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Novel 2-Hydroxypropyltrimethyl Ammonium Chitosan Derivatives: Synthesis, Characterization, Moisture

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Novel 2-Hydroxypropyltrimethyl Ammonium Chitosan Derivatives: Synthesis, Characterization, Moisture Absorption and Retention Properties
Mi, Yingqi1,2,3; Miao, Qin1,2,3; Cui, Jingmin1,2,3; Tan, Wenqiang1,2,3; Guo, Zhanyong1,2,3
发表期刊MOLECULES
2021-07-01
卷号26期号:14页码:14
关键词chitosanmoisture absorptionmoisture retention
DOI10.3390/molecules26144238
通讯作者Guo, Zhanyong(zhanyongguo@hotmail.com)
英文摘要Recent years have seen a steady increase in interest and demand for the use of humectants based on biodegradable natural polymers in many fields. The aim of this paper is to investigate the moisture absorption and retention properties of 2-hydroxypropyltrimethyl ammonium chitosan derivatives which were modified by anionic compounds via ion exchange. FTIR, H-1 NMR, and C-13 NMR spectroscopy were used to demonstrate the specific structures of chitosan derivatives. The degrees of substitution for objective products were calculated by the integral ratio of hydrogen atoms according to H-1 NMR spectroscopy. Meanwhile, moisture absorption of specimens was assayed in a desiccator at different relative humidity (RH: 43% and 81%), and all target products exhibited enhanced moisture absorption. Furthermore, moisture retention measurement at different relative humidity (RH: 43%, 81%, and drier silica gel) was estimated, and all target products possessed obviously improved moisture retention property. Specifically, after 48 h later, the moisture retention property of HACBA at 81% RH was 372.34%, which was much higher than HA (180.04%). The present study provided a novel method to synthesize chitosan derivatives with significantly improved moisture absorption and retention properties that would serve as potential humectants in biomedical, food, medicine, and cosmetics fields.
资助机构National Key Research and Development Program of China; Youth Innovation Promotion Association CAS; Natural Science Foundation of Shandong Province Science and Technology Development Plan
收录类别SCI
语种英语
关键词[WOS]CHLORIDE CHITOSAN; CAPACITY; NANOPARTICLES; ANTIOXIDANT; HUMECTANTS
研究领域[WOS]Biochemistry & Molecular Biology; Chemistry
WOS记录号WOS:000676493200001
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/29537
专题海岸带生物学与生物资源利用重点实验室_海岸带生物资源高效利用研究与发展中心
海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室

通讯作者Guo, Zhanyong作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

推荐引用方式
GB/T 7714Mi, Yingqi,Miao, Qin,Cui, Jingmin,et al. Novel 2-Hydroxypropyltrimethyl Ammonium Chitosan Derivatives: Synthesis, Characterization, Moisture Absorption and Retention Properties[J]. MOLECULES,2021,26(14):14.
APAMi, Yingqi,Miao, Qin,Cui, Jingmin,Tan, Wenqiang,&Guo, Zhanyong.(2021).Novel 2-Hydroxypropyltrimethyl Ammonium Chitosan Derivatives: Synthesis, Characterization, Moisture Absorption and Retention Properties.MOLECULES,26(14),14.
MLAMi, Yingqi,et al."Novel 2-Hydroxypropyltrimethyl Ammonium Chitosan Derivatives: Synthesis, Characterization, Moisture Absorption and Retention Properties".MOLECULES 26.14(2021):14.


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