姓　　名
李滨 性　　别
男
出生年月
1980-02 籍　　贯
浙江衢州常山县
学　　历
硕士毕业院校
南开大学
职　　称
副教授管理职务

学科专业
有机化学 系所单位
化学系
特殊人才称号

通讯地址
天津市南开区卫津路94号南开大学化学学院化学楼北楼518
电话
**
电子邮件
nklibin@nankai.edu.cn
课题组网站

研究领域
金属有机化学：
(1)金属有机化合物的合成与表征
(2)导向有机合成的金属有机化学

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教育及科研经历
受教育经历
2001/09–2006/06，南开大学，化学学院化学系，博士，导师：徐善生教授
1997/09–2001/06，南开大学，化学学院化学系，学士

研究工作经历
2009/01 至今，南开大学，化学学院化学系，副教授
2013/02–2014/02，Korea Institute of Basic Science，Center for Catalytic Hydrocarbon Functionalizations，博士后，
导师：Prof.Sukbok Chang
2009/11–2010/07，北京大学，化学与分子工程学院，交流学者，导师：施章杰教授
2006/07–2008/12 月，南开大学，化学学院化学系，讲师
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荣誉和奖励
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科研成果与代表作
借助于本课题组十多年来一直从事合成分离鉴定金属有机化合物这一特色优势，首次分离鉴定了钌和铑催化的C-H/N-H与炔烃氧化环化反应催化循环中的全部三个关键反应中间体，并研究了其转化反应，明确地揭示出相应的催化反应机理；较为系统地考察了桥连双茂型双核金属化合物在活化不饱和有机小分子以及催化聚合反应中的协同效应；同时，在反应机理的研究基础上，开发出多个高效的过渡金属催化的C-H键官能团化新反应。目前已在J. Am. Chem. Soc.，Angew. Chem. Int. Ed.，Org. Lett.，Chem. Eur. J.，J. Org. Chem.，Organometallics等刊物上发表论文29篇，其中第一作者及通讯作者论文16篇，SCI他人引用300次。在国内学术交流会议上做学术报告3次。

主持或参加科研项目及人才基金项目情况
(1)国家自然科学基金面上项目，**、[(p-Cymene)RuCl2]2催化的C-H 键直接官能团化反应及机理研究、2014/01-2017/12、80万元、在研、主持。

(2)国家自然科学基金面上项目，**、钴催化的碳氢活化及碳-碳和碳-杂键偶联反应研究、2011/01-2013/12、36 万元、已结题、主持。

(3)国家自然科学基金青年科学基金，**、双桥连双茂型双核金属化合物在催化反应中的协同效应研究、2008/01-2010/12、19 万元、已结题、主持。

论著目录
一、5篇代表性成果(论著)
1、Li, Bin; Park, Yoonsu; *Chang, Sukbok，Regiodivergent Access to Five- and Six-Membered Benzo-Fused Lactams: Ru-Catalyzed Olefin Hydrocarbamoylation，Journal of the American Chemical Society, 136(3), pp 1125-1131，2014/1

2、Wang, Nuancheng; *Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan，Investigation and Comparison of the Mechanistic Steps in the [(Cp*MCl2)(2)] (Cp*=C5Me5; M = Rh, Ir)-Catalyzed Oxidative Annulation of
Isoquinolones with Alkynes，
Chemistry - A European Journal, 19(1), pp 358-364, 2013/1

3、*Li, Bin; Feng, Huiliang; Wang, Nuancheng; Ma, Jianfeng; Song, Haibin; Xu, Shansheng; *Wang, Baiquan，Ruthenium-Catalyzed Oxidative Coupling/Cyclization of Isoquinolones with Alkynes through
C-H/N-H Activation: Mechanism Study and Synthesis of Dibenzo[a,g]quinolizin-8-one Derivatives，
Chemistry
- A European Journal, 18(40), pp 12873-12879, 2012/10

4、*Li, Bin; Ma, Jianfeng; Wang, Nuancheng; Feng, Huiliang; Xu, Shansheng; *Wang,
Baiquan，Ruthenium-Catalyzed Oxidative C-H Bond Olefination of N-Methoxybenzamides Using an Oxidizing
Directing Group，
Organic Letters, 14(3), pp 736-739, 2012/2/3

