Zhang, Ruichang1,2; Tu, Chen3
; Zhang, Haibo4; Luo, Yongming2,3,5发表期刊JOURNAL OF SOILS AND SEDIMENTS
ISSN1439-0108
2020-03-01
卷号20期号:3页码:1395-1403
关键词Amorphous iron oxideRetentionStabilityTitanium dioxide nanoparticlesTransportVariable-charge soil
DOI10.1007/s11368-019-02509-x
通讯作者Luo, Yongming(ymluo@issas.ac.cn)
英文摘要Purpose The exposure pathways and environmental impacts of titanium dioxide nanoparticles (TiO2 NPs) released into soils could be significantly influenced by their stability and transport behaviors. The aim of this study was to investigate the stability and transport of TiO2 NPs in three variable-charge soils and to determine the key factors controlling these behaviors. Materials and methods Three surface (0~15 cm) variable-charge soils derived from quaternary red clay, humid ferralsols and stagnic anthrosols collected from Yingtan, Jiangxi Province (YT-H and YT-S, respectively), and humid ferralsols collected from Fuyang, Zhejiang Province (FY-H), were used in this study. Batch sedimentation experiments of TiO2 NPs in soil suspensions were performed for 10 h to quantify their stability. Transport of TiO2 NPs in soil columns was conducted with and without the presence of fulvic acid (FA). Results and discussion Apart from soil organic matter (SOM) and iron oxides, there was no significant difference between the tested soils. Batch experiments showed that TiO2 NPs were more stable in the YT-S soil suspension with high dissolved organic matter than in the YT-H and FY-H soil suspensions. In the column experiments, all TiO2 NPs were retained in YT-H and YT-S, while 11% of the TiO2 NPs were eluted from FY-H with a low amorphous iron oxide content. The significant retention of TiO2 NPs in the soils could be attributed to the straining and adsorption of TiO2 NPs on the surface of soil particles. FA enhanced the transport of TiO2 NPs in YT-H and FY-H by dispersing the TiO2 NPs and reducing their adsorption onto soil particles, while all the TiO2 NPs dispersed in the FA solution were still deposited in YT-S with a high amorphous iron oxide content. Conclusions The stability of TiO2 NPs in three variable-charge soil suspensions was dependent on the SOM. However, the mobility of TiO2 NPs in soils was not directly related to their stability in the soil suspensions. The difference in amorphous iron oxide content could induce the disparity in mobility of TiO2 NPs in soils.
收录类别SCI
语种英语
关键词[WOS]POROUS-MEDIA; TIO2 NANOPARTICLES; IONIC-STRENGTH; RETENTION; AGGREGATION; FILTRATION; SAND; BIOACCUMULATION; SUSPENSIONS; MECHANISMS
研究领域[WOS]Environmental Sciences & Ecology; Agriculture
WOS记录号WOS:000534512900020
引用统计被引频次：5[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/29062
专题中科院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室
中科院海岸带环境过程与生态修复重点实验室
通讯作者Luo, Yongming作者单位1.Henan Univ Sci & Technol, Chem Engn & Pharmaceut Sch, Luoyang 471023, Peoples R China
2.Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
4.Zhejiang A&F Univ, Key Lab Soil Pollut Bioremediat Zhejiang Prov, Hangzhou 311300, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714Zhang, Ruichang,Tu, Chen,Zhang, Haibo,et al. Stability and transport of titanium dioxide nanoparticles in three variable-charge soils[J]. JOURNAL OF SOILS AND SEDIMENTS,2020,20(3):1395-1403.
APAZhang, Ruichang,Tu, Chen,Zhang, Haibo,&Luo, Yongming.(2020).Stability and transport of titanium dioxide nanoparticles in three variable-charge soils.JOURNAL OF SOILS AND SEDIMENTS,20(3),1395-1403.
MLAZhang, Ruichang,et al."Stability and transport of titanium dioxide nanoparticles in three variable-charge soils".JOURNAL OF SOILS AND SEDIMENTS 20.3(2020):1395-1403.
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