本课题组研究的领域为无机原子簇（多金属氧酸盐POM原子簇和银纳米原子簇），量子点材料及无机有机杂化材料（金属有机框架MOF）的自组装及面向分子功能材料与器件设计的相关研究。迄今为止，在国际学术期刊上已发表原创性论文45 篇。其中以第一作者或者通讯作者在Chem. Soc. Rev.（1 篇，内封面文章，IF = 38.62）、Nat. Commun.（1 篇，IF=12.12）、Angew. Chem. Int. Ed. （3 篇，IF=11.99）、Energy Storage Mater. （1 篇，IF=16.28）、Nanoscale（1 篇，IF=6.91）、Chem. Commun.（2 篇，IF=6.32）、Inorg. Chem.（1 篇，IF=4.86）等高档次期刊发表论文10 篇。目前，课题组主要研究方向包括：1）多金属氧酸盐POM的构建与性能研究；2）银纳米原子簇的组装与合成；3）复合量子点材料的合成与发光性能研究；4）金属有机框架MOF材料的合成与吸附催化性能研究。

本课题组的工作计划是一项从基础研究到实际应用的系统研究。与多个国际知名课题组和研究机构建立了良好的合作关系。与浙江大学彭笑刚教授团队及中科院福建物构所张健研究员团队合作，探讨研究POM 和量子点及MOF 复合纳米材料及分子电子器件的组装与应用。并保持和英国格拉斯哥大学Cronin 教授（英国爱丁堡皇家科学院院士）在POM 合成性质研究和格拉斯哥大学Gregory 教授在无机金属卤族、硫族材料合成应用方面的合作。热烈欢迎热爱物理化学和无机化学的同学们加入我们充满活力的团队，我们将努力为大家营造良好的学习环境和宽松自由的科研氛围，让每一位成员快乐的享受科研的探索与创造过程。

团队成员：
詹才宏（课题组负责人），教授，“双龙****”
英国格拉斯哥大学 （University of Glasgow） 理学博士，师从英国爱丁堡皇家科学院院士Cronin 教授。浙江省物理学会X射线衍射专业委员。主要从事多金属氧酸盐POM，铜银金团簇化学，金属有机框架MOF，量子点及复合材料的设计合成与性能研究，多次应邀在大型国际学术会议上作分会口头报告。2017年荣获国际博士后交流奖学金并邀请到德国慕尼黑工业大学访问交流。2016 年荣获国家优秀留学生奖学金。2011-2015年荣获格拉斯哥大学科学工程学院全额奖学金。
蒋战果
厦门大学理学博士，讲师。主要从事过渡金属有机框架材料的合成与应用研究及金银原子簇化学，多酸化学的研究。

在读硕士研究生：黄丹平（2018级），毛威涛（2018级），王宇（2018级），王潮（2019级），吴伟虹（2019级），曾慧敏（2019级），袁云月（2020级），王明月（2020级）。

主讲课程
主讲本科生课程：《物理化学》（英语教学）；《无机化学》（英语教学）

科研项目
主持项目：
国家自然科学基金青年科学基金项目：无机柔性多酸多孔框架材料的自组装与性质研究，在研。
浙江省自然科学基金项目：多酸量子点复合材料的自组装与电荷转移研究，在研。
3. 浙江师范大学高层次人才引进启动经费，在研。

联系方式
通讯地址：浙江省金华市迎宾大道688号浙江师范大学生化学院，邮编：321004
Email：chzhan@zjnu.cn

发表论文
Cai-Hong Zhan,Dan-Ping, Huang, Yu, Wang, Wei-Tao, Mao, Xiao-Juan, Wang*, Zhan-Guo Jiang*, Feng Yun-Long. Four anionic Ln-MOFs for remarkable separations of C2H2–CH4 / CO2–CH4 and highly sensitive sensing of nitrobenzene, CrystEngComm, 2021, 10.1039/D1CE00235J.
