Li, Yiwei1,2; Ma, Yaohong1,2; Lichtfouse, Eric5,6; Song, Jin1,2; Gong, Rui7; Zhang, Jinheng1,2; Wang, Shuo1,2; Xiao, Leilei1,3,4
发表期刊JOURNAL OF HAZARDOUS MATERIALS
ISSN0304-3894
2022-01-05
卷号421页码:11
关键词P-nitrophenolGraphenePoly-arginineElectrochemical analysisWastewater monitoring
DOI10.1016/j.jhazmat.2021.126718
通讯作者Xiao, Leilei(llxiao@yic.ac.cn)
英文摘要Para-Nitrophenol (p-nitrophenol) is a common industrial pollutant occurring widely in water bodies, yet actual monitoring methods are limited. Herein we proposed a fully electrochemically in situ synthesized graphenepolyarginine composite functionalized screen printed electrode, as a novel p-nitrophenol sensing platform. The electrode was characterized by morphologic, spectrometric and electrochemical techniques. p-nitrophenol in both pure aqueous solution and real water samples was tested. Results show a detection limit as low as the nanomolar level, and display a linear response and high selectivity in the range of 0.5-1250 mu M. Molecular simulation reveals a detailed synergy between graphene and poly-arginine. The preferable orientation of nitrophenol molecules on the graphene interface in the presence of poly-arginine induces H- and ionic binding. This sensor is an ideal prototype for p-nitrophenol quantification in real waters.
资助机构Youth Innovation Pro-motion Association, CAS; National Natural Science Foundation of China
收录类别SCI
语种英语
关键词[WOS]PRINTED CARBON ELECTRODES; GRAPHENE; SENSOR; 4-NITROPHENOL; NANOCOMPOSITE; ISOMERS; SURFACE; GROWTH
研究领域[WOS]Engineering; Environmental Sciences & Ecology
WOS记录号WOS:000696603200006
引用统计被引频次：1[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/29753
专题中科院海岸带环境过程与生态修复重点实验室
海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
通讯作者Xiao, Leilei作者单位1.Qilu Univ Technol, Biol Inst, Shandong Acad Sci, Jinan 250103, Peoples R China
2.Shandong Prov Key Lab Biosensors, Jinan 250103, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Biol Resources Utilizat, Yantai 264003, Peoples R China
4.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
5.Aix Marseille Univ, CNRS, IRD, INRA,Coll France,CEREGE, Ave Louis Philibert, F-13100 Aix En Provence, France
6.Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
7.Chinese Acad Sci, CAS Ctr Excellence Biomacromol, Inst Biophys, Natl Lab Biomacromol, 15 Datun Rd, Beijing 100101, Peoples R China
推荐引用方式
GB/T 7714Li, Yiwei,Ma, Yaohong,Lichtfouse, Eric,et al. In situ electrochemical synthesis of graphene-poly(arginine) composite for p-nitrophenol monitoring[J]. JOURNAL OF HAZARDOUS MATERIALS,2022,421:11.
APALi, Yiwei.,Ma, Yaohong.,Lichtfouse, Eric.,Song, Jin.,Gong, Rui.,...&Xiao, Leilei.(2022).In situ electrochemical synthesis of graphene-poly(arginine) composite for p-nitrophenol monitoring.JOURNAL OF HAZARDOUS MATERIALS,421,11.
MLALi, Yiwei,et al."In situ electrochemical synthesis of graphene-poly(arginine) composite for p-nitrophenol monitoring".JOURNAL OF HAZARDOUS MATERIALS 421(2022):11.
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