5、Li, Bin; Wu, Zhen-Hua; Gu, Yi-Fan; Sun, Chang-Liang; *Wang, Bai-Quan; *Shi, Zhang-Jie，Direct
Cross-Coupling of C-H Bonds with Grignard Reagents through Cobalt Catalysis，
Angewandte Chemie
International Edition, 50(5), pp 1109-1113, 2011

二、全部成果(论著)
1、*Li, Bin; Wang, Nuancheng; Liang, Yujie; Xu, Shansheng; *Wang, Baiquan ，Ruthenium-Catalyzed Pyrrole
Synthesis via Oxidative Annulation of Enamides and Alkynes ，
Organic Letters, 15(1), pp 136-139,
2013/1/4

2、*Li, Bin; Ma, Jianfeng; Xie, Weijia; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，Ruthenium-Catalyzed
Regioselective C2 Alkenylation of Indoles and Pyrroles via C-H Bond Functionalization ，
Journal of Organic Chemistry, 78(18), pp 9345-9353, 2013/9/20

3、*Li, Bin; Ma, Jianfeng; Xie, Weijia; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，Regioselective C2
Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation ，Chemistry - A European Journal, 19(36), pp 11863-11868, 2013/9/2

4、*Li, Bin; Ma, Jianfeng; Liang, Yujie; Wang, Nuancheng; Xu, Shansheng; Song, Haibin; *Wang, Baiquan
，Regio- and Stereoselective Olefination of Phenol Carbamates through C-H Bond Functionalization
，European Journal of Organic Chemistry, pp 1950-1962, 2013/4

5、Tan, Xing; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Synthesis, Reactivities, and Catalytic
Properties of Iodo-Bridged Polymeric Iridium Complexes with Flexible Carbon Chain-Bridged
Bis(tetramethylcyclopentadienyl) Ligands ，Organometallics, 32(11), pp 3253-3261, 2013/6/10

6、Tan, Xing; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Photochemical C-H activation and
subsequent aerobic oxidation reactions of benzene with Cp*Ir(CO)(2) ，Journal of Organometallic Chemistry,pp 72-79, 2013/7/1

7、Tan, Xing; Liu, Bingxian; Li, Xiangyu; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan
，Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by
Sequential Cleavage of C(sp(2))-H/C(sp(3))-H and C(sp(2))-H/O-H Bonds ，Journal of the American Chemical
Society, 134(39), pp 16163-16166, 2012/10/3

8、*Li, Bin; Feng, Huiliang; Xu, Shansheng; *Wang, Baiquan ，Ruthenium-Catalyzed Isoquinolone Synthesis
through C-H Activation Using an Oxidizing Directing Group ，Chemistry - A European Journal, 17(45), pp
12573-12577, 2011/11/4

9、Zhang, Congying; Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，Reactions of Unsynnmetrically
Substituted N-Heterocyclic Carbenes with Ru-3(CO)(12) ，Organometallics, 30(11), pp 3029-3036, 2011/6/13

10、Tan, Xing; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Trinuclear and Tetranuclear Ruthenium
Carbonyl Clusters Derived from Indenylphosphines: Cleavage of C-H and C-P Bonds ，Organometallics,
30(8), pp 2308-2317, 2011/4/25

11、Zhao Xi; Li Bin; Xu Shan-sheng; Song Hai-bin; *Wang Bai-quan ，Synthesis, Structure, and Ring-opening
Metathesis Polymerization of eta(5)-Pentamethylcyclopentadienyl-(eta(5)-exo-tricyclo[5.2.1.0(2,6)]dec
a-2,5,8-trien-6-yl) Iron ，高等学校化学研究(英文版), 25(5), pp 662-665, 2009/9/2

12、Zhang, Congying; Zhao, Yang; Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，The intramolecular
sp(2) and sp(3) C-H bond activation of (p-cymene)ruthenium(II) N-heterocyclic carbene complexes ，Dalton Transactions,pp 5182-5189, 2009

13、Xu, Kun; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Reactions of Dihydrooctamethyl-s-indacene and 1,2,3,4,7-Pentamethylindene with Ru-3(CO)(12): Intramolecular sp(3) C-H
Activation ，Organometallics, 28(15), pp 4438-4442, 2009/8/10