Zhan-Guo Jiang, Wei-Tao Mao, Dan-Ping Huang, Yu Wang, Xiao-Juan Wang, Cai-Hong Zhan*. A nonconventional host–guest cubic assembly based on γ-cyclodextrin and a Keggin-type polyoxometalate. Nanoscale, 2020, 12, 10166–10171.
Zhan-Guo Jiang, Xin Wu, Zhong-Xuan Xu, Cai-Hong Zhan*, Jian Zhang*. Synthesis and photocatalytic activities of two homochiral metal–organic frameworks with cages and hydrogen bonding helices. CrystEngComm, 2020, 22, 4206–4209.
Cai-Hong Zhan, Qi Zheng, De-Liang Long, Laia Vilà-Nadal, Leroy Cronin. Controlling the reactivity of the [P₈W₄₈O₁₈₄]^40-inorganic ring and its assembly into POMZite inorganic frameworks with silver ions. Angew. Chem. Int. Ed.2019, 131, 17442–17446.
Cai-Hong Zhan, Jamie M. Cameron, David Gabb, Thomas Boyd, Ross S. Winter, Laia Vilà-Nadal, Scott G. Mitchell, Stefan Glatzel, Joachim Breternitz, Duncan H. Gregory, De-Liang Long, Andrew Macdonell, Leroy Cronin.A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nat. Commun.2017, 8, 14185.
Zhi-Gang Gu^﹟, Cai-Hong Zhan^﹟, Jian Zhang, Xianhui Bu.Chiral chemistry of metal–camphorate frameworks. Chem. Soc. Rev.2016, 45, 3122-3144. (﹟Equal contribution, Inside Front Cover, Highly cited paper)
Cai-Hong Zhan, Ross Winter, Qi Zheng, Jun Yan, De-Liang Long, Leroy Cronin. Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W₄₈}, {W₅₆}, {W₉₂} polyoxometalate clusters. Angew. Chem. Int. Ed.2015, 54, 14308– 14312.
Cai-Hong Zhan, Jamie M. Cameron, Jing Gao, Jamie Purcell, De-Liang Long, Leroy Cronin. Time resolved assembly of cluster-in-cluster {Ag₁₂}-in-{W₇₆} polyoxometalates under supramolecular control. Angew. Chem. Int. Ed.2014, 53, 10362– 10366.
Cai-Hong Zhan, Christoph Busche, De-Liang Long, Pedro I. Molina, Ross S. Winter and Leroy Cronin. Encapsulation of a {Cu₁₆} cluster containing four [Cu₄O₄] cubanes within an isopolyoxometalate {W₄₄} cluster.Chem. Commun.2017,53, 7076– 7079.
Minjie Guo, Xuemei Wang, Cai-Hong Zhan, Paul Demay-Drouhard, Wenjiao Li, Ke Du, Mark A. Olson, Han Zuilhof, Andrew C.-H. Sue. Rim-Differentiated C₅-symmetrical Tiara-Pillar[5]arenes.J. Am. Chem. Soc.2018, 140, 74– 77.
Cai-Hong Zhan, Hai-Ying wang, Zhan-Guo Jiang, Andrew C.-H. Sue. Spontaneous Resolution of “Inseparable” Enantiomeric Pillar[5]arene Conformers.Angew. Chem. Int. Ed.(submitted).
Cai-Hong Zhan, Fei Wang, Yao Kang, Jian Zhang. Lanthanide-thiophene-2, 5-dicarboxylate frameworks: ionothermal synthesis, helical structures, photoluminescent properties and single-crystal-to-single-crystal guest exchange. Inorg. Chem. 2012, 51,523– 530.
Cai-Hong Zhan, Mei-Xiang Jiang, Yun-Long Feng, Jian-Wen Cheng. An unusual fluorite topology built by dinuclear manganese and 5-carboxyl-1-carboxymethyl-3-oxidopyridimium. CrystEngComm.2010, 12, 420 – 424.
