姓　　名
王佰全 性　　别
男
出生年月
1968-05 籍　　贯
辽宁锦州黑山县
学　　历
硕士毕业院校
南开大学
职　　称
教授管理职务
副院长
学科专业
有机化学 系所单位
化学系
特殊人才称号

通讯地址
天津市南开区卫津路94号南开大学化学学院化学系
电话
**
电子邮件
bqwang@nankai.edu.cn
课题组网站
http://skleoc.nankai.edu.cn/professors/wangbq/wangbq.htm
研究领域
金属有机化学与均相催化

1. C-H键活化的金属有机化学
通过分步和计量反应分离鉴定关键反应中间体，研究过渡金属催化的C-H键活化反应的反应机理
基于对反应机理的理解，设计和发展新型高效的过渡金属催化的C-H键活化及转化反应

2. 过渡金属聚合催化剂的设计合成及催化聚合反应
重点研究基于阴离子N-杂环卡宾配体的过渡金属化合物的设计合成，研究它们在配位聚合、活性自由基聚合、开环易位聚合等聚合反应的催化性能，开发具有自主知识产权的高效聚合催化剂。

教育及科研经历
1990年，南开大学化学系，理学学士学位。
1993年，南开大学化学系，理学硕士学位（有机化学）。
1996年，南开大学化学系，理学博士学位（有机化学）。
1996年，南开大学化学系，任讲师。
1998年，南开大学化学系，教授。
2001年，南开大学化学系，博士生导师。
其中1997年3月至12月到香港中文大学化学系作访问学者。
1999年9月至2000年8月到德克萨斯大学奥斯汀分校作博士后研究。
2003年起主讲化学学院本科生必修课《有机化学》，该课程2005年被评为南开大学校级示范精品课程。
主要从事金属有机化学及均相催化研究。科研成果累计发表SCI收录论文70余篇，授权中国发明专利8项。曾5次在国际或双边学术会议上作邀请报告。1998年获教育部科技进步二等奖。2004年入选教育部“新世纪优秀人才支持计划”。

相关网页参见：
http://skleoc.nankai.edu.cn/professors/wangbq/index.html
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荣誉和奖励
新世纪优秀人才

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科研成果与代表作
代表性研究成果：

1.宋礼成，王佰全，金属有机化学原理及应用，高等教育出版社，103万字，2012.

2. Wang, B. Ansa-metallocene polymerization catalysts: effects of the bridges on the catalytic activities, Coord. Chem. Rev. 2006, 250, 242-258.

3.Tan, X.; Liu, B.; Li, X.; Li, B.; Xu, S.; Song, H.; Wang B.* Rhodium-catalyzed cascade oxidative annulation leading to substituted naphtho[1,8-bc]pyrans by sequential cleavage of C(sp2)?H/C(sp3)?H and C(sp2)?H/O?H bonds,
J. Am. Chem. Soc. 2012, 134, 16163-16166.

4.Liu, B.; Zhou, T.; Li, B.; Xu, S.; Song, H.; Wang, B.* Rhodium(III)-catalyzed alkenylation reactions of 8-methylquinolines with alkynes via C(sp3)-H activation,
Angew. Chem., Int. Ed. 2014, 53, in press.

5.Li, B.; Wu, Z.; Gu, Y.; Sun, C.; Wang, B.*; Shi, Z.* Direct cross-coupling of C-H bonds with Grignard reagents through cobalt catalysis,
Angew. Chem., Int. Ed. 2011, 50, 1109-1113.

6.Wang, N.; Li, B.*; Song, H.; Xu, S.; Wang, B.* Investigation and comparison of the mechanistic steps of the [Cp*MCl2]2 (Cp* = C5Me5, M = Rh, Ir)-catalyzed oxidative annulation of isoquinolones with alkynes,
Chem. Eur. J. 2013, 19, 358-364.

7.Li, B.*; Ma, J.; Xie, W.; Song, H.; Xu, S.; Wang, B.* Regioselective C2 oxidative olefination of indoles and pyrroles through cationic rhodium(III)-catalyzed C-H bond activation,
Chem. Eur. J. 2013, 19, 11863-11868.

8.Li, B.*; Feng, H.; Wang, N.; Ma, J.; Song, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed oxidative coupling/cyclization of isoquinolones with alkynes through C-H/N-H activation: Mechanism study and synthesis of dibenzo[a,g]quinolizin-8-one derivatives,
Chem. Eur. J. 2012, 18, 12873-12879.

9.Li, B.*; Feng, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed isoquinolone synthesis through C–H activation using an oxidizing directing group,
Chem. Eur. J. 2011, 17, 12573-12577.

10. Wang, B.*; Mu, B.; Deng, X.; Cui, H.; Xu, S.; Zhou, X.; Zou, F.; Li, Y.; Yang, L.; Li, Y.; Hu, Y. Synthesis and structures of cycloalkylidene-bridged cyclopentadienyl metallocene catalysts: effects of the bridges of ansa-metallocene complexes on the catalytic activity for ethylene polymerization, Chem. Eur. J. 2005, 11, 669-679.

