Li, Shan-Shan1; Fang, Jin-Hui1; Li, Li1; Zhu, Min1; Zhang, Feng1; Zhang, Bo-Ya1; Jiang, Tian-Jia2,3
; Zhang, Yong-Xing1发表期刊TALANTA
ISSN0039-9140
2021-04-01
卷号225页码:11
关键词Ni/Fe layered double hydroxidesSodium dodecylsulfateSurface functionalization engineeringNitrobenzeneElectroanalysis
DOI10.1016/j.talanta.2021.122087
通讯作者Jiang, Tian-Jia(tjjiang@yic.ac.cn); Zhang, Yong-Xing(zyx07157@mail.ustc.edu.cn)
英文摘要Hypersensitive detection of organic pollutions with high toxicity in drinking water always keeps its challenge in electroanalysis due to their low concentration and electrochemical redox inert. In this work, a novel nanomaterial modified electrode for the sensitive detection of nitrobenzene (NB) is presented, based on environmental friendly and cost-effective Ni/Fe layered double hydroxides functionalized with sodium dodecyl sulfate (Ni/Fe(SDS)-LDH). Such 2D layered composites were prepared and used to improve the sensitivity for NB detection, due to its good catalytic activity for NB reduction. Besides, the proposed electrode shows a remarkably promoted sensitivity to NB compared to Ni/Fe-LDHs modified one. It is because that the surface modifier SDS can provide more adsorption sites to significantly improve the adsorption of NB, which has been confirmed by the adsorption experiment and the characterization of Fourier transform infrared spectroscopy (FTIR). As a result, an impressive sensing behaviour is achieved at the proposed Ni/Fe(SDS)-LDHs modified electrode with a sensitivity of 15.79 mu A mu M-1 cm(-2). This work provides a promising way to build more advanced nanomaterials to electrochemical detection of organic pollution based on energetically synergizing of adsorption by surface functionalization engineering.
资助机构Natural Science Foundation of Anhui Province; National Science Foundation of China; Key Natural Science Research Project for Colleges and Universities of Anhui Province; National College Students Innovation and Entrepreneurship Training Program of China
收录类别SCI
语种英语
关键词[WOS]LAYERED DOUBLE HYDROXIDES; GOLD NANOPARTICLES; OXYGEN EVOLUTION; SILVER NANOPARTICLES; GREEN SYNTHESIS; NANOSHEETS; EFFICIENT; REMOVAL; ELECTRODE; CARBON
研究领域[WOS]Chemistry
WOS记录号WOS:000652032600122
引用统计被引频次：6[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/29316
专题中科院海岸带环境过程与生态修复重点实验室
中科院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室
通讯作者Jiang, Tian-Jia; Zhang, Yong-Xing作者单位1.Huaibei Normal Univ, Dept Mat Sci & Engn, Anhui Prov Key Lab Pollutant Sensit Mat & Environ, Huaibei 235000, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
推荐引用方式
GB/T 7714Li, Shan-Shan,Fang, Jin-Hui,Li, Li,et al. An ultra-sensitive electrochemical sensor of Ni/Fe-LDH toward nitrobenzene with the assistance of surface functionalization engineering[J]. TALANTA,2021,225:11.
APALi, Shan-Shan.,Fang, Jin-Hui.,Li, Li.,Zhu, Min.,Zhang, Feng.,...&Zhang, Yong-Xing.(2021).An ultra-sensitive electrochemical sensor of Ni/Fe-LDH toward nitrobenzene with the assistance of surface functionalization engineering.TALANTA,225,11.
MLALi, Shan-Shan,et al."An ultra-sensitive electrochemical sensor of Ni/Fe-LDH toward nitrobenzene with the assistance of surface functionalization engineering".TALANTA 225(2021):11.
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