Cai-Hong Zhan, Yun-Long Feng. A novel 4⁴.6⁶five-connected metal-organic framework with strong fluorescent emission constructed by m-thioacetatebenzoic acid, J. Solid State Chem. 2010, 183, 1226 – 1230.
Cai-Hong Zhan, Mei-Xiang Jiang, Yun-Long Feng, Yin-Hua He. Syntheses, structures, network topologies and photoluminescence of four Zn(II) and Cd(II) coordination polymers based on 5-carboxyl-1-carboxymethyl-2-oxidopyridinium. Polyhedron. 2010, 29, 2250– 2257.
Cai-Hong Zhan, Yun-Long Feng. Two 3D supramolecules with helices constructed by hydrogen bonds based onp-thioacetatebenzoic acid ligand. Struct. Chem. 2010, 21, 893– 899.
Cai-Hong Zhan, Xiao-Juan Wang, Zhan-Guo Jiang, Ling-Xian Chen,Yun-Long Feng. Three isostructural 3D supramolecules withp-thioacetatebenzoic acid ligand: syntheses and structure characterizations. Struct. Chem. 2010, 21, 1195– 1201.
Cai-Hong Zhan, Wen-Xuan Cai, Yun-Long Feng, Yin-Hua He. An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration.Science China Chem. 2010, 53, 1261– 1265.
Cai-Hong Zhan, Xiao-Juan Wang, Mei-Xiang Jiang, Yun-Long Feng. A fluorescent Cadmium-organic framework constructed by m-Thioacetatebenzoic acid.Chin. J. Struct. Chem.2010, 29, 1864-1868.
Cai-Hong Zhan, Ling-Xian Chen, Yun-Long Feng. 2-[(2-Carboxyphenyl)sulfanyl]acetic acid. Acta Crystallogr. Sect. E: Struct. Rep. Online.2009, 65, 2315.
Cai-Hong Zhan, Shu-Guang Zhang, Yun-Long Feng. [1-(4-Hydroxyphenyl)-1H-tetrazol-5-yl-sulfanyl]acetic acid. Acta Crystallogr. Sect. E: Struct. Rep. Online.2008, 64, 2451.
Xiao-Juan Wang, Cai-Hong Zhan, Jian-Ling Yin, You-Zhao Lan, Yun-Long Feng. Jian-Wen Cheng. Two unusual (4,6)- and 8-connected metal-organic frameworks constructed from flexible 1,4-benzenebis(thioacetic acid) and pyridine-based ligands, CrystEngComm, 2011, 13, 684– 689.
Yao-Kang Lv, Yun-Long Feng, Cai-Hong Zhan, Jing Chen, Xiao-Juan Wang, Zhan-Guo Jiang. Synthesis, crystal structure and properties of a new Manganese(II) complex with mucic acid. Chin. J. Struct. Chem.2011, 27, 791-796.
Xiao-Juan Wang, Mei-Xiang Jiang, Cai-Hong Zhan, Yun-Long Feng, Yin-Hua He. Two new three-dimensional supramolecular complexes with 5-Carboxyl-1-carboxymethyl-2-oxidopyridinium: syntheses and crystal structures. Chin. J. Struct. Chem.2011, 30, 31-36.
Xiao-Yong Zheng, Cai-Hong Zhan, Shu-Guang Zhang, Yun-Long Feng. A new microporous hydrogen-bonding framework constructed from 1-(4-Hydroxyphenyl)-5-Thioacetatetetrazole. J. Chem. Crystallogr.2011, 41, 587-590.
Mei-Xiang Jiang, Cai-Hong Zhan, Yun-Long Feng, You-Zhao Lan. A series of rutile network constructed by dinuclear transition metal units and 5-carboxyl-1-carboxymethyl -3-oxidopyridimium, Cryst. GrowthDes. 2010, 10, 92 – 98.
Yao-Kang Lv, Cai-Hong Zhan, Yun-Long Feng. A chiral manganese-potassium heterometallic MOF with unusual (3, 7) topology network. CrystEngComm.2010, 12, 3052– 3056.