11. Li, B.*; Wang, N.; Liang, Y.; Xu, S.; Wang, B.* Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes,
Org. Lett. 2013, 15, 136-139.

12. Li, B.*; Ma, J.; Wang, N.; Feng, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed oxidative C-H bond olefination of N-methoxybenzamides using an oxidizing directing group,
Org. Lett. 2012, 14, 736-739.

13. Wang, B.*; Zhuang, Y.; Luo, X.; Xu, S.; Zhou, X. Controlled/“living” radical polymerization of MMA catalyzed by cobaltocene,
Macromolecules 2003, 36, 9684-9686.

14. Xu, S.; Deng, X.; Wang, B.*; Zhou, X.; Yang, L.; Li, Y.; Hu, Y. Ethylene polymerizations with cycloalkylidene-bridged cyclopentadienyl metallocene catalysts,
Macromol. Rapid Commun. 2001, 22, 708-709.

15. Li, B.*; Ma, J.; Xie, W.; Song, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C?H bond functionalization,
J. Org. Chem. 2013, 78, 9345-9353.

16. Wang, B.; Li, M.; Xu, S.; Song, H.; Wang, B.* A general synthetic route to 6,6-substituted- 6H-dibenzo[b,d]pyrans from dibenzofuran,
J. Org. Chem. 2006, 71, 8291-8293.

17. Tan, X.; Li, B.; Xu, S.; Song, H.; Wang, B.* Synthesis, reactivities, and catalytic properties of iodo-bridged polymeric iridium complexes with flexible carbon chain-bridged bis(tetramethylcyclopentadienyl) ligands, Organometallics 2013, 32, 3253-3261.

18. Kong, Y.; Xu, S.; Song, H.; Wang, B.* Synthesis, structures, and norbornene ROMP behavior of o-aryloxide-N-heterocyclic carbene p-cymene ruthenium complexes,
Organometallics 2012, 31, 5527-5532.

19. Kong, Y.; Wen, L.; Song, H.; Xu, S.; Yang, M.; Liu, B.; Wang, B. Synthesis, structures, and norbornene polymerization behavior of aryloxide-N-heterocyclic carbene ligated palladacycles,
Organometallics 2011, 30, 153-159.

20. Chen, D.; Zhang, C.; Xu, S.; Song, H.; Wang, B. Reactions of trinuclear ruthenium complex derived from 3-(2-pyridyl)indene with diphenylacetylene and phenylacetylene: Insertion of alkynes into the Ru-C bond, Organometallics 2011, 30, 676-683.

21. Kong, Y.; Cheng, M.; Ren, H.; Xu,
S.; Song, H.; Yang, M.; Liu, B.; Wang, B. Synthesis, structures, and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene) nickel complexes,
Organometallics 2011, 30, 1677-1681.

22. Tan, X.; Li, B.; Xu, S.; Song, H.; Wang, B. Trinuclear and tetranuclear ruthenium carbonyl clusters derived from indenylphosphines: C-H and C-P bonds cleavage,
Organometallics 2011, 30, 2308-2317.

23. Zhang, C.; Li, B.; Song, H., Xu, S.; Wang, B. Reactions of unsymmetrically substituted N-heterocyclic carbenes with Ru3(CO)12,
Organometallics 2011, 30, 3029-3036.

24. Chen, D.; Zhang, X.; Xu, S.; Song, H.; Wang, B. Pyridyl-substituted indenyl ruthenium complexes: Synthesis, structures, and reactivities, Organometallics 2010, 29, 3418-3430.

25. Li, M.; Song, H.; Xu, S.; Wang, B. Alkyne-functionalized zirconocene complexes: synthesis, structures, and reactivities,
Organometallics 2010, 29, 6092-6096.

26. Kong, Y.; Ren, H.; Xu, S.; Song, H.; Liu, B.; Wang, B.* Synthesis, structures and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene) palladium complexes,
Organometallics 2009, 28, 5934-5940.

27. Luo, S.; Zhao, X.; Mu, B.; Song, H.; Xu, S.; Wang, B.* Diels-Alder reactions of benzyne with indenyl and fluorenyl ruthenium complexes,
Organometallics 2009, 28, 4602-4605.

28. Luo, S.; Shen, B.; Li, B.; Song, H.; Xu, S.; Wang, B.* Synthesis, structures and polymerization catalytic properties of doubly bridged biscyclopentadienyl dinuclear (μ-oxo) titanium complexes, Organometallics 2009, 28, 3109-3112.

29. Xu, K.; Li, B.; Xu, S.; Song, H.; Wang, B.* Reactions of dihydrooctamethyl-s-indacene and 1,2,3,4,7-pentamethylindene with Ru3(CO)12: Intramolecular sp3 C?H activation,
Organometallics 2009, 28, 4438-4442.

30. Chen, D.; Guo, J.; Xu, S.; Song, H.; Wang, B.* Reactions of Si-H-functionalized cyclopentadienes with metal carbonyls,
Organometallics 2007, 26, 4212-4219.

