Wang, Xiaoyan3; Yu, Jialuo1,2; Ji, Wan3; Arabi, Maryam1,2; Fu, Longwen1,2
; Li, Bowei1,2; Chen, Lingxin1,2,3发表期刊ACS APPLIED NANO MATERIALS
ISSN2574-0970
2021-07-23
卷号4期号:7页码:6852-6860
关键词carbon dotsmicrocystin-LRfluorescent chemosensors"on-off-on" modeindirect chemosensing
DOI10.1021/acsanm.1c00921
通讯作者Wang, Xiaoyan(wangxy@yic.ac.cn); Chen, Lingxin(lxchen@yic.ac.cn)
英文摘要The sensing of microcystin-LR (MC-LR) as a nonfluorescent species is still challenging since it has a negligible influence on the emission of fluorescent nanomaterials. Herein, a well-defined "on-off-on" indirect chemosensing strategy is developed by means of nitrogen/phosphorus-codoped carbon dots (N/P CDs) for highly sensitive and selective MC-LR determination. The nanoscale N/P CDs were conveniently synthesized by one-step hydrothermal carbonization of adenosine 5'-triphosphate (ATP) in aqueous media. The fluorescence intensity of the N/P CDs was quenched in the presence of Fe3+ due to the formation of Fe-O-P bonds between Fe3+ and the phosphate groups of the N/P CDs. The resulting N/P CD-Fe3+ system was sensitive to MC-LR, and its fluorescence intensity recovered dramatically and quickly since the MC-LR cavity competitively coordinated with Fe3+. Under optimized conditions, the proposed chemosensor exhibited a wide linear response for MC-LR in the range of 0.05-3 mu g/L, with a detection limit down to 17.1 ng/L. Moreover, the chemosensor was successfully applied to accurately detect MC-LR in real water samples and achieved high recoveries in the range of 95.0-109.3%, with relative standard deviations within 1.8-4.7%. By relying on the benefits of fluorescent chemosensors, such as simple operation, low production cost, fast response time, selectivity, and sensitivity, the proposed sensing platform possesses promising applicability for MC-LR determination in complex environmental water samples.
资助机构National Natural Science Foundation of China; Science and Technology Innovation Development Plan of Yantai of China; Natural Science Foundation of Shandong Province; Chinese Academy of Sciences President's International Fellowship Initiative; Taishan Scholar Project Special Funding
收录类别SCI
语种英语
关键词[WOS]GRAPHENE QUANTUM DOTS; SENSITIVE DETECTION; ADENOSINE-TRIPHOSPHATE; NITROGEN; REMOVAL; PROBE; FE3+; NANOPARTICLES; SENSORS; ELISA
研究领域[WOS]Science & Technology - Other Topics; Materials Science
WOS记录号WOS:000677582900036
引用统计被引频次：5[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/29540
专题中科院海岸带环境过程与生态修复重点实验室
中科院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
通讯作者Wang, Xiaoyan; Chen, Lingxin作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res,Shandong Key Lab Coa, Res Ctr Coastal Environm Engn & Technol, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao 266071, Peoples R China
3.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China
推荐引用方式
GB/T 7714Wang, Xiaoyan,Yu, Jialuo,Ji, Wan,et al. On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR[J]. ACS APPLIED NANO MATERIALS,2021,4(7):6852-6860.
APAWang, Xiaoyan.,Yu, Jialuo.,Ji, Wan.,Arabi, Maryam.,Fu, Longwen.,...&Chen, Lingxin.(2021).On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR.ACS APPLIED NANO MATERIALS,4(7),6852-6860.
MLAWang, Xiaoyan,et al."On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR".ACS APPLIED NANO MATERIALS 4.7(2021):6852-6860.
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