Yao-Kang Lv, Cai-Hong Zhan, Zhan-Guo Jiang, Yun-Long Feng. A chiral helical Mn(II) MOF showing unusual utg topology based on D-saccharic acid. Inorg.Chem.Commu. 2010, 13, 440– 444.
Mei-Xiang Jiang, Xiao-Juan Wang, Cai-Hong Zhan, Yun-Long Feng, Yin-Hua He. A new three-dimensional supramolecular framework with an unprecedented (5,6)-connected topology. Chin. J. Struct. Chem .2010, 26, 1284-1288.
Yin-Hua He, You-Zhao Lan, Cai-Hong Zhan, Yun-Long Feng, Hong Su. A stable second-order NLO and luminescent Cd (II) complex based on 6-hydroxynicotinic acid, Inorg.Chim. Acta.2009, 362, 1952– 1956.
Zhan-Guo Jiang, Tie-Feng Liu, Li-Jing Yan, Jie Liu, Fei-Fei Dong, Ming Ling, Cheng-Du Liang, Zhan Lin. Metal-organic framework nanosheets-guided uniform lithium deposition for metallic lithium batteries. Energy Storage Mater.2018, 11, 267–273.
Zhan-Guo Jiang, Kang Shi, Yu-Mei Lin, Quan-Ming Wang [Ag₇₀(PW₉O₃₄)₂(^tBuC≡C)₄₄(H₂O)₂]⁸⁺: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions. Chem.Commu.2014, 50, 2353-5.
Zhan-Guo Jiang, Yao-Kang Lv, Cheng J-W, Yun-Long Feng Two types of rare earth-organic frameworks constructed by racemic tartaric acid. J. Solid State Chem. 2012, 185, 253-63.
Zhan-Guo Jiang, Xiao-Juan Wang, Jian-Ling Yin, Yun-Long Feng, Jian-Wen Cheng. Two cobalt(II) compounds assembled by flexible 1,4-benzenbis(thioacetic acid) and rigid 2,2'-dipyridine ligands: synthesis, crystal structure and electrochemical property. Chin. J. Inorg. Chem.2012, 28, 607-12.
Zhan-Guo Jiang, Jing Chen, Yun-Long Feng Poly[[bis-(2,2-bipyridine)-bis-[μ(6)-5-(carboxyl-atometh-oxy)benzene -1,3 -dicarboxyl-ato]trimanganese(II)] monohydrate]. Acta Crystallogr. Sect. E: Struct. Rep. Online.2011, 67, 259-60.
Li-Jing Yan, Jie Liu, Qian-Qian Wang, Ming-Hao Sun, Zhan-Guo Jiang, Cheng-Du Liang, Feng Pan, Zhan Lin. In situ wrapping Si nanoparticles with 2D carbon nanosheets as high-areal-capacity anode for lithium-ion batteries. ACS Appl. Mater. Inter.2017, 9, 38159-18164.
Yu-Mei Lin, Zong-Jie Guan, Kuan-Guan Liu, Zhan-Guo Jiang, Quan-Ming Wang. Assembly of silver alkynyl compounds with various nuclearities. Dalton Trans.2015, 44, 2439-2446.
Zhen Lei, Xiao-Li Pei, Zhan-Guo Jiang, Quan-Ming Wang. Cluster linker approach: preparation of a luminescent porous framework with NbO topology by linking silver ions with gold(I) clusters. Angew. Chem. Int. Ed.2014, 53, 12771-12775.
Ming-Ming Han, Xiao Chen, Zhan-Guo Jiang, Rui-Qin Li, Jian-Wen Cheng, Yun-Long Feng. Two coordination polymers based on chiral camphoric acid and flexible 1,4-bis(imidazol)-butane ligands: structures and magnetic properties. Chin. J. Inorg. Chem.2014, 30, 2157-2164.