31. Li, B.; Wang, B.*; Xu, S.; Zhou, X.; Song, H. Reactions of CpArCHCHArCp with Ru3(CO)12: An unexpected cleavage of bridging C?C bond and coupling of the two cyclopentadienyl rings to fulvalene diruthenium complexes,
Organometallics 2006, 25, 1158-1166.

32. Chen, D.; Li, Y.; Wang, B.*; Xu, S.; Song, H. Reactions of pyridyl side-chain- functionalized cyclopentadienes with metal carbonyl: intramolecular C-H Activation of pyridine,
Organometallics 2006, 25, 307-310.

33. Wang, B.*; Mu, B.; Chen, D.; Xu, S.; Zhou, X. Diels-Alder reactions of benzyne with indenyl iron complexes, Organometallics 2004, 23, 6225-6230.

34. Wang, B.*; Zhu, B.; Zhang, J.; Xu, S.; Zhou, X.; Weng, L. Reactions of doubly bridged biscyclopentadienes with iron pentacarbonyl,
Organometallics 2003, 22, 5543-5555.

35. Wang, B.*; Zhu, B.; Xu, S.; Zhou, X. Reactions of doubly bridged biscyclopentadienes with molybdenum (tungsten) carbonyl,
Organometallics 2003, 22, 4842-4852.

36. Zhang, Y.; Wang, B.*; Xu, S.; Zhou, X. Unexpected formation of the ruthenium carbonyl cluster with a trigonal-bipyramidal Ge2Ru3 core accompanied by loss of germanium methyl groups, Organometallics 2001, 20, 3829-3932.

37. Zhang, C.; Zhao, Y.; Li, B.; Song, H.; Xu, S.; Wang, B.* The intramolecular sp2 and sp3 C-H bond activation of (p-cymene)ruthenium(II) N-heterocyclic carbene complexes,
Dalton Trans. 2009, 5182-5189.

38. Zhang, C.; Luo, F.; Cheng, B.; Li, B.; Song, H.; Xu, S.; Wang, B.* Reactions of indenyl-functionalized imidazolium salts and N-heterocyclic carbenes with Ru3(CO)12,
Dalton Trans. 2009, 7230-7235.

39. Luo, X.; Zhao, X.; Xu, S.; Wang, B.* The exo-substituted ?4-cyclopentadiene CpCo(I) complexes: A new kind of ATRP catalysts and the actual catalyst for the Cobaltocene-catalyzed ATRP,
Polymer 2009, 50, 796-801.

40. Zhao, X.; Xu, S.; Wang, B.* Controlled/“living” radical polymerization of methyl methacrylate catalyzed by CpCo(I) complexes conveniently generated from cobaltocene in situ,
Polymer 2009, 50, 2258-2263.

41. Luo, X.; Zhuang, Y.; Zhao, X.; Zhang, M.; Xu, S.; Wang, B.* Controlled/living radical polymerization of styrene catalyzed by cobaltocene,
Polymer 2008, 49, 3457-3461.

42. Deng, X., Wang, B.*, Xu, S. Zhou, X., Yang, L., Li, Y., Hu, Y., Li, Y., Zou, F., Synthesis and polymerization catalytic properties of aryl-substituted tetramethylcyclopentadienyl zirconocenes,
J. Mol. Catal. A: Chem. 2002, 184, 57-64.
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人才培养
2004，朱柏林，PhD，天津师范大学化学学院，副教授
2004，庄岩，PhD，上海华谊丙烯酸有限公司，研究所所长
2004，李颖，MS，北京中咨律师事务所知识产权部
2005，林进，PhD，河北师范大学化学与材料学院，教授
2005，穆彬，PhD，上海汽巴(ciba)高桥化学有限公司
2005，赵玉云，MS，北京国家纳米中心
2006，李滨，PhD，天津南开大学化学学院，讲师
2007，王斌，PhD，天津师范大学，副教授
2007，任鸿平，PhD，江苏扬子石化
2007，罗峰，MS，上海
2008，陈大发，PhD，哈尔滨工业大学化工学院，研究员
2008，张明亮，MS，天津药明康德
2008，程彬，MS，上海药明康德
2009，雒雄雄，PhD，中国化工集团公司工程中心（北京），产品经理
2009，赵熙，PhD，广东顺德Valspar
2009，张曦，MS，北京
2010，罗爽，PhD，北京大学化学与分子学院，博士后
2010，徐昆，MS，德国
2010，陈丽娟，MS，天津药明康德
2010，于艳琼，MS，天津药明康德
2010，郭剑，MS，北京
2011，张聪颖，PhD，烟台万华
2011，李敏雄，PhD，深圳市东阳光实业发展有限公司
2011，赵阳，MS，美国Rochest University
2011，沈波，MS，广州慧谷化学有限公司
2012，孔勇，PhD，中石化石油工程技术研究院（北京）
2012，任景云，MS，香港
2012，冯会良，MS，中国石油化工股份有限公司润滑油分公司（北京）

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