Zhu, G.*J. Org. Chem. 2014, 79, 3487-3493.
45. An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides. Yang, Y.; Wang, L.; Zhang, J.; Jin, Y.; Zhu, G.*Chem. Commun.2014, 50, 2347-2349.
46. Synthesis ofcis-1,2-dichlorovinylsulfones via Fe-catalyzed regio- and stereoselective addition of sulfonyl chlorides to aromatic chloroalkynes. Wang, L.; Zhu, H.; Che, J.; Yang, Y.*; Zhu, G.*Tetrahedron Lett. 2014,55,1011-1013.
47. Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study. Zhu, G.*; Kong, W.; Feng, H.; Qian, Z.* J. Org. Chem. 2014, 79, 1786-1795.
48. A regio- and stereoselective entry to (Z)-β-halo alkenyl sulfides and their applications to the access of stereodefined trisubstituted alkenes. Liu, G.; Kong, L.; Shen, J.; Zhu, G.*Org. Biomol. Chem.2014,12, 2310-2321.
2013年
49. Palladium-Catalyzed Direct Alkenylation of 2-Oxazolones: An Entry to 3,4,5-Trisubstituted 2-Oxazolones, Lu, Z.; Luo, F.; Wang, L.; Zhu, G.*J. Org. Chem.2013, 78, 10894-10901.
50. Pd-catalyzed addition of boronic acids to ynol ethers: a highly regio- and stereoselective synthesis of trisubstituted vinyl ethers. Bai, Y.; Yin, J.; Kong, W.; Mao, M.; Zhu, G.*Chem. Commun.2013, 49, 7650-7652.
51. Regioselective and Stereoselective Entry to β,β-Disubstituted Vinyl Ethers via the Sequential Hydroboration/Suzuki–Miyaura Coupling of Ynol Ethers. Cui, W.; Mao, M.; He, Z.; Zhu, G.*J. Org. Chem.2013, 78, 9815-9821.
52. Copper-catalyzed direct thiolation of xanthines and related heterocycles with disulfides. He, Z.(本科生); Luo, F.;*Li, Y.; Zhu, G.*Tetrahedron Lett. 2013,54, 5907-5910.
53. An operationally simple approach to (E)-α-halo vinyl sulfides and their applications for accessing stereodefined trisubstituted alkenes. Yang, Z.(本科生); Chen, X.; Kong, W.; Xia, S.; Zheng, R.; Luo, F.; Zhu, G.*Org. Biomol. Chem.2013,11, 2175-2185.
2012年
54. Highly stereoselective synthesis of (Z)-1,2-dihaloalkenes by a Pd-catalyzed hydrohalogenation of alkynyl halides. Zhu, G.*;Chen, D.; Wang, Y.; Zheng, R.Chem. Commun.2012, 48, 5796-5798.
55. Preparation of 3,4,5-Trisubstituted Oxazolones by Pd-Catalyzed Coupling of N-Alkynyl tert-Butyloxycarbamates with Aryl Halides and Related Electrophiles. Lu, Z.; Cui, W.; Xia, S.; Bai, Y.; Luo, F.;Zhu, G.*J. Org. Chem.2012,77,9871-9877.
56. A Facile Access to 3,5-Disubstituted Oxazolones Featuring a Cu-catalyzed Cyclization of N-Alkynyl tert-Butyl Carbamates. Lu, Z.; Yang, Z.; Cui, W.;Zhu, G.* Chem. Lett.2012, 41, 636-638.
57. Approach to highly functionalized oxazolones by a Pd-catalyzed cyclization of N-alkynyl tert-butyloxycarbamates. Lu, Z.; Xu, X.; Yang, Z.; Kong, L.*;Zhu, G.*Tetrahedron Lett. 2012, 53, 3433-3436.
58. A Facile Method for the Synthesis of 3-Alkyloxindole. Du, T.; Zhu, G.*; Zhou, J.* Lett. Org. Chem.2012, 9, 225-232.
2011年
59. Palladium-catalyzed haloallylation of aromatic ynol ethers with allyl chlorides: a highly regio- and stereoselective approach to (1E)-α-chloroenol ethers. Cai, H.(本科生); Yuan, Z.; Zhu, W.; Zhu, G.*Chem. Commun.2011, 47, 8682-8684.