Hong-Yan Yuan, Ming-Ming Han, Xian-Rong Jiang, Zhan-Guo Jiang, Yun-Long Feng. Six new coordination polymers constructed by 3-carboxyl-5-oxycarboxymethylpyridinio-1-carboxylate: Crystal structures, topologies, photoluminescent and magnetic properties. J. Solid State Chem. 2013, 202, 191-9.
Zi-Ming Xia, Kan Wang, Ji-Ni Zheng, Zhi-Yang Ma, Zhan-Guo Jiang, Xiao-Xia Wang, Xin Lv. Copper-catalyzed domino intramolecular cyclization: a facile and efficient approach to polycyclic indole derivatives. Organic & Biomolecular Chemistry. Org. Biomol. Chem.2012, 10, 1602-1611.
Yao-Kang Lv, Zhan-Guo Jiang, Li-Hua Gan, Mi-Xu Liu, Yun-Long Feng. Three novel organic-inorganic hybrid materials based on decaoxovanadates obtained from a new liquid phase reaction. CrystEngComm.2012, 14, 314-22.
Xiao-Juan Wang, Zhan-Guo Jiang, Jing Chen, Yun-Long Feng. Lanthanide complexes with disulfide ligand generated in situ: Syntheses, crystal structures and fluorescent properties. Inorg.Chim. Acta.2011, 373, 270-5.
Yao-Kang Lv, Zhan-Guo Jiang, Jing Chen, Wang X-J, Yun-Long Feng. Three new metal(II) complexes with unusual 2D hydrogen bond network based on N-methylimidazole. J. Inorg. Organomet. P.2011, 21, 223-8.
Yao-Kang Lv, Yun-Long Feng, Ji-Wei Liu, Zhan-Guo Jiang. Two new frameworks of potassium saccharate obtained from acidic and alkaline solution. J. Solid State Chem. 2011, 184, 1339-45.
Jing Chen, Yun-Long Feng, Zhan-Guo Jiang, Jian-Wen Cheng. Two unusual binodal highly-connected 3D networks constructed with multiflexible ligands. CrystEngComm. 2011, 13, 6071-6.

大会报告
Cai-Hong Zhan, Zhan-Guo Jiang.Fifth Technical Seminar on X Ray Analysis in the Yangtze River Delta Region, Hangzhou,China, 07– 10 / 01 / 2021. (Oral presentation)
2.Cai-Hong Zhan, Zhan-Guo Jiang.Symposium on Inorganic Chemistry and Chemical Industry in Central and Western China, Chong qing,China, 19– 22 / 04 / 2019.
3.Cai-Hong Zhan, Zhan-Guo Jiang.The 15thConference on Solid State Chemistry and Inorganic Synthesis, Fuzhou,Fujian,China, 08– 11 / 11 / 2018. (Oral presentation)
4.Cai-Hong Zhan, De-Liang Long, Leroy Cronin.Frontiers in Metal Oxide Cluster Science (FMOCS) 2017, Changchun, China, 21– 24 / 08 / 2017. (Poster award-winner)
5.Cai-Hong Zhan, De-Liang Long, Leroy Cronin.250^thACS National Meeting & Exposition, Boston,Massachusetts,USA, 16– 20 / 08 / 2015. (Oral presentation)
6. Cai-Hong Zhan, Leroy Cronin.The 5^thEuropean Chemistry Congress, Istanbul, Turkey, 31 / 08– 04 / 09 / 2014. (Oral presentation)
7. Cai-Hong Zhan, Leroy Cronin.Frontiers in Metal Oxide Cluster Science (FMOCS) 2014, Maffliers, France, 12– 15 / 07 / 2014. (Short talk)
8. Cai-Hong Zhan, De-Liang Long, Leroy Cronin.Macrocyclic and Supramolecular Chemistry (MASC) Meeting 2012, Queen Mary University, London, UK, 17– 18 / 12 / 2012. (Poster)
9. Cai-Hong Zhan, Yin-Hua He, Yun-Long Feng.The 4th National Congressof Chinese Crystallographic Society and Academic Conference, University of Science and Technology of China, China, 27– 30 / 07 / 2008. (Poster)