14、Luo, Shuang; Shen, Bo; Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，Synthesis, Structures, and
Polymerization Catalytic Properties of Doubly Bridged Bis(cyclopentadienyl) Dinuclear (mu-Oxo)titanium
Complexes ，Organometallics, 28(10), pp 3109-3112, 2009/5/25

15、Li, Bin; Tan, Xing; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Synthesis and reactivity of
2-(tert-butylcyclopentadienyl)-indenyl dinuclear ruthenium complex
[eta(5):eta(5)-((t)BuC(5)H(3))(C(9)H(6))]Ru(2)(CO)(4): Halogen induced Ru cleavage from indenyl ring
，Journal of Organometallic Chemistry, 694(9-10), pp 1503-1508, 2009/4/15

16、Zhang, Congying; Luo, Feng; Cheng, Bin; Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，Reactions
of indenyl-functionalized imidazolium salts and N-heterocyclic carbenes with Ru-3(CO)(12) ，Dalton
Transactions,pp 7230-7235, 2009

17、Li, Bin; Xu, Shansheng; Song, Habin; *Wang, Baiquan ，Reactions of
(Me2C)(Me2Si)[(eta(5)-C5H3)Mo(CO)(3)](2) with Phosphanylalkynes: Rearrangement of Phosphanylalkynes into
Phosphido-Substituted Vinylidenyl Ligands by Cleavage of the P-C(alkyne) Bond and Formation of a
P-C(alkene) Bond ，European Journal of Inorganic Chemistry,pp 5494-5504, 2008/12

18、Zhao, Xi; Luo, Xiongxiong; Li, Bin; Song, Haibin; Xu, Shansheng; *Wang, Baiquan ，A new ruthenium
complex with benz[f]indenyl ligand for living radical polymerization ，European Polymer Journal, 44(10),
pp 3264-3270, 2008/10

19、Li, Bin; Zhang, Congying; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Reactions of the doubly bridged
bis(cyclopentadienyl) dinuclear molybdenum complex (Me2C)(Me2Si)[(eta(5)-C5H3)Mo(CO)(3)](2) with a
carboxylate-substituted allene ，European Journal of Inorganic Chemistry,pp 1277-1286, 2008/3

20、Li, Bin; Tan, Xing; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Unexpected reactions of
(Me2C)(Me2Si)[(eta(5)-C5H3)Mo(CO)(3)](2) with diazoalkane and carbon disulfide: Activation and cleavage
of the N = N bond and disproportionation of carbon disulfide ，Journal of Organometallic Chemistry,
693(4), pp 667-674, 2008/2/15

21、Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Balquan ，Reactions Of
(Me2C)(Me2Si)[(eta(5)-C5H3)Mo(CO)(3)](2) with nitrile and subsequent cleavage of the C N bond by
cooperation of molybdenum and ruthenium ，Journal of Organometallic Chemistry, 693(1), pp 87-96,
2008/1/1

22、Lin, Jin; Gao, Peng; Li, Bin; Xu, Shansheng; Song, Haibin; *Wang, Baiquan ，Synthesis and structures of
aryl-substituted tetramethylcyclopentadienyl dinuclear metal carbonyl complexes ，Inorganica Chimica
Acta, 359(14), pp 4503-4510, 2006/11/1

23、Li, B; *Wang, BQ; Xu, SS; Zhou, XZ; Song, HB ，Reactions of CpArCHCHArCp with Ru-3(CO)(12): An
unexpected cleavage of a bridging C-C bond and coupling of the two cyclopentadienyl rings to fulvalene
diruthenium complexes ，Organometallics, 25(5), pp 1158-1166, 2006/2/27

24、Li, B; *Wang, BQ; Xu, SS; Zhou, XZ ，Synthesis and structures of dinuclear iron, molybdenum and tungsten
complexes derived from (PhCHCHPh)-coupled bis(cyclopentadiene) ，Journal of Organometallic Chemistry,
690(23), pp 5309-5317, 2005/11/15
人才培养
指导硕士研究生4名。
本课题组研究生在读期间均获得国家奖学金或万香奖学金。
欢迎对有机化学和金属有机化学感兴趣的同学加入和报考本课题组。


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