60. Palladium-catalyzed highly regio- and stereoselective synthesis of (1E)- or (1Z)-1,2-dihalo-1,4-dienes via haloallylation of alkynyl halides. Chen, X.; Kong, W.; Cai, H.; Kong, L.;Zhu, G.*Chem. Commun. 2011,47,2164-2166.
61. Palladium-Catalyzed Dienylation of Haloalkynes Using 2,3-Butadienyl Acetates: A Facile Access to (1Z)-1,2-Dihalo-3-vinyl-1,3-dienes. Chen, D.; Chen, X.; Lu, Z.; Cai, H.; Shen, J.; Zhu, G.*Adv. Synth. Catal. 2011, 353, 1474-1478.
62. Synthesis of Multisubstituted Enamides via Pd-Catalyzed Chloroallylation of Ynamides. Lu, Z.; Kong, W.; Yuan, Z.; Zhao, X.; Zhu. G.*J. Org. Chem.2011,76, 8524-8529.
63. Palladium-Catalyzed Coupling of Haloalkynes with Allyl Acetate: A Highly Regio- and Stereoselective Synthesis of (Z)-β-Haloenol Acetates. Chen, X.; Chen, D.; Lu, Z.; Kong, L.; Zhu, G.*J. Org. Chem. 2011,76, 6338-6343.
64. Synthesis of cis-1,2-Dihaloalkenes Featuring Palladium-Catalyzed Coupling of Haloalkynes and α,β-Unsaturated Carbonyls. Chen, D.; Cao, Y.; Yuan, Z.; Cai, H.; Zheng, R.; Kong, L.; Zhu, G.*J. Org. Chem. 2011,76, 4071-4074.
2010年
65. Highly efficient and diastereoselective synthesis of 1,3-oxazolidines featuring a palladium-catalyzed cyclization reaction of 2-butene-1,4-diol derivatives and imines. Chen, D.; Chen, X.; Du, T.; Kong, L.; Zheng, R.; Zhen, S.; Wen, Y.;Zhu, G.*Tetrahedron Lett.2010, 51, 5131-5133.
博士及博士后阶段
66. A Tunable Mimics of Pyridoxal
67. Efficient and Selective Synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-Hexamethyldocosane via Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA Reaction). Zhu, G.; Liang, B.; Negishi, E.*Org. Lett.2008, 10, 1099-1101.
68. 1,4-Pentenyne as a Five-Carbon Synthon for Efficient and Selective Syntheses of Natural Products Containing 2,4-Dimethyl-1-penten-1,5-ylidene and Related Moieties via Zr-Catalyzed Carboalumination of Alkynes and Alkenes. Zhu, G.; Negishi, E.* Chem. Eur. J.2008, 14, 311-318.
69. Fully Reagent-Controlled Asymmetric Synthesis of (–)-Spongidepsin via the Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA Reaction). Zhu, G.; Negishi, E.* Org. Lett.2007, 9, 2771-2774.
70. Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA)_Lipase-Catalyzed Acetylation Synergy. Huang, Z.; Tan, Z.; Novak, T.; Zhu, G.; Negishi, E.* Adv. Synth. Catal.2007, 349, 539-545.
71. Zirconium-Catalyzed Methylalumination of Heterosubstituted Arylethynes. Factors Affecting the Regio-, Stereo-, and Chemoselectivities. Wang, G.; Zhu, G.; Negishi, E.* J. Organomet. Chem.2007, 692, 4731-4736.
72. Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation.Negishi, E.*; Wang, G.; Zhu, G. Topics in Organometallic Chemistry,2006, 19, 1-48.
73. Transition Metal-Catalyzed Intramolecular Enyne Cyclization Reaction. Zhang, Z.*; Zhu, G.; Tong, X.; Wang, F.; Xie, X.; Wang, J.; Jiang, L. Curr. Org. Chem.2006, 10, 1457-1478.
74. Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,6-Enynes: Reaction Scope and Mechanism. Zhu, G.; Tong, X.; Cheng, J.; Sun, Y.; Li, D.; Zhang, Z.* J. Org. Chem. 2005, 70, 1712-1717.
75. cis-Chloropalladation of 1,6-Enynes. Zhu, G.; Zhang, Z.* J. Org. Chem. 2005, 70, 3339-3341.
76. A Concise Synthesis of 2-Diarylphosphino-20-methoxy-1,10-binaphthalenes (MOPs) by Simple Resolution. Luo, Y.; Wang, F.; Zhu, G.; Zhang, Z.* Tetrahedron Asymmetry2004, 15, 15-17.
77. Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,2,7-trienes.Zhu, G.; Zhang, Z.* Org. Lett.2004, 6, 4041-4044.
78. Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,6-Enynes. Zhu, G.; Zhang, Z.* Org. Lett.2003, 5, 3645-3648.
学术报告：
1. 自由基迁移引发的远程醛基直接官能团化反应研究,第二届全国有机自由基化学会议，深圳，2019.04.14。
2. 自由基加成启动的远程碳-氢官能团化反应研究，第十七届江淮有机化学论坛，台州，2019.11.03。
3. 自由基加成启动的远程碳-氢官能团化，2019世界青年科学家峰会-绿色化学国际论坛，2019.10.26。
4. 醛基的氧化自由基加成反应研究，第31届中国化学会学术年会，浙江杭州，2018.05.07。
5. 醛基参与的自由基转化反应研究，有机合成与药物化学研讨会，复旦大学，2018.08.28。
6. 远程醛基碳-氢键的直接官能团化反应研究，第十届全国有机化学学术会议，广东深圳，2017.12.19。
7. 醛直接转化为酮的催化自由基反应研究，第十五届全国均相催化学术讨论会，浙江杭州，2017.09.28。
8. Transition-Metal-Catalyzed Radical Transformation of Aldehydes for the Synthesis of Carbonyl Compounds，第一届全国有机自由基化学会议，苏州，2017.11.04。
授权专利：
1、 顺式-1-卤-2-氯代烯烃及其制备方法和应用，朱钢国、陈东旭，专利号：ZL 7.9，授权时间：2013.11.27。
2、 一种莽草酸的合成方法，朱钢国、崔伟剑、夏思苑、何祖莺，专利号：ZL 7.7，授权时间：2013.11.27。
3、 一种3,4,5-三取代噁唑-2-酮的合成方法，朱钢国、卢增辉、刘鸽、罗芳、夏思苑，专利号：ZL 8.X，授权时间：2014.11.05。
4、 一种利用顺式-1-卤-2-氯代烯烃合成维生素A的方法，朱钢国，陈东旭，专利号：ZL8.9，授权时间：2014.11.05。
5、 一种替马罗汀的合成方法，朱钢国、李英龙、金雅丽、金发根、吴平、楼益义，专利号：ZL 9.5，授权时间：2015.01.14。
6、 一种奥司他韦的合成方法，朱钢国、杜思全、章洁妮、程存归，专利号：ZL 8.7，授权时间：2015.05.27。
7、 一种多环酮的制备方法，朱钢国、车超、黄倩雯、郑汉良，专利号：ZL 0.3，授权时间：2018.03.20。
8、 一种ε-三氟甲基取代酰胺的制备方法，朱钢国，刘水有，罗芳，黄倩雯，专利号：ZL 0.3，授权时间：2018.06.26。
9、 一种2-氨基-5-叠氮基甲基呋喃的制备方法，朱钢国，黄倩雯，罗芳，郑汉良，刘水有，郭冬梅，专利号：ZL 4.3，授权时间：2018.06.29。
10、一种3,4-环戊基-1-萘满酮的制备方法，朱钢国，朱慧，罗芳，黄倩雯，专利号：ZL 9.0，授权时间：2018.09.11。
11、一种二苯并环庚烷衍生物的制备方法，朱钢国，卢丹阳，罗芳，专利号：ZL 8.3，授权时间：2019.03.08。
12、一种2-三氟甲基-1,4-萘醌衍生物的制备方法，朱钢国，张岩，罗芳，金伟伟，专利号：ZL 0.1，授权时间：2019.07.30。
13、一种6-二氟烷基酮的制备方法，朱钢国，聂新亮，罗芳，程存归，郭冬梅，专利号：ZL2.8，授权时间：2019.08.06。
14、一种1,1-二氟四氢萘化合物的制备方法，朱钢国，聂新亮，罗芳，程存归，郭冬梅，专利号：ZL4.4，授权时间：2019.09.06。
指导学生：
1、校优秀硕士学位论文：陈东旭（2012）、卢增辉（2013）、崔伟剑（2014）、孔伟（2015）、印靖（2015）、车超（2016）、刘水有（2016），聂新亮（2017）、卢丹阳（2017）、金伟伟（2018）。
2、夏思苑等，杂原子取代炔烃的氢卤化反应研究及其应用，第十三届大学生“挑战杯”竞赛浙江省一等奖、全国二等奖。
